Evidence that the Second Law of Thermodynamics is wrong?

Posted 18 February 2010 by

by Joe Felsenstein, http://evolution.gs.washington.edu/felsenstein.html The Discovery Institute Press has published a book by Granville Sewell, a mathematician at the University of Texas at El Paso. Under the title of In The Beginning And Other Essays on Intelligent Design, it apparently consists of previous writings of Sewell, some in revised versions. I hasten to say that I do not have a copy of the book, and have not read it. However Sewell makes it clear that its basic arguments can also be found online in earlier versions of these essays. The one that interests me is his argument that evolution contradicts the Second Law of Thermodynamics, which will be found online here, here, here, and here. Now the statement that evolution can't have occurred because it contradicts the Second Law is one of the hoariest old creationist myths. When you hear it you know you are dealing either with someone who does not understand science, or else someone who does understand science but is actively, and dishonestly, trying to get you not to understand science. It is easily answered, and has been, many times: in a closed system entropy does increase, but the biosphere is not a closed system --- it is utterly dependent on inflows of energy, mostly from the sun, and the entropy increase from the outflow of energy from the sun far exceeds the decrease of entropy by reproduction and by evolution. Surely the Discovery Institute wants its scientific arguments to be ones that can be taken seriously. Sewell must have come up with some new argument that is more powerful than the old creationist howler, no? Well ... no. Granville Sewell's arguments about the Second Law have already been answered, years ago and at length, by Mark Perakh (here) and by Jason Rosenhouse (here). Even in Sewell's announcement of his book at Uncommon Descent, in the comments on that post the pro-evolution commentator "nakashima" has made a fairly devastating critique. Granville Sewell's response to the basic argument that the biosphere is not a closed system is that
... if all we see entering is radiation and meteorite fragments, it seems clear that what is entering through the boundary cannot explain the increase in order observed here.
Which leads me to a thought. My back yard has some very tough and capable weeds, with which we struggle. I know that if I take a few seeds from one of these weeds and plant them, in a few months there will be weed plants there, ones that have a great many of those same seeds on them. That is a local decrease in entropy, an increase in order. A few seeds are replaced by many, with stems and leaves too. How did this happen? Aside from some water, carbon dioxide and minerals, mostly it happened by sunlight striking the plants and driving photosynthesis. It's not a mystery. But all we saw entering the plants was radiation! If Granville Sewall is right, the growth of the weeds is a violation of the Second Law of Thermodynamics. Since Granville Sewell is a trained mathematician, and his work is endorsed by the Discovery Institute Press, surely we must be hesitant to conclude that his argument is simply wrong. No, the inevitable conclusion is that Second Law of Thermodynamics must be wrong. A momentous conclusion. Someone should tell the physicists. There can hardly be any more repeatable and easily verifiable phenomenon in nature than the growth of weeds in my back yard. Evolution happens, natural selection improves the fitness of organisms ... and weeds grow. If Granville Sewell is right, these all prove that the Second Law of Thermodynamics is wrong.

263 Comments

eric · 18 February 2010

Dear Lord, if you exist, spare us from 2LOT trolls...

TomS · 18 February 2010

Bringing up the 2nd law of thermodynamics (2lot) is a clever ploy, for very few people understand it, and any argument based on the 2lot therefore sounds like quibbling over fine points between two groups of experts. That is, it sounds like there really is a "scientific controversy", and it is "only fair to have open discussion between the two sides of the controversy."

May I simply point out, rather, that the 2lot applies also to intelligent designers. It was discovered precisely because the very clever engineers of the 19th century ran into limitations on what they were able to do. They couldn't make "perpetual motion machines of the 2nd kind".

Therefore, if anyone discovers a violation of the 2lot, we can feel confident that the explanation for that violation is not to be found in the activity of intelligent designers.

This is, of course, merely pointing out once again that the advocates of intelligent design do not have an answer to the very question that they are raising.
Which is an instance of the observation that ID does not have an answer to any question.

Phillip Moon · 18 February 2010

As a rule, when I see this argument used, the IDiot tends to simply state that complexity can not come from simplicity. It violates the 2nd law.

Have any of these people been to a child birthing? From a single sperm and a single egg we get babies. That's about as complicated as any 747.

harold · 18 February 2010

Creationist claims that there cannot be a LOCAL decrease in entropy demonstrate either extreme dishonesty or complete lack of ignorance of thermodynamics.

Also, presumably, since life does require energy input to be maintained, the ongoing reproduction and growth of organisms does represent a local decrease in entropy at some scale.

But this would be the case whether or not life was evolving. The facts that reproduction results in offspring that vary from parents, and that natural selection of phenotypes and other factors such as genetic drift can cause variation in allele frequency in population, don't necessarily seem to suggest increased consumption of energy/extra decrease of local entropy. It takes energy and presumably local decrease in entropy to reproduce and survive; it doesn't necessarily take EXTRA energy/local entropy decrease to evolve. Maybe it does, maybe it doesn't (the chemistry behind mutations is complex but they are spontaneous events).

Perhaps the 2LOT argument is not merely wrong about 2LOT, but also entirely irrelevant. It may actually amount to an argument that life itself does not exist.

Chris Lawson · 18 February 2010

Ah, so now the DI is promoting 2LOT denial: all power to the big tent!

carlsonj · 18 February 2010

If Granville Sewall is right, the growth of the weeds is a violation of the Second Law of Thermodynamics.
Unless, of course, there is intervention of an intelligent designer capable of violating SLOT. So, in conclusion, if you are having problems with weeds in your yard, it is clearly a punishment from God The Intelligent Designer. HTH.

DS · 18 February 2010

Now let's see, all we have to do to fool the ignorant rubes is make a few nebulous statements conflating the terms energy, entropy and information (without ever actually defining these terms mind you) and everyone will be fooled. Brilliant!

Why these charlatans always think that they can bring down hundreds of years of scientific advancement with a few simple word games and absolutely no evidence or experimentation is beyond me. Why anyone would fall for this kind of tripe is another matter altogether.

Mike Elzinga · 18 February 2010

It is a well-known prediction of the second law that, in a closed system, every type of order is unstable and must eventually decrease, as everything tends toward more probable states. Not only will carbon and temperature distributions become more disordered (more uniform), but the performance of all electronic devices will deteriorate, not improve. Natural forces, such as corrosion, erosion, fire and explosions, do not create order, they destroy it. The second law is all about probability, it uses probability at the microscopic level to predict macroscopic change: the reason carbon distributes itself more and more uniformly in an insulated solid is, that is what the laws of probability predict when diffusion alone is operative.

— Granville Sewell
Sigh! I have been watching this shtick for over 40 years, and it is one of the most exasperating displays of gut-bustingly, determined stupidity imaginable. The second law of thermodynamics is NOT about order. Entropy is NOT about order. I and other physicists have said this repeatedly over those 40 years, but the meme spreads faster than we can keep up with it. We even see other scientists catching this virus. And I have also pointed out here on PT and in talks I have given over the years that this misconception is The Fundamental Misconception of the ID/creationists. There is nothing else that even comes close to identifying ID/creationist writings as reliably as this misconception. Even when ID/creationists attempt to avoid using the 2nd law argument overtly, the misconceptions remain in their work. Dembski’s “conservation of information” and “complex specified information” and his tactics for calculating probabilities all reveal the misconception. Behe’s “irreducible complexity” is founded on this misconception. Abel’s “spontaneous molecular chaos” is a result of this misconception. Sanford’s “genetic entropy” derives from this misconception. So do entropy barriers. Every example given by ID/creationists from the time of Morris and Gish and their “tornadoes-in-junkyards” argument employs this misconception and makes the further mistake of completely disregarding the energy ranges in which various complex systems form and operate. All the “improbability arguments” made by ID/creationists rely on this misconception because they must employ the “lottery winner fallacy” in order to get their “argument” to come out “right.”

If archeologists of some future society were to unearth the many versions of my PDE solver, PDE2D , which I have produced over the last 20 years, they would certainly note a steady increase in complexity over time, and they would see many obvious similarities between each new version and the previous one.

— Granville Sewell
This one is particularly ironic in view of the claims by Dembski, et. al. that Dawkins’ Weasel Program has the solution put in by intelligence. Dembski and Marks also criticize the genetic algorithm programs for having algorithms that make use of “active information” to find the solution. Just what the hell does Sewell think his partial differential solvers do; randomly select solutions from essentially infinite solution spaces? Not on your life; Sewell “cheats” just like anyone else who puts in things like continuity, differentiability, analyticity, and whatever other properties one can use to solve systems of PDEs. Suggesting that physicists and biologists cannot be allowed to put into their computer programs the algorithms that nature uses to “find solutions” is also another manifestation of that Fundamental Misconception. ID/creationists, as I have said before, live inside their heads. They never observe what goes on in nature, they never study how complex systems evolve in nature. They know nothing of the four fundamental forces in nature. They know nothing of solids and liquids, of wetted surfaces, of Vander Waals forces. By coincidence there is a very nice article in the February 2010 issue of Physics Today about how water wets. But this stuff has been known about and studied for well over a century. The more technological tools we acquire, the more we learn of the subtle details of these processes. And NONE of them violate the laws of thermodynamics, PERIOD.

eric · 18 February 2010

carlsonj said: Unless, of course, there is intervention of an intelligent designer capable of violating SLOT.
That, of course, is the unspoken crux of their argument. Unspoken because natural designers obey 2LOT, so admitting their designer does not shows their whole "it could be aliens" line is bogus and they are only talking about God.

Matt G · 18 February 2010

harold said: Creationist claims that there cannot be a LOCAL decrease in entropy demonstrate either extreme dishonesty or complete lack of ignorance of thermodynamics.
A lack of ignorance? No, that is something of which they have an endless supply.

Jim Thomerson · 18 February 2010

http://books.google.com/books?id=s7twnshsNW8C&printsec=frontcover&dq=E.+O.+Wiley+second+law&source=bl&ots=SGeXb9DMh0&sig=bSsA1IE_b6TNSgkGGtv1YnOgC5Q&hl=en&ei=3b19S-upAciWtged2PihBQ&sa=X&oi=book_result&ct=result&resnum=5&ved=0CBQQ6AEwBA#v=onepage&q=&f=false

Has anyone read this book?

Joshua Zelinsky · 18 February 2010

Granville is a fascinating example of how much trouble the creationists and intelligent design proponents have of getting people who are actually productive in their fields (although in the case of Behe it looks like he was productive until he got involved). Let's look at Granville's publication record according to Mathscinet, which covers pretty much all mathematics in the Western hemisphere

We have two items about his software (which he can't resist plugging any here), one from 1983 and the other from 1985. We have a paper from 1988 about making graphs look pretty and easy to see on computer screens. We have two marginally large works. One is a review work/textbooks on the state of PDE research from 2005, but that is a second edition. Original is from 1988. The other is a textbook on computational linear algebra from 2005. The textbooks seem to be well-received judging from a quick Google search for reviews, two of which note that Granville uses the textbook in his own classes (memo to Granville, you are not Serge Lang). It seems like his productivity isn't exactly high. No real research since the 1980s.

Joshua Zelinsky · 18 February 2010

Hmm, I may need to take my comment back slightly. I just looked also at Granville's resume (linked to from his homepage http://www.math.utep.edu/Faculty/sewell/ )and it looks like if one moves outside pure math his productivity doesn't look as bad, with some papers in metallurgy and geology. The result doesn't look nearly as bad. He doesn't look impressive at all. Seems more like a mediocre academic than someone with a poor record.

Also apparently he's been pushing some form of ID for a while. There appears to be some sort of postscript to "Analysis of a Finite Element Method: PDE/PROTRAN" which the DI claims is pro-ID. That's from 1985. If anyone can track down a copy I'd be interested in seeing what it says.

Mike Elzinga · 18 February 2010

With time, the second law came to be interpreted more and more generally, and today most discussions of the second law in physics textbooks offer examples of entropy increases (order decreases, since we are defining order to be the opposite of entropy) which have nothing to do with heat conduction or diffusion, such as the shattering of a wine glass or the demolition of a building.

— Granville Sewell
Damn! He even accuses the physicists of spreading this meme. Prior to the Morris and Gish, physicists knew of the misconceptions about entropy and compensated for them in their courses. Since Morris and Gish, the misconceptions students brought into statistical mechanics and thermodynamics courses in physics grew dramatically. The meme was spreading with a vengeance by the 1980s. The history of thermodynamics, the 2nd law and entropy contains many “interpretations” which were gradually being consolidated into a more consistent picture, and physics instructors were making efforts to ensure students understood that thermodynamics was about the bookkeeping of energy, NOT order. It didn’t help that von Neuman and Shannon started using the term entropy for a formula in information theory that looked a lot like Boltzmann’s expression for entropy. But that was being dealt with by instructors. However, some physicists, in their attempts to introduce the concepts of probability and statistics, would use illustrations of permutations and combinations that involved the spatial distributions of balls in slots. It was a well-intentioned attempt to clarify concepts that sometimes backfired when the instructor or textbook made the transition back to the enumeration of energy states. Students sometimes didn’t make the transition and would conflate spatial order with energy states. Then along came the creationists and Morris and Gish who managed to grab onto the most egregious mischaracterizations of thermodynamics. After “scientific” creationism morphed into ID, those very misconceptions and mischaracterizations flooded the molecular level arguments by Dembski, Behe, et. al.. There are many efforts by the physics community as well as the chemistry community to deal with this misconception. Many introductory courses are placing far more emphasis on the enumeration of ENERGY states and trying to avoid the association of entropy with disorder. I suspect one of the reasons that the ID/creationists jumped onto the “information shtick” is because it is a relatively new field compared with physics and chemistry, and the word “entropy” is used differently but can be easily conflated with its use in thermodynamics. Conflation is one of the favorite games of ID/creationists. That game derives from their upbringing in exegesis, hermeneutics, etymology, and generalized word-gaming. I have never seen an ID/creationist speaker who didn’t play this game.

Alann · 18 February 2010

Confusing entropy with disorder is ridiculous. It has nothing to do with order/disorder and if it did entropy increases order.
Example: add hot water to a cup of cold water the initial state is quite disorderly but over time it becomes a uniform temperature due to entropy.
And discounting the sun? The sun adds 0.174 exajoules to Earth every second. That means every 10 minutes it add more energy than that consumed by the US every year (105 EJ).

feralboy12 · 18 February 2010

Dude, if you've really overturned the second law of thermodynamics, you need to email the President of Physics.

Henry J · 18 February 2010

How would it help the antievolution activists to show that the 2nd law was wrong, anyway? That wouldn't rule out evolution, it would just rule out one of their oldest arguments. At least, to anyone who's paying attention that's what it would do.

Besides, entropy is about the distribution of energy states among atomic (or subatomic) particles, not the arrangements of those particles in molecules.

Henry

fnxtr · 18 February 2010

Joe, their argument will simply be that God "the designer" (nudge, wink), created the weeds in the first place, they're just doing what they were designed to do.

Not agreeing, just saying.

Joshua Zelinsky · 18 February 2010

Mike, not exactly. From a mathematical perspective entropy really is deeply related to permutation issues. Boltzmann entropy and Gibbs entropy are both defined specifically in terms of permutations, and there are some of the oldest forms of entropy known. And yes, some formulations of Shannon information theory aren't just similar to the entropy equations, but actually identical. And the analogy is actually a helpful one in some contexts (such as for example in making Landauer principle argumens which are sort of related to understanding why Maxwell's demon doesn't work).

Note also that we need to be careful when we talk about just "entropy" as a general issue because there are actually multiple definitions used by physicists. All the often used defintions agree closely if one is dealing with a well behaved object, such as a gas that is close to ideal. However, they branch off quickly from there, not so much from disagreement of values (although in the case of Boltzmann v. Gibbs that does happen) so much as that some of them are just not meaningful in certain contexts. Thus for example, the definitions of entropy used for most classical purposes will break down in contexts where there is quantum mechanical behavior but we have other definitions that pick up the slack in those cases.

Disclaimer: I'm a math grad student not a physicist, so some of the above may be wrong.

Ravilyn Sanders · 18 February 2010

These mathematicians are a funny lot. They happily start with a few axioms and start proving theorem after theorem that were all consistent with those axioms even if it has absolutely no connection to reality.

Italian mathematician Giovanni Girolamo Saccheri set about to prove that Euclidean geometry is the only possible geometry. He started with a postulate that basic axioms of Euclid are not true and proved theorem after theorem, looking for a violation of the starting axioms to finally say, "Since this can not be true, our assumption Euclidean axioms are wrong also can not be true. So Euclidean geometry is the only True Geometry". He never could. Every theorem he proved was consistent. He died thinking he was a miserable failure. But what he had done was to have invented an entirely new branch of mathematics, "Non Euclidean geometry". Of course we dont have a single example of non euclidean geometry existing, none physicists could detect. But that still that non euclidean geometry is a vibrant and active field.

So let this mathematician also start with the axiom that second law of thermody is false, and go on to prove a new field of mathematics. Since 2lot is the only physical law that obeys an arrow of time, (all other physical laws work forward as well as backward in time) he will have a fertile field where water flows uphill, heat flows from cool to hot bodies, even faster than light travel may be possible.

But that will not make it real or physical any more than non Euclidean geometry.

Sorry guys, yesterday I was roped in to sit in an all day meeting a French mathematician who kept talking about Kryolov sub spaces and singular value decomposition till we all keeled over.

Dan · 18 February 2010

Joshua Zelinsky said: Mike, not exactly. From a mathematical perspective entropy really is deeply related to permutation issues. Boltzmann entropy and Gibbs entropy are both defined specifically in terms of permutations, and there are some of the oldest forms of entropy known.
The permutation issues arise only for the ideal gas and, as we all know, no gas is ideal. A good discussion about why disorder is a poor metaphor for entropy is presented by Professor of Chemistry Frank L. Lambert at http://entropysite.oxy.edu/ Since retirement, Lambert has led a crusade to get texts to stop using the "entropy as disorder" metaphor. (As Granville notes, this poor usage is depressingly common. Granville, however, takes this as evidence that it's correct!) The site currently starts off with the announcement: "The 2nd edition of Burdge’s Chemistry was published in late January. It is truly excellent. Not only have all references in the previous edition to entropy as “disorder” been eliminated but, far beyond this, the introduction to “what entropy is” is superbly handled."

DavidK · 18 February 2010

A side note here is that this book was published by the Dishonesty Institute Press (who/what?). The DI has apparently gone into the business of publishing their own nonsense. This allows them to publish their religious tracts as science, their creationism as science, and also they can claim their materials are peer reviewed (by fellow creationits of course), thus giving them an air of legitmacy to their followers and answering the claims of the real scientific community that they have no peer-reviewed materials. This must be a strategy linked to their 2010 wedge efforts.

Dan · 18 February 2010

Ravilyn Sanders said: Sorry guys, yesterday I was roped in to sit in an all day meeting a French mathematician who kept talking about Kryolov sub spaces and singular value decomposition till we all keeled over.
I love singular value decomposition! But I must admit that if I've ever heard of Kryolov subspaces, I've forgotten.

jswise · 18 February 2010

If someone disses your experimental results, just say, "They're as repeatable and verifiable as Felsenstein's Weeds." In this way, you can demonstrate a complete lack of ignorance.

Ryan Cunningham · 18 February 2010

Phillip Moon said: As a rule, when I see this argument used, the IDiot tends to simply state that complexity can not come from simplicity. It violates the 2nd law. Have any of these people been to a child birthing? From a single sperm and a single egg we get babies. That's about as complicated as any 747.
I use the EXACT same argument. "Wait. Don't all your arguments apply equally well to development? Are you arguing that the second law forbids a single cell to grow into a person?"

KP · 18 February 2010

Yes there is a Flea in the comment threads of my local newspaper who is a YEC/bible literalist. He repeats all the old creationist canards and 2LOT is a favorite. Yesterday I got the giraffe neck one. Yawn.

Jim Harrison · 18 February 2010

I'd love to know how many creationists believe that human inventors can evade the 2nd law. My impression is that many of them don't realize that genuine intelligent design, i.e. what engineers do for a living, is as constrained by thermodynamics as any other process in the universe.

Joshua Zelinsky · 18 February 2010

Dan said: The permutation issues arise only for the ideal gas and, as we all know, no gas is ideal.

As I understand it, the issue arises if one wants the approximate entropy of a near-ideal gas to actually behave asymptotically how it should. Indeed, the whole permutation thing comes in what amounts to the non-ideal case. In an ideal gas Boltzmann and Gibbs entropy agree. It is only in the non-ideal case that we care about permutations. Am I missing something here?

A good discussion about why disorder is a poor metaphor for entropy is presented by Professor of Chemistry Frank L. Lambert at http://entropysite.oxy.edu/

I have zero objection to that and indeed support it a lot. Thinking about entropy in terms of disorder is generally misleading and thinking in terms of information is only helpful in certain narrow contexts. But this is a distinct issue from what I was talking about, which is thinking in terms of permutations and ensembles.

Mike Elzinga · 18 February 2010

Joshua Zelinsky said: Mike, not exactly. From a mathematical perspective entropy really is deeply related to permutation issues. ...
Josh, Entropy refers to the number of energy microstates that are consistent with the macrostate of the system (its temperature, pressure, volume, magnetization, etc.) It is actually the logarithm of that number multiplied by Boltzmann’s constant(S = kB ln W, where W is the number of microstates). The enumeration of those states gets into the technical issues of counting, and that is often where the confusion starts because there are lots of individual cases one can play with. It also depends on whether one is considering a classical system or a quantum mechanical system. Then there are the issues of energy distributions, Boltzmann, Bose-Einstein, and Fermi-Dirac. But the form of that relationship (the logarithm along with Boltzmann’s constant) gives it a tight relationship to the absolute temperature of the system and the way that number of microstates changes with total energy. And it eventually all ties together with the older thermodynamic calculations. I don’t want to drive away people here. My past experiences warn me to avoid getting into the nerdy, arcane details in the presence of people who may be uncomfortable with the math; and it isn’t necessary to get into these details because the misconceptions actually begin at a much more elementary level. So let me just divide this into a couple of stages. You may be familiar with the fact that thermodynamics can be taught without any regard to the details of the “internal states” of a system. One can divide up the energy budget into “heat” or “internal energy” and energy that goes into doing mechanical work. The “working medium” can hold energy, and we can do empirical measurements to determine how much the medium can store energy in the form of “heat”. Then the entire subject can be reduced to a set of partial derivatives on multivariable functions that give the relationships among things like temperature, volume, pressure; all macroscopic parameters of the system. Some courses can be taught in an almost axiomatic fashion. But ultimately one wants to lay the groundwork that actually allows one to look into the “working medium” and actually account for where that internal energy is stored and in what form. To do that in a beginning calculus level or classical mechanics course, one can start making toy models of classical molecules that spin, vibrate, bend and do a number of other kinds of motions for which kinetic and potential energy can be calculated. Then a collection of these “molecules” can be made the “working medium” inside a container in which they can also pick up energy from interactions with the “outside world”. From this little exercise, one can begin to talk about the total internal energy and the average energy per degree of freedom among all the ways the toy molecules can store energy. This starts laying the groundwork for the concept of temperature from the microscopic perspective (in classical thermodynamics, temperature is related to a macroscopic property of the system, such as its length within a constraining tube; i.g., a mercury thermometer. There are lots of other things that can be used also; and there are details that need to be considered as well, but let’s hold off on that for now.). However, for laypersons, explanations have to be far simpler; and it is very difficult for a working physicist to not want to start slinging around mathematics, but one must learn to resist. Therefore, one is limited to telling laypeople that energy is contained inside a system within a bunch of microscopic “buckets” or “wiggly mechanisms” that vibrate in various ways. With a little effort and elaboration, one can bridge the gap somewhat so that people get the idea (I have used rattle-trap cars with all their loose and vibrating parts as it hauls down a bumpy road to illustrate frictional heating, for example.) I think most physicists these days are being very careful about “multiple definitions” of entropy. The issues for the transition from classical to quantum physics comes down to counting; and even classical systems must ultimately come down to a denumerable set of states. Quantum mechanics ultimately erased the paradoxes in classical physics with infinitesimal divisions of energy states. So that issue no longer exists; or at least should not cause serious problems. Where the issue for the layperson and the ID/creationists lies is in how matter condenses into increasingly complex systems and does this within various distinct energy ranges. This is the mistake that nearly all ID/creationists make; namely, that “spontaneous molecular chaos”, to use Abel’s made up term, applies. That is dead wrong and always has been. The rule in nature is that matter condenses; and it does so in various energy ranges depending on the depth of the potential wells formed by their mutual interactions. In order for particles to condense into these wells, energy must be released. That energy goes off in the form of photons, phonons, or is carried away by other particles. And in accounting for that energy, one finds that the second law always holds. One can also count the number of microstates and compute entropy. If the total number of microstates for a given set of molecules has decreased because they clustered, a greater number of microstates had to become available in order for them to do this. That greater number encompasses all those photons, phonons, and other molecules that carried excess energy away. Here is a link to a colloquial description of Maxwell’s Demon I did on an earlier thread. I can think of better ways to do it if I had to do it again, but it conveys the idea, I hope.

Flint · 18 February 2010

The reason these thermodynamic arguments persist so long, and despite so much debunking, is probably simple: they're one of the few arguments where the creationist god is not an option, it is absolutely required, and evolution is either impossible and so didn't happen, or is impossible without the creationist god.

For the average non-physicist creationist (and even for those who ARE physicists), the claim that their god MUST be involved, because evolution would defy fundamental laws without it, is obviously intoxicating. I think this is a sort of creationist version of physics envy.

Steve Morrison · 18 February 2010

Joshua Zelinsky · 18 February 2010

Mike,

You may be familiar with the fact that thermodynamics can be taught without any regard to the details of the “internal states” of a system. One can divide up the energy budget into “heat” or “internal energy” and energy that goes into doing mechanical work. The “working medium” can hold energy, and we can do empirical measurements to determine how much the medium can store energy in the form of “heat”. Then the entire subject can be reduced to a set of partial derivatives on multivariable functions that give the relationships among things like temperature, volume, pressure; all macroscopic parameters of the system. Some courses can be taught in an almost axiomatic fashion.

Hmm, was vaguely aware of that but hadn't heard a statement that explicit before to that effect. That makes sense. The rest of your post also helps clarify stuff a bit. I guess I'm too used to thinking in terms of the counting issues since from a mathematicians perspective that's where a lot of the interesting stuff is happening (and for other analogs we care about like topological entropy which really stretches the use of the word). Thanks, that helped a lot.

Joe Felsenstein · 19 February 2010

carlsonj
[me:] If Granville Sew[e]ll is right, the growth of the weeds is a violation of the Second Law of Thermodynamics.
Unless, of course, there is intervention of an intelligent designer capable of violating SLOT. So, in conclusion, if you are having problems with weeds in your yard, it is clearly a punishment from God The Intelligent Designer. HTH.
(Oops, that one time I got Sewell's name mixed up with Sewall Wright). Thanks, that actually goes far to explain why there are still so many weeds in spite of my heroic efforts. But that is little comfort, because I get to feel not only frustrated but guilty too.
feralboy12 Dude, if you’ve really overturned the second law of thermodynamics, you need to email the President of Physics.
Well, if my weeds haven't overturned the SLOT then we'd have to say that Granville Sewell doesn't know what he is talking about, and that the Discovery Institute is pushing blatantly invalid scientific arguments! Can't have that, can we? So the obvious answer is that SLOT is wrong.
fnxtr said: Joe, their argument will simply be that God "the designer" (nudge, wink), created the weeds in the first place, they're just doing what they were designed to do. Not agreeing, just saying.
Hard to see how these material entities (the weeds), even if created by supernatural entities, could then be designed so as to violate the SLOT by growing! (If SLOT is true, that is, and if Granville Sewell's argument is correct ...)

Mike Elzinga · 19 February 2010

Flint said: The reason these thermodynamic arguments persist so long, and despite so much debunking, is probably simple: they're one of the few arguments where the creationist god is not an option, it is absolutely required, and evolution is either impossible and so didn't happen, or is impossible without the creationist god.
I think this pretty much captures it. Dogma first; all else bent to fit. Yet I have also wondered if at an even deeper level lies terror of Hell; the “what if you’re wrong” shtick. Every time I have encountered an ID/creationist and pointed out their problem with not only thermo, but other scientific concepts as well, it’s as though their entire nervous system shuts off. I had one just yesterday start really laying into me with name-calling and blustering, telling me that I had no idea of what I was talking about. Here is his parting shot at me after I asked him if he could state the units of entropy, “negentropy”, and “information”; all terms he himself conflated.

“your reply is so pathetic, and your ignorance of the deep, substantial connections between the IT and TD notions of entropy (ever heard of Maxwell's Demon?) is so obvious that I am quite happy to let you boil in your prejudice broth. :( "

This is what I have seen for over 40 years now. I don’t know if it can be changed.

Mike Elzinga · 19 February 2010

Joe Felsenstein said: Hard to see how these material entities (the weeds), even if created by supernatural entities, could then be designed so as to violate the SLOT by growing! (If SLOT is true, that is, and if Granville Sewell's argument is correct ...)
Devil weeds.

Vince · 19 February 2010

Mike Elzinga said:
Joe Felsenstein said: Hard to see how these material entities (the weeds), even if created by supernatural entities, could then be designed so as to violate the SLOT by growing! (If SLOT is true, that is, and if Granville Sewell's argument is correct ...)
Devil weeds.
My yard must be a mini version of hell....

Steve Taylor · 19 February 2010

Steve Morrison said: Krylov subspaces
Krylov - what an incredible life.

Stuart Weinstein · 19 February 2010

Joshua Zelinsky said: Mike,

You may be familiar with the fact that thermodynamics can be taught without any regard to the details of the “internal states” of a system. One can divide up the energy budget into “heat” or “internal energy” and energy that goes into doing mechanical work. The “working medium” can hold energy, and we can do empirical measurements to determine how much the medium can store energy in the form of “heat”. Then the entire subject can be reduced to a set of partial derivatives on multivariable functions that give the relationships among things like temperature, volume, pressure; all macroscopic parameters of the system. Some courses can be taught in an almost axiomatic fashion.

Hmm, was vaguely aware of that but hadn't heard a statement that explicit before to that effect. That makes sense. The rest of your post also helps clarify stuff a bit. I guess I'm too used to thinking in terms of the counting issues since from a mathematicians perspective that's where a lot of the interesting stuff is happening (and for other analogs we care about like topological entropy which really stretches the use of the word). Thanks, that helped a lot.
The above was classical Thermodynamics and this is how it is usually introduced in Chemistry classes; Underneath that is Statistical Mechanics.

TomS · 19 February 2010

Mike Elzinga said: The second law of thermodynamics is NOT about order. Entropy is NOT about order.
The Noah's Flood people have told us that the arrangement of the fossils is due to something like "hydrodynamic sorting" in the Flood. They recognize that order can come from disorder. At least, they recognize that when it serves their purposes. But the creationists go beyond confusing the terms of thermodynamics with "order" and "disorder". They also switch between "order" and "information" and "complexity" and who-knows-what-else as it serves their purposes. Consider a completely uniform state and a completely chaotic state: which has the most entropy, probability, order, information, and complexity?

TomS · 19 February 2010

Ryan Cunningham said:
Phillip Moon said: As a rule, when I see this argument used, the IDiot tends to simply state that complexity can not come from simplicity. It violates the 2nd law. Have any of these people been to a child birthing? From a single sperm and a single egg we get babies. That's about as complicated as any 747.
I use the EXACT same argument. "Wait. Don't all your arguments apply equally well to development? Are you arguing that the second law forbids a single cell to grow into a person?"
A great many of the creationist arguments against evolution apply with at least as much force against reproduction and development. So much so, that whenever I hear a creationist argument I automatically check whether it works just as well as an argument for Scientific Storkism (or the "Big Top" version that doesn't identify the Stork: "Intelligent Delivery").

Bob O'H · 19 February 2010

Of course we dont have a single example of non euclidean geometry existing, none physicists could detect.
Stand on the equator, and draw 2 parallel lines. Then extrapolate them, and they meet at the poles. The surface of a globe is an example of elliptical geometry.

Dan · 19 February 2010

Joshua Zelinsky said:

Dan said: The permutation issues arise only for the ideal gas and, as we all know, no gas is ideal.

As I understand it, the issue arises if one wants the approximate entropy of a near-ideal gas to actually behave asymptotically how it should. Indeed, the whole permutation thing comes in what amounts to the non-ideal case. In an ideal gas Boltzmann and Gibbs entropy agree. It is only in the non-ideal case that we care about permutations. Am I missing something here?
Well, I can't give you a whole stat mech course in a few paragraphs. I recommend the book by Dan Schroder. The upshot is that in the ideal case, ONLY permutations matter. In the real case, both permutations and the configuration integral matter.

Dan · 19 February 2010

Mike Elzinga said:
Joshua Zelinsky said: Mike, not exactly. From a mathematical perspective entropy really is deeply related to permutation issues. ...
Josh, Entropy refers to the number of energy microstates that are consistent with the macrostate of the system (its temperature, pressure, volume, magnetization, etc.) It is actually the logarithm of that number multiplied by Boltzmann’s constant(S = kB ln W, where W is the number of microstates). The enumeration of those states gets into the technical issues of counting, and that is often where the confusion starts because there are lots of individual cases one can play with. It also depends on whether one is considering a classical system or a quantum mechanical system. Then there are the issues of energy distributions, Boltzmann, Bose-Einstein, and Fermi-Dirac. But the form of that relationship (the logarithm along with Boltzmann’s constant) gives it a tight relationship to the absolute temperature of the system and the way that number of microstates changes with total energy. And it eventually all ties together with the older thermodynamic calculations. I don’t want to drive away people here.
I don't want to drive away people either, but I do want to add that the above treatment holds only for the microcanonical ensemble. For the canonical, grand canonical, and other ensembles different definitions apply. The formula correct for all ensembles is S = -k_B SUM p_i log p_i where p_i is the probability of occupying microstate i. And since ideality has come up, I want to remind everyone the Fermi-Dirac and Bose-Einstein statistics apply only to non-interacting particles.

Dan · 19 February 2010

Steve Morrison said: Krylov subspaces
Ahh yes! I did know about them, just not their name. I love all things related to the Jordan normal form.

eric · 19 February 2010

Mike Elzinga said: Every time I have encountered an ID/creationist and pointed out their problem with not only thermo, but other scientific concepts as well, it’s as though their entire nervous system shuts off... ...This is what I have seen for over 40 years now. I don’t know if it can be changed.
Once you're perceived to be attacking someone's deep-seated beliefs, the rational part of their mind shuts down and they start thinking emotionally. At that point rational arguments and scientific explanations lose their value to convince. To change this situation you have to do one of two things: make them believe, emotionally, that good science is worth giving up their religion. Or make them believe that good science /= refuting Jesus. Which you do depends on whether you fall into the PZ or Ken Miller camp. But I think the first step is recognizing that neither job is really a "science" job. To change fundamentalist minds we ultimately have to address the question of what science means for their religious faith. Which requires that we at least don a different hat, and frankly it may be better accomplished by leaving it to our mainstream theology colleagues. To try and be pithy, Popes count more than Paulings in this debate.

heddle · 19 February 2010

Mike Elzinga
I have been watching this shtick for over 40 years, and it is one of the most exasperating displays of gut-bustingly, determined stupidity imaginable. The second law of thermodynamics is NOT about order. Entropy is NOT about order.
Very true, but it would not change the misuse of the 2nd Law. Sewell would just say: There are fewer microstates available to the atoms and molecules when arranged in people than if they were, say, unbound, therefore the SLOT is violated. It is almost better that he not only misuses the law, but misuses it with incorrect language. TomS,
Consider a completely uniform state and a completely chaotic state: which has the most entropy, probability, order, information, and complexity?
Not enough information to say. In fact, if you are talking about two microstates states accessible to the same system, then it is more proper to say that they both contribute the same amount to the system’s entropy and they both have equal probability.

Dave Thomas · 19 February 2010

TomS said: A great many of the creationist arguments against evolution apply with at least as much force against reproduction and development. So much so, that whenever I hear a creationist argument I automatically check whether it works just as well as an argument for Scientific Storkism (or the "Big Top" version that doesn't identify the Stork: "Intelligent Delivery").
Indeedly! I recommend the related article Strengths and Weaknesses that we posted at NMSR back in 2008. Cheers, Dave

TomS · 19 February 2010

Dave Thomas said: Indeedly! I recommend the related article Strengths and Weaknesses that we posted at NMSR back in 2008. Cheers, Dave
Thank you. I have added your reference to the article on Scientific storkism at RationalWiki

Stuart Weinstein · 19 February 2010

Bob O'H said:
Of course we dont have a single example of non euclidean geometry existing, none physicists could detect.
Stand on the equator, and draw 2 parallel lines. Then extrapolate them, and they meet at the poles. The surface of a globe is an example of elliptical geometry.
There is that. But Eddington would have been surprised by the original claim.

raven · 19 February 2010

Nothing to add. I too have defied the Second Law of Thermodynamics by growing from a single cell to an adult. This would be more impressive if my cats hadn't been able to do the same thing.
The Discovery Institute Press has published a book by Granville Sewell,...
I'm surprised that the DI had the nerve or confusion to actually publish such an obviously stupid and wrong YEC argument. It does not do their credibility any good if they keep trying to pretend they are promoting science. My impression is that the DI is going back to pure YECism, xian Dominionism, and extreme fundie xianity. This is a recipe for being marginalized to the lunatic fringes, not that they aren't already well on the way there.

RodW · 19 February 2010

It seems to me the most influential IDers now are Meyer and Behe, and perhaps to a lesser extent Dembski and Berlinski. I'm fairly confident that if any of them were asked in a debate if the Second Law violates evolution they would without hesitation reply: "no it doesnt" ...... End of Discussion...we should not waste our time with crank arguements that the main IDers themselves wouldnt touch.

Donald Pabst · 19 February 2010

Flint said: The reason these thermodynamic arguments persist so long, and despite so much debunking, is probably simple: they're one of the few arguments where the creationist god is not an option, it is absolutely required, and evolution is either impossible and so didn't happen, or is impossible without the creationist god. For the average non-physicist creationist (and even for those who ARE physicists), the claim that their god MUST be involved, because evolution would defy fundamental laws without it, is obviously intoxicating. I think this is a sort of creationist version of physics envy.
To be fair, I think this misses the point.

Donald Pabst · 19 February 2010

raven said: Nothing to add. I too have defied the Second Law of Thermodynamics by growing from a single cell to an adult. This would be more impressive if my cats hadn't been able to do the same thing.
The Discovery Institute Press has published a book by Granville Sewell,...
I'm surprised that the DI had the nerve or confusion to actually publish such an obviously stupid and wrong YEC argument. It does not do their credibility any good if they keep trying to pretend they are promoting science. My impression is that the DI is going back to pure YECism, xian Dominionism, and extreme fundie xianity. This is a recipe for being marginalized to the lunatic fringes, not that they aren't already well on the way there.
As a former Scientist myself, I find it difficult that you guys misunderstand the Creation Science side of the argument. I might not agree with Biblical creationism, but I do happen to agree with some sort of Intelligent Design as a form of Natural Science, and don't think there is anything wrong with that as well.

Donald Pabst · 19 February 2010

RodW said: It seems to me the most influential IDers now are Meyer and Behe, and perhaps to a lesser extent Dembski and Berlinski. I'm fairly confident that if any of them were asked in a debate if the Second Law violates evolution they would without hesitation reply: "no it doesnt" ...... End of Discussion...we should not waste our time with crank arguements that the main IDers themselves wouldnt touch.
I think it does, and fellow university professors do as well.

Donald Pabst · 19 February 2010

I met Behe once and I have assisted other Intelligent Design Movement advocates in writing books. I have to say, Behe is an intelligent gentleman.

Donald Pabst · 19 February 2010

raven said: Nothing to add. I too have defied the Second Law of Thermodynamics by growing from a single cell to an adult. This would be more impressive if my cats hadn't been able to do the same thing.
The Discovery Institute Press has published a book by Granville Sewell,...
I'm surprised that the DI had the nerve or confusion to actually publish such an obviously stupid and wrong YEC argument. It does not do their credibility any good if they keep trying to pretend they are promoting science. My impression is that the DI is going back to pure YECism, xian Dominionism, and extreme fundie xianity. This is a recipe for being marginalized to the lunatic fringes, not that they aren't already well on the way there.
No....I think its worth notice that it might be something that Young Earth Creation Science has agreed with for some time now, but while that might be the case, we as Intelligent Design Movement advocates are trying to separate ourselves from the Young Earth Creation movement.

donald pabst · 19 February 2010

I honestly agree that Panspermia is more Scientific of an explanation than God did it.

Mike Elzinga · 19 February 2010

Dan said: I don't want to drive away people either, but I do want to add that the above treatment holds only for the microcanonical ensemble. For the canonical, grand canonical, and other ensembles different definitions apply. The formula correct for all ensembles is S = -k_B SUM p_i log p_i where p_i is the probability of occupying microstate i. And since ideality has come up, I want to remind everyone the Fermi-Dirac and Bose-Einstein statistics apply only to non-interacting particles.
When it comes to details such as this, I have tended to sweep this into a statement to the effect that this gets into some of the more technical aspects of statistical mechanics. Many years ago when I was giving talks addressing laypersons about these issues at the height of the creationist storm, I had the help of my wife and some others who were in the audience assessing the effects of my presentations. As a result of their feedback, I dropped every reference to math. I hated that, but it turned out to be the right thing to do, and my presentations improved and I began getting more invitations to speak. Ultimately I settled on “folksy” illustrations that were necessarily classical in their nature even though I and many of my colleagues knew these were not the entire picture. As you may know, any time one leaves out some arcane detail of science, ID/creationists, if they spot it, will jump on it as an argumentative point to show that they are “in the game” and that the scientist is not telling the whole truth. This presented me with a dilemma, because I knew that might happen from what I was observing in debates I had seen. Fortunately that didn’t happen during the time I was giving presentations, but I did have a backup strategy in case it did. It was, in effect, to commend such an accuser for his understanding, but that he should seek clarification of the details in a good textbook. This also ultimately stopped me from writing a short little folksy book about statistical mechanics and thermodynamics for the layperson because I couldn’t resolve in my own mind where to draw the line in folksy illustrations, that my colleagues would lambaste me for, and sufficient detail that would keep them at bay but still help laypeople’s understanding. I abandoned the idea and ultimately regretted it after I saw other small books coming out that were not only worse, but also didn’t address these conflations. How have your own experiences with laypeople been on this issue? It comes up only sporadically these days, so I don’t think there is much interest on the part of the public at the moment. Back when I was doing it, creationists were getting large multi-page spreads in the Sunday newspapers and many people in the various churches and in the general public were at least aware of the “crisis in science.”

raven · 19 February 2010

As a former Scientist myself... I do happen to agree with some sort of Intelligent Design as a form of Natural Science, and don’t think there is anything wrong with that as well.
Think you may have just contradicted yourself there. Scientist and Intelligent Design don't belong in the same sentence. Panspermia is a real scientific hypothesis. UFO aliensdidit or spores drifting in fron space. There are two problems with it. 1. Where did those UFO aliens or spores come from? Were they created by goddidit or did they....evolve? This just pushes the questions back a step or three. 2. Where is the data, evidence, proof for it? Evolution has 150 years of data, whole mountains of it with huge volumes of such being accumulated every year. We won't be teaching the kids the UFO aliensdidit theory very soon without any data whatsoever. I don't think the fundie xian Dominionists of the DI have been pushing very hard for that one either.
we as Intelligent Design Movement advocates are trying to separate ourselves from the Young Earth Creation movement.
And failing completely. Just crossing out creation and substituting Intelligent Design and crossing out god and substituting Intelligent Designer didn't work. And the DI is going more towards xian Dominionist YEC. The ones I've dealt with are hardcore fundies who know zero science and babble on compulsively about god and jesus and flat out told me that I and all the evolutionists better repent before we end up in hell. That isn't science. It isn't even common xianity.

eric · 19 February 2010

Donald Pabst said:
RodW said: I'm fairly confident that if any of them [Behe etc...] were asked in a debate if the Second Law violates evolution they would without hesitation reply: "no it doesnt" [quote snipped]
I think it does, and fellow university professors do as well.
Could you expand on that? Address how you think intelligent agencies can violate 2LOT? I forsee many applications if you can show me how its done.

Stanton · 19 February 2010

Donald Pabst said: As a former Scientist myself, I find it difficult that you guys misunderstand the Creation Science side of the argument. I might not agree with Biblical creationism, but I do happen to agree with some sort of Intelligent Design as a form of Natural Science, and don't think there is anything wrong with that as well.
Can you explain how saying that an Intelligent Designer, whom the staff at the Discovery Institute unsubtly hint at being God, as described in the Bible, designed life using methods that scientists will never understand, is science?

phantomreader42 · 19 February 2010

raven said:
As a former Scientist myself... I do happen to agree with some sort of Intelligent Design as a form of Natural Science, and don’t think there is anything wrong with that as well.
Think you may have just contradicted yourself there. Scientist and Intelligent Design don't belong in the same sentence.
Well, he did say he was a FORMER scientist. So thank you, Donald Pabst, for admitting that you have abandoned science, and that ID is not, never has been, and never will be science.

Henry J · 19 February 2010

I might not agree with Biblical creationism, but I do happen to agree with some sort of Intelligent Design as a form of Natural Science, and don’t think there is anything wrong with that as well.

What is wrong with ID as science is that the concept doesn't explain anything. Evolution on the other hand explains matching nested hierarchies constructed from anatomy and DNA, geographic clustering of related species, fossil series, the existence of intermediates, and observations of short term evolution. Those things follow as a logical consequence of the theory, and none of them follow as a logical consequence of "something deliberately engineered some aspect of life as we know it". Henry

william e emba · 19 February 2010

I recall seeing Sewell's book on numerical solutions to ODES/PDES, browsed through it, thinking maybe I wanted a copy, and then I noticed there was an Appendix D: Can "ANYTHING" Happen in an Open System?. He briefly says to apply the book's theorem X for yourself to living systems, and you'll have a clearcut disproof of evolution.

Golly, he couldn't bother writing it out. Needless to say, I did not buy it. I later realized I recognized his name. Springer-Verlag had published his mathematical diatribe against evolution in "The Mathematical Intelligencer" (the article is on Sewell's webpage). It was garbage.

eric · 19 February 2010

william e emba said: He briefly says to apply the book's theorem X for yourself to living systems, and you'll have a clearcut disproof of evolution.
I have no idea what theorem X is but applying thermodynamics to living systems at the most general level is quite easy: food in, poop out, the difference in usable chemical work is orders of magnitude more than you need to alter a nucleotide sequence in reproductive cells. It had better be: it has to be enough energy for the billions of other cells in the body to function.

Joe Felsenstein · 19 February 2010

Henry J said: What is wrong with ID as science is that the concept doesn't explain anything.
But there are ID arguments that are science. Those are the negative arguments about evolutionary biology not being able to explain phenomenon X. For example, the argument that evolution violates the Second Law of Thermodynamics is a scientific argument. It's a wrong scientific argument, but a scientific argument nonetheless. If Donald Pabst wants to make a sensible contribution here, he could explain what scientific argument persuades him that the SLOT makes evolution impossible.

Mike Elzinga · 19 February 2010

Dan said: The formula correct for all ensembles is S = -k_B SUM p_i log p_i where p_i is the probability of occupying microstate i.
Elaborating a bit more on my last reply. When I was advised to kick the math out of my talks, probability was one of the prime sources of confusion. Everything I said after that word was simply lost. I argued and resisted taking out the math and lost the argument because, as it ultimately turned out, I was wrong. That did make me realize, however, that it was far more effective to keep the classical notions of accounting for energy and to simply suggest with those classical folksy illustrations various ways energy is stored inside a working medium. I think the key for lay audiences lies in the bookkeeping examples. But the real issue is why matter condenses; and it is no coincidence that the subfield of condensed matter physics is call that instead of just solid state physics. So here again we are up against teaching basic physics concepts to laypersons without the use of math. Generally the bookkeeping of energy seems to be the best approach, but now we talk about kinetic energy, potential energy, total energy and falling into wells and staying in the wells instead of bouncing back out. I got very satisfying feedback on my presentations and lecture series; so at least on a local level, I and others seemed to help. Looking at the more global picture however, I felt we hardly made a dent, and that public understanding of science was getting worse overall. My biggest regret is my early ignorance or naiveté of the political nature of ID/creationism; and then after becoming aware, my total underestimation of the unchristian ruthlessness of ID/creationist tactics.

Just Bob · 19 February 2010

Donald Pabst said: As a former Scientist myself, I find it difficult that you guys misunderstand the Creation Science side of the argument. I might not agree with Biblical creationism, but I do happen to agree with some sort of Intelligent Design as a form of Natural Science, and don't think there is anything wrong with that as well.
Curious. What sort of scientist, even former, thinks 'Scientist' should be capitalized? Or 'Creation Science'? Is there a formal organization by that name? And if so, are you referring to it, or to the nebulous field of "creation science"? And Natural Science...is that a club too? Can I join? Even 'Intelligent Design,' in that sentence, is clearly not a proper noun. Seems to me a (former) scientist should have a little better mastery of SEE (standard edited English).

Henry J · 19 February 2010

But there are ID arguments that are science. Those are the negative arguments about evolutionary biology not being able to explain phenomenon X.

But that's not an attempt to provide an explanation; that's an attempt to reduce confidence in an already existing explanation. Besides, even if they did somehow "prove" that known processes were insufficient to account for known species, all that would prove is that there's an unknown process. To actually support "ID", one would need to show some consistently observed pattern that would be a logical consequence of some version of "life was engineered", but that wouldn't be expected otherwise. Henry

AnswersInGenitals · 19 February 2010

Violating the Second Law of Thermodynamics, as Sewell understands it, is as simple as pie. Or at least as easy as baking a cake. The classical definition of change in Entropy S for a change in the state of a substance that happens at temperature T and requires a heat input of Q is that S ==Q/T (where '==' is used to mean "defined as", not just equal to). The second law then states that if the substance is in a closed system with no other influences on it other than that heat input, then S is always positive, i. e., the entropy of the substance can only increase.

So, let's bake a cake. This requires heat input at a certain temperature, which is why we put the batter in the oven set at 350 degrees fahrenheit. The liquid batter changes into the solid cake greatly increasing its order (Creationists and IDers always like to use the example of adding heat to ordered solid ice to melt it into disordered liquid water, or to somewhat disordered water to produce highly disordered gaseous steam, both of which processes involve an increase in thermodynamic entropy, to show that entropy increases always lead to greater disorder.) Damn, Entropy increases and order increases - It obviously must be a Devil's food cake.

Joe Felsenstein · 19 February 2010

Henry J said: (in response to my statement that)

But there are ID arguments that are science. Those are the negative arguments about evolutionary biology not being able to explain phenomenon X.

But that's not an attempt to provide an explanation; that's an attempt to reduce confidence in an already existing explanation. Besides, even if they did somehow "prove" that known processes were insufficient to account for known species, all that would prove is that there's an unknown process. To actually support "ID", one would need to show some consistently observed pattern that would be a logical consequence of some version of "life was engineered", but that wouldn't be expected otherwise.
ID advocates and creationists make these negative arguments (typically they have no positive arguments). They are quick to point to blanket statements that what they are doing “isn't science” as evidence that we aren't able to deal with these (negative) arguments honestly. They are particularly effective when they can juxtapose statements that “ID isn't science” with statements that experiments can be done that refute ID. Making the distinction between their (nonexistent and thus nonscientific) positive arguments, and their scientific-but-wrong negative arguments seems to be essential if evolutionary biology wants to win these arguments.

Eric Finn · 19 February 2010

Mike Elzinga said: But the real issue is why matter condenses; and it is no coincidence that the subfield of condensed matter physics is call that instead of just solid state physics. So here again we are up against teaching basic physics concepts to laypersons without the use of math. Generally the bookkeeping of energy seems to be the best approach, but now we talk about kinetic energy, potential energy, total energy and falling into wells and staying in the wells instead of bouncing back out. I got very satisfying feedback on my presentations and lecture series; so at least on a local level, I and others seemed to help.
What is required, if a ball ends up on the bottom of a well, instead of bouncing back? What is required to change the orbit of a planet from highly elliptical to almost circular? What is required for matter to condense? What is required for atoms to build molecules? What is required for molecules to form even bigger molecules? You have diligently explained these every-day observations based on the current understanding in physics. Let me give you a little feedback. You may then decide, how well you have performed. I will make four statements for you to evaluate. (1) A common requirement to the above phenomena is that the system in question can dissipate energy. (2) Dissipative processes are covered by the second law of thermodynamics. (3) The second law of thermodynamics is in agreement with the forming of complex structures in a system, provided there is energy available AND there is a way to dissipate some of the said energy outside of the system we are discussing. (4) Structures formed by elementary particles, atoms or molecules may change without any disagreement with the second law of thermodynamics, provided there is a flow of energy through the structure. Maybe as a fifth statement one might add that there are numerous experimental observations on matter forming these kind of structures, and quite rigorous mathematical models to predict the features in those structures.

harold · 19 February 2010

Mike Elzinga -

I just want to note one thing with respect to the excellent discussion of thermodynamics here.

As I tried to articulate in my first comment, and as has come up a couple of times again in the thread, the creationist line of argument here is not only wrong but also self-contradictory (a common combination).

The creationist argument from thermodynamics cannot possibly be right, as reproduction and development of life would also be impossible if it were. Not only is it wrong, but it is not even specific to biological evolution either. It actually argues against all sorts of things that even creationists don't deny.

(The first time I saw a creationist make a thermodynamics argument, I told him that I possessed some high tech devices that could violate 2LOT as he understood it, namely an ice cube tray and a freezer.)

Flint -

Yes, it is true that "proving 'by logic' that evolution must be impossible despite all the evidence" is always popular among creationists. That is because this tactic is compatible with both laziness and avoidance of cognitive dissonance. By not actually bothering to even address biology, they get to avoid both the hard work of studying and the discomfort of seeing any actual evidence for biological evolution.

Of course, certain types, like Luskin and Wells, are actually capable of going through the motions of getting degrees in biology, solely to claim the credentials in service of their science-denying agenda. But not everyone is cut out for that intense a level of deception of self and others, and cognitive dissonance.

Mike Elzinga · 19 February 2010

Eric Finn said: Let me give you a little feedback. You may then decide, how well you have performed. I will make four statements for you to evaluate.
Eric, You appear to have the basic structure in place. The actual mechanisms of energy dissipation (photons, phonons, other particles) are going to be involved. But as you dig deeper, you will also confront the issues like, say, “Where did those photons come from when two neutral atoms or molecules interacted?” You could take the leap to quantum electrodynamics, but I don’t think that would help the layperson. So you will need to explore some classical models of what actually happens with the distributions of electrons around those atoms or molecules as two or more of them come into each other’s close proximity. We know what happens when electrical charge distributions are “sloshed around.” And we also know that atoms and molecules all have characteristic electromagnetic signatures throughout the electromagnetic spectrum and well into the infrared and microwave regions. But you will very likely have to leave behind quantum mechanics and only refer to it as producing refinements on your model. If anyone doubts that photons are coming off freezing lead or iron as it cools, you can take them down to your “local foundry” and stand next to a crucible of molten metal. And, of course, anyone can experiment with all the phases of water. This is stuff kids should be taught anyway.

Arthur Hunta · 19 February 2010

Sewell (in The American Spectator):
It is a well-known prediction of the second law that, in a closed system, every type of order is unstable and must eventually decrease, as everything tends toward more probable states. Not only will carbon and temperature distributions become more disordered (more uniform), but the performance of all electronic devices will deteriorate, not improve. Natural forces, such as corrosion, erosion, fire and explosions, do not create order, they destroy it. The second law is all about probability, it uses probability at the microscopic level to predict macroscopic change: the reason carbon distributes itself more and more uniformly in an insulated solid is, that is what the laws of probability predict when diffusion alone is operative.
Think about this the next time you shake up a few trillion trillion molecules of salad oil and water. Think about the bolded statements in particular, and stare in amazement as these bajillions of molecules assemble into a perfectly ordered system, one set of molecules choosing the top of the vessel and the other the bottom. Sewell in essence is saying that your eyes are playing tricks on you, that oil and water in fact do not spontaneously, in a totally isolated system, separate. For more giggles, try and estimate the probability that this collection of molecules can sort themselves so completely, so that they do not mix at all. But of course, don't try this is you are convinced that such a violation of the SLOT will mean the demise of existence. At least, wait until Monday, so that you can squeeze in one last weekend.

Mike Elzinga · 19 February 2010

harold said: The creationist argument from thermodynamics cannot possibly be right, as reproduction and development of life would also be impossible if it were. Not only is it wrong, but it is not even specific to biological evolution either. It actually argues against all sorts of things that even creationists don't deny.
Indeed, if they were consistent in their arguments, it would be easy to find lots of examples. They don’t seem to care about inconsistency if it means they don’t have to give up dogma. I think their argument about the freezer would be that it is intelligently designed. One of the consistent patterns I have noticed about their arguments claiming “the second law says everything falls apart” is their emphasis on death and decay (I can only guess at the psychological implications of that). Somewhere along the line they want life, humans in particular, to have “bucked the 2nd law.” So the impression I sometimes get is that they will argue that the 2nd law applies to the inanimate world, but not to life; hence, entropy barriers. Of course, I wouldn’t be able to resist asking what this eating, defecating, and breathing are all about. Early on, when I got feisty, I had a characterization that captured the essence of Gish’s creationist arguments; namely, if you put a mouse in a thermos bottle, seal it up and put in on a shelf for a few million years, when you finally open it up, a cat won’t come out.

Ichthyic · 20 February 2010

They are particularly effective when they can juxtapose statements that "ID isn't science" with statements that experiments can be done that refute ID.

no. the experiments disproving ID are innumerable in the literature already.

by using their very own terminology/approach, each and every successful test of a hypothesis regarding evolutionary theory is a disproof of ID.

Joe, you're being suckered.

ID cannot even formulate a testable hypothesis without evidence of how a purported designer can and DOES operate within the natural world.

It simply is insufficient to formulate a logical construct, call it a "hypothesis", and say that it's testable.

again, there simply is no real world evidence whatsoever to utilize to even begin to formulate a testable hypothesis regarding intelligent design.

again, and I've said this before, you seem easily suckered by their logical arguments that have nothing to do at all with real world testability.

Joe Felsenstein · 20 February 2010

Ichthyic said:
[I had said:] They are particularly effective when they can juxtapose statements that "ID isn't science" with statements that experiments can be done that refute ID.
no. the experiments disproving ID are innumerable in the literature already. by using their very own terminology/approach, each and every successful test of a hypothesis regarding evolutionary theory is a disproof of ID. Joe, you're being suckered. ID cannot even formulate a testable hypothesis without evidence of how a purported designer can and DOES operate within the natural world. It simply is insufficient to formulate a logical construct, call it a "hypothesis", and say that it's testable. again, there simply is no real world evidence whatsoever to utilize to even begin to formulate a testable hypothesis regarding intelligent design. again, and I've said this before, you seem easily suckered by their logical arguments that have nothing to do at all with real world testability.
There is some disconnect here. I am not saying that they can formulate any testable hypotheses. They find statements by evolutionary biologists that ID isn't science, that it does not make any testable predictions. Then they find statements by biologists, sometimes even the same biologists, that say that one can test ID and reject it. They then make fun of the obvious contradiction. What one can do is take negative arguments by ID advocates, and test them. Those negative arguments (about how it is impossible for evolution to do X or to do Y) are scientific arguments, and they can be tested. And they are commonly rejected. The statements that they make that you are referring to that need information about the motives, means, and opportunity of the Designer, are the positive claims of ID as to what Design has done. Those are not testable. We have to make this distinction. You aren't making it.

henry · 20 February 2010

AnswersInGenitals said: Violating the Second Law of Thermodynamics, as Sewell understands it, is as simple as pie. Or at least as easy as baking a cake. The classical definition of change in Entropy S for a change in the state of a substance that happens at temperature T and requires a heat input of Q is that S ==Q/T (where '==' is used to mean "defined as", not just equal to). The second law then states that if the substance is in a closed system with no other influences on it other than that heat input, then S is always positive, i. e., the entropy of the substance can only increase. So, let's bake a cake. This requires heat input at a certain temperature, which is why we put the batter in the oven set at 350 degrees fahrenheit. The liquid batter changes into the solid cake greatly increasing its order (Creationists and IDers always like to use the example of adding heat to ordered solid ice to melt it into disordered liquid water, or to somewhat disordered water to produce highly disordered gaseous steam, both of which processes involve an increase in thermodynamic entropy, to show that entropy increases always lead to greater disorder.) Damn, Entropy increases and order increases - It obviously must be a Devil's food cake.
The answer is in the genitals. The sperm and egg form the embryo which grows to an adult, according to its genetic code, which includes the capacity to reproduce and the next generation continues. Since most of us will not live to 100, we'll succumb to the 2nd Law eventually.

raven · 20 February 2010

Since most of us will not live to 100, we’ll succumb to the 2nd Law eventually.
According to one way of looking at life, we are just DNA's way of reproducing itself and spreading. The DNA of myself and my cats have been doing this for 3.7 billion years. We are tough, competent, lucky survivors of a chain stretching back a long ways. It won't last forever but it could easily last billions of more years. The galaxy appears to be empty right now. We could spread out and own it all if we want.

Ron Okimoto · 20 February 2010

phantomreader42 said:
raven said:
As a former Scientist myself... I do happen to agree with some sort of Intelligent Design as a form of Natural Science, and don’t think there is anything wrong with that as well.
Think you may have just contradicted yourself there. Scientist and Intelligent Design don't belong in the same sentence.
Well, he did say he was a FORMER scientist. So thank you, Donald Pabst, for admitting that you have abandoned science, and that ID is not, never has been, and never will be science.
It has to be difficult to claim to support intelligent design when the main guys that perpetrated the creationist scam ran and are running a bait and switch scam on their own creationist supporters. Instead of getting any ID science all the rubes have ever gotten is an obfuscation scam that doesn't even mention that ID ever existed. To bend over and take the switch scam from the same guys that lied to you about ID has to take a special person. But I read something else into what he wrote. He may not adhere to the creationist scam arguments. He may just think that the issue of some type of intelligent interference in the evolution of life on earth may have happened. If he hasn't given up on science that is as far as he can go. It is a question that you can think about, but it just hasn't made the grade. It never amounted to anything ever in science. If he can't acknowledge that he would be in the creationist camp even if he doesn't understand that himself. There are likely some serious researchers thinking about this problem, they just aren't associated with scam outfits like the Discovery Institute. They would be the guys that haven't given up and are quietly searching for something that would make their notions scientifically viable. We haven't heard much about these guys because they have enough on the ball to understand that they aren't there, yet, and are willing to wait until they do have something to talk about before putting their ideas forward.

Ron Okimoto · 20 February 2010

raven said:
Since most of us will not live to 100, we’ll succumb to the 2nd Law eventually.
According to one way of looking at life, we are just DNA's way of reproducing itself and spreading. The DNA of myself and my cats have been doing this for 3.7 billion years. We are tough, competent, lucky survivors of a chain stretching back a long ways. It won't last forever but it could easily last billions of more years. The galaxy appears to be empty right now. We could spread out and own it all if we want.
How long will Henrietta Lacks' DNA keep replicating (HeLa cell culture)? Is she immortal?

TomS · 20 February 2010

Joe Felsenstein said: The statements that they make that you are referring to that need information about the motives, means, and opportunity of the Designer, are the positive claims of ID as to what Design has done. Those are not testable.
But the point is that the advocates of ID have no positive claims about what "design" has done. Or what it has not done. Or what it can or cannot do. And as to their "scientific" claims about what evolution cannot do: Yes, I agree that we can evaluate those claims. But we can also point out that they are not able to make the corresponding affirmative claim: That ID can do it, much less did do it. (Except in the trivial sense that ID can do anything, as well as its opposite.)

harold · 20 February 2010

Mike Elzinga -

You are entirely right about how a modern, "sophisticated" creationist would respond to the ice cube tray example.

Although the exchange in question took place since the invention of ID (*I actually wasn't really involved with creationists before about 1999*), it took place in the pre-Dover environment, when many "amateurs" were still active. That particular person merely responded by not using any more thermodynamics arguments when addressing me.

I'm sure he did use them when addressing others. As we all know, the implied logical objective of the creationist is to "win" each individual exchange, and "truth" is implicitly "whatever the 'winner' can force the other guy to admit". Arguments are not intended to be "true" or "false" in the way we understand the terms, but as tactics.

Just Bob · 20 February 2010

henry said: Since most of us will not live to 100, we'll succumb to the 2nd Law eventually.
Umm... but a FEW of us WILL live to 100! So we won't have to succumb to the 2nd Law? Forgive me for literally interpreting your words.

Frank J · 20 February 2010

Now the statement that evolution can’t have occurred because it contradicts the Second Law is one of the hoariest old creationist myths. When you hear it you know you are dealing either with someone who does not understand science, or else someone who does understand science but is actively, and dishonestly, trying to get you not to understand science.

— Joe Felsenstein
Thank you!!! When critics of ID/creationism accuse anti-evolution activists of not understanding science, they almost never mention the possibility that they do understand the science, but deliberately misrepresent it to suit their radical agenda. Yet omitting that possibility gives the activists just what they want. Which to make casual nonscientist readers conclude either (1) that the activists do understand science, and that we're the clueless ones, or (2) that the activists are honestly mistaken and that we're the bad guys for ridiculing them.

John Kwok · 20 February 2010

Now that you mention it Donald, could you explain to us how Intelligent Design creationism makes valid scientific predictions that would be far more robust - statistically speaking - than those made by the Modern Synthesis Theory of Evolution? I know Stephen Meyer has tried to do just that in his recently published mendacious intellectual pornography (Something to the effect that one could test scientifically for "deviations" from a "perfect" Design.), but it's rhetorical BS and, moreover, BS that can't be subjected to any rigorous scientific scrutiny:
Donald Pabst said:
raven said: Nothing to add. I too have defied the Second Law of Thermodynamics by growing from a single cell to an adult. This would be more impressive if my cats hadn't been able to do the same thing.
The Discovery Institute Press has published a book by Granville Sewell,...
I'm surprised that the DI had the nerve or confusion to actually publish such an obviously stupid and wrong YEC argument. It does not do their credibility any good if they keep trying to pretend they are promoting science. My impression is that the DI is going back to pure YECism, xian Dominionism, and extreme fundie xianity. This is a recipe for being marginalized to the lunatic fringes, not that they aren't already well on the way there.
As a former Scientist myself, I find it difficult that you guys misunderstand the Creation Science side of the argument. I might not agree with Biblical creationism, but I do happen to agree with some sort of Intelligent Design as a form of Natural Science, and don't think there is anything wrong with that as well.

John Kwok · 20 February 2010

Well said, Joe. Should remind Ichthyic that Ken Miller has opted to take ID creo claims seriously in his book "Only A Theory: Evolution and the Battle for America's Soul" and does a superb job in demolishing each and every one. We need to demonstrate how and why ID is bad science, instead of coming across as sanctimonious jerks who think we know it all simply because we are trained in recognizing what is - and what isn't - valid science.
Joe Felsenstein said:
Ichthyic said:
[I had said:] They are particularly effective when they can juxtapose statements that "ID isn't science" with statements that experiments can be done that refute ID.
no. the experiments disproving ID are innumerable in the literature already. by using their very own terminology/approach, each and every successful test of a hypothesis regarding evolutionary theory is a disproof of ID. Joe, you're being suckered. ID cannot even formulate a testable hypothesis without evidence of how a purported designer can and DOES operate within the natural world. It simply is insufficient to formulate a logical construct, call it a "hypothesis", and say that it's testable. again, there simply is no real world evidence whatsoever to utilize to even begin to formulate a testable hypothesis regarding intelligent design. again, and I've said this before, you seem easily suckered by their logical arguments that have nothing to do at all with real world testability.
There is some disconnect here. I am not saying that they can formulate any testable hypotheses. They find statements by evolutionary biologists that ID isn't science, that it does not make any testable predictions. Then they find statements by biologists, sometimes even the same biologists, that say that one can test ID and reject it. They then make fun of the obvious contradiction. What one can do is take negative arguments by ID advocates, and test them. Those negative arguments (about how it is impossible for evolution to do X or to do Y) are scientific arguments, and they can be tested. And they are commonly rejected. The statements that they make that you are referring to that need information about the motives, means, and opportunity of the Designer, are the positive claims of ID as to what Design has done. Those are not testable. We have to make this distinction. You aren't making it.

Joe Felsenstein · 20 February 2010

TomS said:
Joe Felsenstein said: The statements that they make that you are referring to that need information about the motives, means, and opportunity of the Designer, are the positive claims of ID as to what Design has done. Those are not testable.
But the point is that the advocates of ID have no positive claims about what "design" has done. Or what it has not done. Or what it can or cannot do. And as to their "scientific" claims about what evolution cannot do: Yes, I agree that we can evaluate those claims. But we can also point out that they are not able to make the corresponding affirmative claim: That ID can do it, much less did do it. (Except in the trivial sense that ID can do anything, as well as its opposite.)
Well, they do have a positive claim, that ID can explain the biological world as we see it. But they offer no details. They cannot offer details without losing their “big tent” which includes both Young Earth Creationists and people like Michael Behe who allow deep time and common descent as well as an unspecified number of instances of design. So I say they have a positive claim, and you say they don't, but we're not really disagreeing. They have no positive claim that's a scientific hypothesis.

Scott · 20 February 2010

Arthur Hunta said: Think about this the next time you shake up a few trillion trillion molecules of salad oil and water. Think about the bolded statements in particular, and stare in amazement as these bajillions of molecules assemble into a perfectly ordered system, one set of molecules choosing the top of the vessel and the other the bottom.
That brings up an interesting question. When one talks about 2LOT and a "closed" system, must that system be closed wrt all forms of energy, or just "heat" energy? In this experiment the oil and water separate (become "ordered") in the presence of a gravitational (acceleration) gradient. The two would not tend to separate in orbit, for example (at least in that way). So, is the stoppered, insulated flask "closed" in the 2LOT sense when in a gravity well? The rest of you: quit apologizing for trying to educate others. :-) Think about your audience. Do you think a bit of real math is going to chase away the PT lurkers? Where else can I find mathematicians arguing with physicists in language I can understand? Makes me want to go back to college.

ckc (not kc) · 20 February 2010

How long will Henrietta Lacks' DNA keep replicating (HeLa cell culture)? Is she immortal?
Actually, it's her parents DNA - she just borrowed it

Frank J · 20 February 2010

So I say they have a positive claim, and you say they don’t, but we’re not really disagreeing. They have no positive claim that’s a scientific hypothesis.

— Joe Felsenstein
More important that quibbling over whether what the ID strategy has can be called "positive claims," is the fact it has far fewer of them than either YEC or OEC in terms of testable claims regarding "what happened when." If the anti-evolution movement is supposed to be science it's going in exactly the wrong direction.

Kevin B · 20 February 2010

Scott said: That brings up an interesting question. When one talks about 2LOT and a "closed" system, must that system be closed wrt all forms of energy, or just "heat" energy? In this experiment the oil and water separate (become "ordered") in the presence of a gravitational (acceleration) gradient. The two would not tend to separate in orbit, for example (at least in that way). So, is the stoppered, insulated flask "closed" in the 2LOT sense when in a gravity well?
That's not really a very helpful way of looking at it. The oil and water separate because the total potential energy of the arrangement where the denser water is below the oil is less than that of the mixed oil and water. Because the mixture is mobile and able to separate out, it does so. The "left-over" potential energy is converted into the kinetic energy of the constituents in motion, and finally the "excess" energy is converted into heat. Although it would normally be assumed that the motion of the Earth resulting from the mass of the oil and water is small enough to be ignored, nevertheless it is there; if the cause of the gravitational field is external to the boundary of the system being considered, that system cannot be "closed". And the 2LOT is about "energy" not "heat energy".

SWT · 20 February 2010

Kevin B said:
Scott said: That brings up an interesting question. When one talks about 2LOT and a "closed" system, must that system be closed wrt all forms of energy, or just "heat" energy? In this experiment the oil and water separate (become "ordered") in the presence of a gravitational (acceleration) gradient. The two would not tend to separate in orbit, for example (at least in that way). So, is the stoppered, insulated flask "closed" in the 2LOT sense when in a gravity well?
That's not really a very helpful way of looking at it. The oil and water separate because the total potential energy of the arrangement where the denser water is below the oil is less than that of the mixed oil and water. Because the mixture is mobile and able to separate out, it does so. The "left-over" potential energy is converted into the kinetic energy of the constituents in motion, and finally the "excess" energy is converted into heat. Although it would normally be assumed that the motion of the Earth resulting from the mass of the oil and water is small enough to be ignored, nevertheless it is there; if the cause of the gravitational field is external to the boundary of the system being considered, that system cannot be "closed". And the 2LOT is about "energy" not "heat energy".
The oil and water will spontaneously separate regardless of the presence of the gravitational field -- the free energy of the system is minimized when the interfacial area is minimized, which means that the dispersed phase will eventually coalesce regardless of whether a gravitational field is acting on the system. FWIW, when I teach thermodynamics. I distinguish between a closed system (no flows of matter in or out) and an isolated system (no flows of matter or energy in or out). Work done by gravity would count as energy added to the system, but the magnitude of the gravitational effect is often negligible in the engineering thermodynamic calculations involved in my work.

Mike Elzinga · 20 February 2010

Scott said:
Arthur Hunta said: Think about this the next time you shake up a few trillion trillion molecules of salad oil and water. Think about the bolded statements in particular, and stare in amazement as these bajillions of molecules assemble into a perfectly ordered system, one set of molecules choosing the top of the vessel and the other the bottom.
That brings up an interesting question. When one talks about 2LOT and a "closed" system, must that system be closed wrt all forms of energy, or just "heat" energy? In this experiment the oil and water separate (become "ordered") in the presence of a gravitational (acceleration) gradient. The two would not tend to separate in orbit, for example (at least in that way). So, is the stoppered, insulated flask "closed" in the 2LOT sense when in a gravity well?
Actually it's a bit more complicated than that. It depends on whether or not the inter and intramolecular interactions are larger than the gravitational gradient. In the Earth's gravitational field, they are quite probably much larger depending on the types of molecules in the liquids. If the molecules in the oil are hydrophobic, the attractions among the oil molecules will be greater than they are between the oil and the water. The oil will pull itself into spherical shapes that minimize the surface potential energy of the spheres. On the other hand, if the substance in hydrophilic, they won't separate because the attractions between the substance and the water are greater than the attractions among the substance molecules. But I can hardly scratch the surface of this topic here. The possibilities are virtually endless; and this is precisely why the study of condensed matter is so important and so relevant to the misconceptions of the ID/creationists. This is such a rich field to explore, that there are endless examples of why "spontaneous molecular chaos" is such a stupid pseudo-science misconception. Nobody who has even shacken a salad dressing should come up with such conceptions. For the entire time I have been observing them, ID/creationists appear to be making extreme efforts to become the dumbest rocks in the universe.

fnxtr · 20 February 2010

surface tension and hydrogen bonds?

RBH · 21 February 2010

This is the 'positive' ID claim:
Sometime or other, some intelligent agent(s) designed something, and then somehow manufactured that thing, all the while leaving no independent evidence of the design process or the manufacturing process, and no independent evidence of the presence or even the existence of the designing and manufacturing agent(s).
Test that, science man!

Paul Burnett · 21 February 2010

RBH said: This is the 'positive' ID claim:
Sometime or other, some intelligent agent(s) designed something, and then somehow manufactured that thing, all the while leaving no independent evidence of the design process or the manufacturing process, and no independent evidence of the presence or even the existence of the designing and manufacturing agent(s).
More easily summarized as "Lo, a miracle!"
Test that, science man!
And miracles, by definition, are not science - there's nothing to test.

Frank J · 21 February 2010

RBH said: This is the 'positive' ID claim:
Sometime or other, some intelligent agent(s) designed something, and then somehow manufactured that thing, all the while leaving no independent evidence of the design process or the manufacturing process, and no independent evidence of the presence or even the existence of the designing and manufacturing agent(s).
Test that, science man!
We don't need to connect no stinkin' dots.

TomS · 21 February 2010

Joe Felsenstein said: So I say they have a positive claim, and you say they don't, but we're not really disagreeing. They have no positive claim that's a scientific hypothesis.
I quite agree. I would say that they have a claim, in the sense of advertising: "new, improved".

MrrKAT · 21 February 2010

Two examples from me.

1)A Big ball of water (planet) cools in quite empty place of cold space. Entropy decreases, icy mountains grow up. (At least in my flask in freezer). Impossible ? Shouldn't mountains always decrease in corrupted ID/ICR world ? ;)

2) Complexity under sun-light. Mix sodium sulfate and aluminium sulfate with water and let crystallize. You'd get very complex
molecule [NaAl(SO4)2·12H2O or Na2SO4·Al2(SO4)3·24H2O]where there are up to 96 atoms.
Impossible in ID/ICR-world ?
In nature there are minerals alum-(Na), mendozite and tamarugite.(At least latter).
No DNA or info is needed for complexity increase.

Stuart Weinstein · 21 February 2010

MrrKAT said: Two examples from me. 1)A Big ball of water (planet) cools in quite empty place of cold space. Entropy decreases, icy mountains grow up. (At least in my flask in freezer). Impossible ? Shouldn't mountains always decrease in corrupted ID/ICR world ? ;) 2) Complexity under sun-light. Mix sodium sulfate and aluminium sulfate with water and let crystallize. You'd get very complex molecule [NaAl(SO4)2·12H2O or Na2SO4·Al2(SO4)3·24H2O]where there are up to 96 atoms. Impossible in ID/ICR-world ? In nature there are minerals alum-(Na), mendozite and tamarugite.(At least latter). No DNA or info is needed for complexity increase.
Uh oh. Now ya dun it. You mentioned "complexity"

John Kwok · 21 February 2010

It's for the very reason you noticed that ID has been referred to as "Madison Avenue advertising-styled Intelligent Design creationism":
TomS said:
Joe Felsenstein said: So I say they have a positive claim, and you say they don't, but we're not really disagreeing. They have no positive claim that's a scientific hypothesis.
I quite agree. I would say that they have a claim, in the sense of advertising: "new, improved".

henry · 21 February 2010

Just Bob said:
henry said: Since most of us will not live to 100, we'll succumb to the 2nd Law eventually.
Umm... but a FEW of us WILL live to 100! So we won't have to succumb to the 2nd Law? Forgive me for literally interpreting your words.
There is no living person who is 200 so we'll all succumb to the 2nd law.

henry · 21 February 2010

John Kwok said: It's for the very reason you noticed that ID has been referred to as "Madison Avenue advertising-styled Intelligent Design creationism":
TomS said:
Joe Felsenstein said: So I say they have a positive claim, and you say they don't, but we're not really disagreeing. They have no positive claim that's a scientific hypothesis.
I quite agree. I would say that they have a claim, in the sense of advertising: "new, improved".
By the way, here is what Gordon Wood on Ushistory.org stated on an online interview. 6th answer, may 8, 1999 american revolution His book, "The Radicalism of the American Revolution," won the Pulitzer Prize in 1991. shs I thought our founding fathers were deists. Did that carry over to the general population? Prof. Wood No. The leaders and most educated tended to be deists -- they saw God as the great mover and were doubtful of the divinity of Christ. But most people were devout Protestant believers. Deism is confined to the elite. Wood recognized the Christian nature of most of the people at the beginning of our nation, which continues even today but to a lesser degree.

Dave Luckett · 21 February 2010

henry's moved the goalposts. What a surprise.

He gave us the usual creo malarky, that the USA was founded as a Christian nation. It was pointed out to him that most of the Founders were deists, and mostly only nominally Christians, and that the founding documents not only made no specific reference to Christianity, but they forbade the State from favouring any religion.

Now here henry is again, telling us that most of the population were Protestant Christian, and that this means the same thing.

Only it doesn't. In 1776 the people of the United States were mostly Christians, true, and I believe that a simple majority were Protestants, but they founded an avowedly secular nation, not a Christian one. Part of the covenant that they made among themselves was that no creed would be a State creed, no church a State church, no-one favoured or disadvantaged by religious belief, and that in matters of religion the State would preserve an impartial neutrality.

The USA is not a Christian nation. It is a secular State, and all the maunderings and foolish antihistory of religious whackaloons like henry will not change the fact.

Alex H · 22 February 2010

henry said:
John Kwok said: It's for the very reason you noticed that ID has been referred to as "Madison Avenue advertising-styled Intelligent Design creationism":
TomS said:
Joe Felsenstein said: So I say they have a positive claim, and you say they don't, but we're not really disagreeing. They have no positive claim that's a scientific hypothesis.
I quite agree. I would say that they have a claim, in the sense of advertising: "new, improved".
By the way, here is what Gordon Wood on Ushistory.org stated on an online interview. 6th answer, may 8, 1999 american revolution His book, "The Radicalism of the American Revolution," won the Pulitzer Prize in 1991. shs I thought our founding fathers were deists. Did that carry over to the general population? Prof. Wood No. The leaders and most educated tended to be deists -- they saw God as the great mover and were doubtful of the divinity of Christ. But most people were devout Protestant believers. Deism is confined to the elite. Wood recognized the Christian nature of most of the people at the beginning of our nation, which continues even today but to a lesser degree.
Thank you, Lewis. That was short, yet completely irrelevant in the 21st Century.

Mike Elzinga · 22 February 2010

henry said: Since most of us will not live to 100, we'll succumb to the 2nd Law eventually.
What does “succumbing to the 2nd Law eventually” actually mean to you? And why eventually? What are we doing with the 2nd Law now?

Joe Felsenstein · 22 February 2010

RBH said: This is the 'positive' ID claim:
Sometime or other, some intelligent agent(s) designed something, and then somehow manufactured that thing, all the while leaving no independent evidence of the design process or the manufacturing process, and no independent evidence of the presence or even the existence of the designing and manufacturing agent(s).
Test that, science man!
I think that what needs to be discussed on this thread is
  1. Whether the negative claims of ID are science or can be dismissed as “not science”. We're in agreement about the not-science nature of the positive claims.
  2. Whether agreement has been reached about “order” and the Second Law.
But what should not be discussed here is whether the U.S. is a Christian Nation®. All that should go to the Bathroom Wall. I am but a humble Guest Contributor so I can't do that -- maybe someone else can. I will just add that PT has a problem with people feeding the trolls, just because they enjoy stomping on them so much -- the result is that lots of useful threads get disrupted.

Dan · 22 February 2010

henry said:
Just Bob said:
henry said: Since most of us will not live to 100, we'll succumb to the 2nd Law eventually.
Umm... but a FEW of us WILL live to 100! So we won't have to succumb to the 2nd Law? Forgive me for literally interpreting your words.
There is no living person who is 200 so we'll all succumb to the 2nd law.
1. The second law of thermodynamics holds at all times, not just at age 100 years or 200 years. 2. One does not "succumb" to the second law of thermodynamics any more than one "succumbs" to Newton's law of motion. Both of these laws just are true. 3. Living things do not violate the second law of thermodynamics, or any other law of physics.

Just Bob · 22 February 2010

henry said:
Just Bob said:
henry said: Since most of us will not live to 100, we'll succumb to the 2nd Law eventually.
Umm... but a FEW of us WILL live to 100! So we won't have to succumb to the 2nd Law? Forgive me for literally interpreting your words.
There is no living person who is 200 so we'll all succumb to the 2nd law.
Oh, now I get it: BECAUSE no humans live to 200, THAT'S WHY we succumb to the 2nd Law. So that means that if we could extend ANYONE's life to 200, then the 2nd Law would cease to operate, at least for people. Is that good biblical physics? Hey, wait a minute! Genesis has men (not women?) living to over 900! That means that in those days the 2nd Law wasn't in effect! Even long after the Fall, entropy WASN'T increasing. So when did it go into effect, and how do you know? Oh, and thanks for confirming that we can't take things that bible-thumpers say literally. They just make stuff up that they think sounds good. If it doesn't quite work, they just make something else up.

eric · 22 February 2010

Joe Felsenstein said: I think that what needs to be discussed on this thread is 1. Whether the negative claims of ID are science or can be dismissed as “not science”. We're in agreement about the not-science nature of the positive claims. 2. Whether agreement has been reached about "order" and the Second Law.
I think there's a much simpler response to Sewell's claim (well, other than the deserved "pbbbbbt"). Ask him to build a perpetual motion machine of the second kind. I mean seriously: if they think intelligent agents can violate the 2nd law, they could make gazillions patenting refrigerators which run on nothing except room heat.

TomS · 22 February 2010

I think there's a much simpler response to Sewell's claim (well, other than the deserved "pbbbbbt"). Ask him to build a perpetual motion machine of the second kind. I mean seriously: if they think intelligent agents can violate the 2nd law, they could make gazillions patenting refrigerators which run on nothing except room heat.
I quite agree. Far too often, arguments for "intelligent design" amount to an example of something which (supposedly) no designer that we have any knowledge of could do. How does an example of "no design" get accepted as an argument "for design"?

John Kwok · 22 February 2010

Obviously you missed what Wood said, since, I do recall that it was the American political elite - strongly influenced by the French and (especially) Scottish Enlightenment - which were responsible for both the Declaration of Independence and the United States Constitution (And henry, thanks. This is the first time an IDiot has quote-mined a college professor of mine.):
henry said:
John Kwok said: It's for the very reason you noticed that ID has been referred to as "Madison Avenue advertising-styled Intelligent Design creationism":
TomS said:
Joe Felsenstein said: So I say they have a positive claim, and you say they don't, but we're not really disagreeing. They have no positive claim that's a scientific hypothesis.
I quite agree. I would say that they have a claim, in the sense of advertising: "new, improved".
By the way, here is what Gordon Wood on Ushistory.org stated on an online interview. 6th answer, may 8, 1999 american revolution His book, "The Radicalism of the American Revolution," won the Pulitzer Prize in 1991. shs I thought our founding fathers were deists. Did that carry over to the general population? Prof. Wood No. The leaders and most educated tended to be deists -- they saw God as the great mover and were doubtful of the divinity of Christ. But most people were devout Protestant believers. Deism is confined to the elite. Wood recognized the Christian nature of most of the people at the beginning of our nation, which continues even today but to a lesser degree.

John Kwok · 22 February 2010

I might add too that, under no stretch of the imagination, would eminent historian Gordon Wood - widely regarded as our foremost historian on the American Revolution and the drafting of the United States Constitution - claim that ours was founded as a "Christian nation". May I suggest you read his books, instead of quote-mining him, please:
John Kwok said: Obviously you missed what Wood said, since, I do recall that it was the American political elite - strongly influenced by the French and (especially) Scottish Enlightenment - which were responsible for both the Declaration of Independence and the United States Constitution (And henry, thanks. This is the first time an IDiot has quote-mined a college professor of mine.):
henry said:
John Kwok said: It's for the very reason you noticed that ID has been referred to as "Madison Avenue advertising-styled Intelligent Design creationism":
TomS said:
Joe Felsenstein said: So I say they have a positive claim, and you say they don't, but we're not really disagreeing. They have no positive claim that's a scientific hypothesis.
I quite agree. I would say that they have a claim, in the sense of advertising: "new, improved".
By the way, here is what Gordon Wood on Ushistory.org stated on an online interview. 6th answer, may 8, 1999 american revolution His book, "The Radicalism of the American Revolution," won the Pulitzer Prize in 1991. shs I thought our founding fathers were deists. Did that carry over to the general population? Prof. Wood No. The leaders and most educated tended to be deists -- they saw God as the great mover and were doubtful of the divinity of Christ. But most people were devout Protestant believers. Deism is confined to the elite. Wood recognized the Christian nature of most of the people at the beginning of our nation, which continues even today but to a lesser degree.

John Kwok · 22 February 2010

Joe, I completely agree with your assessment. But I greatly resent it when a creo troll starts quote-mining one of my college professors. I hope you understand my rationale for rebutting that moron:
Joe Felsenstein said:
RBH said: This is the 'positive' ID claim:
Sometime or other, some intelligent agent(s) designed something, and then somehow manufactured that thing, all the while leaving no independent evidence of the design process or the manufacturing process, and no independent evidence of the presence or even the existence of the designing and manufacturing agent(s).
Test that, science man!
I think that what needs to be discussed on this thread is
  1. Whether the negative claims of ID are science or can be dismissed as “not science”. We're in agreement about the not-science nature of the positive claims.
  2. Whether agreement has been reached about “order” and the Second Law.
But what should not be discussed here is whether the U.S. is a Christian Nation®. All that should go to the Bathroom Wall. I am but a humble Guest Contributor so I can't do that -- maybe someone else can. I will just add that PT has a problem with people feeding the trolls, just because they enjoy stomping on them so much -- the result is that lots of useful threads get disrupted.

TomS · 22 February 2010

One of the skills of the creationists is in moving the discussion off-topic.

They'd rather the conversation be about anything other than the inanity of creationism.

Joe Felsenstein · 22 February 2010

John Kwok said:
Joe Felsenstein said: But what should not be discussed here is whether the U.S. is a Christian Nation®. All that should go to the Bathroom Wall. I am but a humble Guest Contributor so I can't do that -- maybe someone else can. I will just add that PT has a problem with people feeding the trolls, just because they enjoy stomping on them so much -- the result is that lots of useful threads get disrupted.
Joe, I completely agree with your assessment. But I greatly resent it when a creo troll starts quote-mining one of my college professors. I hope you understand my rationale for rebutting that moron:
The problem is, everyone has a good reason, and in all these cases the troll has said something unusually outrageously wrong. As TomS said, creationists are skillful at moving the discussion off-topic. We are aiding and abetting them. If I were moderating, the Bathroom Wall would be used more, to try to curb this.

Mike Elzinga · 22 February 2010

Getting this thread back on track; here is a little exercise that you can use to check your understanding of thermodynamics.

Go to this ID/creationist website and look at the various arguments.

How many arguments can you find that distort the concepts of thermodynamics (warning; there are a lot of them packed into this one page)?

Dissect each misconception and find a reasonably good colloquial way to describe the misconception.

Then find a better colloquial scientific description that corrects the misconception.

Because there are so many rapid-fire distortions and misconceptions on just this page alone, you can begin to see how 40+ years of practice by ID/creationists has subtly injected these memes into the public consciousness.

In fact, sometimes these misconceptions are so subtle, many scientists overlook them, and the misconceptions slip by without correction (for example, the misconception by henry that living things “succumb eventually” to the 2nd law).

As I mentioned on one of my earlier comments, my past experience indicates that the use of mathematics will not help the layperson. You need to look for classical or semi-classical explanations and easily observable examples from condensed matter physics and chemistry that people can use to get the general idea.

It’s a good exercise; and it differs from many of the counter-examples from biology in which one simply draws attention to things ID/creationists ignore or simply deny. In this case, one is dealing with conceptual understanding.

John Kwok · 22 February 2010

Agreed. However I will concede that it may be useful at times to answer their comments replete in their breathtaking inanity just to illustrate to new visitors exactly what we often have to contend here from creo trolls. However, they're not only ones guilty of "trolling" and hijacking discussion threads. I know of a couple of PT posters who will stop by to do some trolling against me when it strikes their fancy.
Joe Felsenstein said:
John Kwok said:
Joe Felsenstein said: But what should not be discussed here is whether the U.S. is a Christian Nation®. All that should go to the Bathroom Wall. I am but a humble Guest Contributor so I can't do that -- maybe someone else can. I will just add that PT has a problem with people feeding the trolls, just because they enjoy stomping on them so much -- the result is that lots of useful threads get disrupted.
Joe, I completely agree with your assessment. But I greatly resent it when a creo troll starts quote-mining one of my college professors. I hope you understand my rationale for rebutting that moron:
The problem is, everyone has a good reason, and in all these cases the troll has said something unusually outrageously wrong. As TomS said, creationists are skillful at moving the discussion off-topic. We are aiding and abetting them. If I were moderating, the Bathroom Wall would be used more, to try to curb this.

Just Bob · 22 February 2010

(for example, the misconception by henry that living things “succumb eventually” to the 2nd law)
Thanks, Mike, for reminding me of one of the main reasons I read PT (besides whack-a-moling trolls--that's just so damn much fun). It makes me think about concepts that I really knew all along in the back of my mind (not in my intestines or heart, like biblical characters), but never quite consciously called up. Like the fact that human aging and death have nothing to do, really, with the SLOT, which governs energy flows. Whoa, deep, man! Our declne and death isn't because we run out of heat, or can't keep it in anymore, or because our molecules "want to" become more disorganized. Hey, I'll bet there's no less "information" in the atoms of a corpse than in the living body, even as those atoms dissipate back into the rest of the natural world. IANAS (I am not a scientist), so colloquial is about all I can manage. So how am I doing, Physics Guy?

Mike Elzinga · 22 February 2010

Here is another set of toy examples of the concept of entropy.

However, this is an example of where conflation with disorder can occur. Be very careful to think about the energy states of these configurations.

Mike Elzinga · 22 February 2010

Just Bob said: Whoa, deep, man! Our declne and death isn't because we run out of heat, or can't keep it in anymore, or because our molecules "want to" become more disorganized. Hey, I'll bet there's no less "information" in the atoms of a corpse than in the living body, even as those atoms dissipate back into the rest of the natural world. IANAS (I am not a scientist), so colloquial is about all I can manage. So how am I doing, Physics Guy?
Doin’ great there, Bob! Somewhere on another thread I also gave some rules-of-thumb about relative depths of potential energy wells. Roughly, nuclear binding energies are on the order of millions of electron volts (MeV). Chemical reactions are on the order of an eV. Binding energies of solids are on the order of one-tenth of an eV. Life as we know it exists roughly in the range of liquid water; i.e., 0.01 to 0.02 eV. When you consider things coming apart and reassembling in the ranges of shallow potential wells, creatures like us that exist in the energy range of liquid water find the extremes of that energy range “quite uncomfortable.” So it is quite natural to think of melting rock and metals as extreme conditions. These molecules come apart and reassemble within much higher energy ranges that we would find even more uncomfortable. Ripping apart molecules is even more uncomfortable, and ripping apart the nuclei of atoms would not be tolerated very well by us.

Mike Elzinga · 22 February 2010

Mike Elzinga said: Here is another set of toy examples of the concept of entropy. However, this is an example of where conflation with disorder can occur. Be very careful to think about the energy states of these configurations.
You will note when reading this article that there is this quote:

“Because they can move flexibly, the nonrigid clusters have high vibrational entropy,” explained Manoharan.

I have no clue what that means, but it suggests that there is some fuzzy thinking going on here.

Dan · 22 February 2010

Mike Elzinga said: Getting this thread back on track; here is a little exercise that you can use to check your understanding of thermodynamics. Go to this ID/creationist website and look at the various arguments. How many arguments can you find that distort the concepts of thermodynamics (warning; there are a lot of them packed into this one page)? Dissect each misconception and find a reasonably good colloquial way to describe the misconception. Then find a better colloquial scientific description that corrects the misconception.
Well, this site's what my father used to call a hum-dinger. The second law of thermodynamics states that in a closed system entropy increases. This site doesn't use the term "entropy", but instead uses the various terms "decay", "chaos", "faded and threadbare", "death", "disorder", "degeneration", "unusable", "simplicity", "downward", "degraded", "random", "disarrangedness". It's simply false that the second law of thermodynamics says these things will increase. I like to give this example: Put an ice cube in a cup, and put the cup on the kitchen counter. The ice cube will go from pure ice, to an ice-liquid water mixture, to pure liquid water. Throughout this process its entropy has been increasing. But there's been no change in its "decay", or "faded and threadbare", or "death", or "degeneration", or "degraded". ================================= The site claims that the second law of thermodynamics is "a basic, unchanging principle of nature", yet that it can be "counteracted" by spending "vast sums". Sorry, but if the law is unchanging, then it can't be counteracted. No amount of bribery will counteract a law of nature. It is indeed true that we spend vast amounts of money preventing decay. But the second law of thermodynamics is not the "law of decay". It is a misconception to hold that liquid water is "decayed ice".

TomS · 23 February 2010

eric said: I think there's a much simpler response to Sewell's claim (well, other than the deserved "pbbbbbt"). Ask him to build a perpetual motion machine of the second kind. I mean seriously: if they think intelligent agents can violate the 2nd law, they could make gazillions patenting refrigerators which run on nothing except room heat.
ISTM that this is the cleanest rebuttal to any "design" invocation of the 2LOT. No mathematics needed. Perfectly clear. Accurate. Intelligent designers can't get around the 2LOT.

Mike Elzinga · 23 February 2010

TomS said:
eric said: I think there's a much simpler response to Sewell's claim (well, other than the deserved "pbbbbbt"). Ask him to build a perpetual motion machine of the second kind. I mean seriously: if they think intelligent agents can violate the 2nd law, they could make gazillions patenting refrigerators which run on nothing except room heat.
ISTM that this is the cleanest rebuttal to any "design" invocation of the 2LOT. No mathematics needed. Perfectly clear. Accurate. Intelligent designers can't get around the 2LOT.
Depending on the ID/creationist you encounter, I suspect from my previous experience that this won’t make a dent in their misconceptions. They would argue that human actions or inanimate matter don’t violate the 2nd law. The implication and, I think, the unspoken belief is that living organisms violate the 2nd law up until the time they die (e.g., henry’s comment above). My guess is that this has lead to the concept of “entropy barriers” among some creationists; and the concept of “genetic entropy” builds on the idea that all mutations are bad and are a result of “The Fall.” Others seem to believe that aging is the result of the 2nd law and that abiogenesis is forbidden by the 2nd law. Both Behe and Dembski capitalized on this misconception (I think they also have the misconception themselves) to argue that molecules and collections of molecules follow what Abel calls “spontaneous molecular chaos.” Behe uses “irreducible complexity”, and Dembski came up with “complex specified information” and “conservation of information.” Dembski’s persistent misconception has been revealed repeatedly in his methods for finding probabilities of assemblies of molecules. It also appears in the Dembski and Marks paper in which they inject the concept of “active information” to clearly imply in that paper that scientists “cheat” when they use search algorithms learned from nature in their programs. But you are right about the inconsistency of their claims about the 2nd law when arguing against evolution and their admission that they can’t build perpetual motion machines. As we all know, inconsistency is something they attribute only to scientists. I have seen a number of creationists and creationist sites that recommend not using the thermodynamics arguments against evolution because they have heard these are erroneous. However, they still don’t understand the nature of that error because they still use all the variations on the same misconceptions without mentioning thermodynamics.

Dale Husband · 23 February 2010

Joe Felsenstein said: The problem is, everyone has a good reason, and in all these cases the troll has said something unusually outrageously wrong. As TomS said, creationists are skillful at moving the discussion off-topic. We are aiding and abetting them. If I were moderating, the Bathroom Wall would be used more, to try to curb this.
Have you looked at the Bathroom Wall lately? It is now up to 1947 Comments, and many of them consist of some troll called IBeleiveInGod being fed constantly by several people. I quit following the mayhem after a week or so.

diogenes · 23 February 2010

I don't think anyone has addressed the quasi-interesting, or at least less obviously wrong (to me) aspects of Sewell's mathematical argument.

In Sewell's mathematical index, he defines some equations for the diffusion of heat and the entropy flux, related to the total entropy change in the system. The math doesn't look wrong to me, but the interpretation does.

Number one: Sewell defines U as local temperature, then J is heat flux vector, and St is (time derivative) of entropy.

But then, later on, he says he can also define an entropy S for ANYTHING, such as "carbon entropy", related to the diffusion of carbon.

OK, now Mike will complain that entropy is not disorder (re: placement of objects in space) so more "carbon entropy" does not necessarily correspond to a uniform diffusion of carbon.

But here's my point: when Sewell substitutes U(temp) with some other like U(carbon), he writes "we can let U(x, y, z, t) represent the concentration of carbon diffusing in a solid
(Q is just U now)", then MAYBE his equations D.1 and D.2 are the same (basically, U is carbon density so J is now carbon flux). But if U(carbon)=Q(carbon), then his equation D.3 can't be right. Can it? Because 2nd Law specifically says that the change in entropy is change in heat over temperature, like in D.2.

But now in D.2, the U in the denominator is no longer temperature like it should be, now it's carbon density. Therefore D.2 no longer holds. Why should D.2 relate change in "carbon entropy", to the integral over a closed surface of carbon flux (dotted with normal vector) divided by carbon density U? Not intuitive to me at all. That would never work, for say, electrical charge, where by Gauss' Law, the integral over a closed surface of charge flux (dotted with normal vector) is just change in total charge. Nothing in the denominator.

Without Equation D.2, the rest of his talk about defining an unlimited number of different kinds of entropy, falls apart.

Furthermore, I can think of a simple experimental counter-example: gravy. I heat gravy on the stove, and forget to stir it. It lumps up. The starch molecules stick together, driven by attractive forces. This is definitely a local DECREASE in "carbon entropy"; the carbon atoms are now LESS DIFFUSE and more lumped up.

However, following Sewell's logic, the only way you can have a local decrease in "carbon entropy" is if (he says) "carbon order" is flowing in from the outside. How the hell is "carbon order" flowing INTO my pot full of gravy? Heat goes in the bottom and radiates off the top and sides, but it's a metal pot surrounded by air. No rearrangement of carbon OUTSIDE the gravy pot.

And this points up the main bogus element of his mathematical discussion: he describes the OUTFLOW of entropy from an open system as an INFLOW of order. This is bull. When a snowflake crystallizes (local entropy decrease), it radiates off the latent heat of crystallization. Heat goes off as IR radiation or whatever. Stuff goes out. NOTHING NEEDS TO ENTER AT ALL.

I know his interpretation is wrong. But I want to know about Equations D.3 and higher: do they really apply for all kinds of entropy such as "carbon entropy"?

Mike Elzinga · 23 February 2010

diogenes said: I know his interpretation is wrong. But I want to know about Equations D.3 and higher: do they really apply for all kinds of entropy such as "carbon entropy"?
You are right that I will object that entropy is about order. There is a situation in which order is associated directly with the entropy of the constituents under study, and that is crystallization. This situation is the one which causes the most confusion because those actual atoms or molecules that condense into a crystalline array do, in fact, ultimately occupy fewer energy states, so they have lower entropy. And they are ordered. But it is important to notice that, by occupying these few number of states, those atoms or molecules are now seated more deeply in the potential wells formed from their mutual interactions. No system of particles can settle into a potential well unless energy is released; and energy is released in the form of photons, phonons (once the collection of particles start behaving collectively) and by other particles upon which energy and momentum is transferred away from those which remain and condense. In other words, the collisions among those remaining constituents are inelastic. The second law still holds. Some of the creationist websites I have seen try to introduce “configurational entropy” in their attempts to “mind-wrestle” their confusion into some kind of sense. “Carbon entropy” appears to be another one of those unnecessary terms (perhaps a special case of “configurational entropy”) that allows creationists to keep their misconceptions intact. You were correct to notice the change in units. This should always be a clue that something is wrong.

Joe Felsenstein · 23 February 2010

Dale Husband said: Have you looked at the Bathroom Wall lately? It is now up to 1947 Comments, and many of them consist of some troll called IBeleiveInGod being fed constantly by several people. I quit following the mayhem after a week or so.
I think that's great. The Wall drains off both the trolls and their feeders, neither of whom we need here.

John Kwok · 23 February 2010

I concur, Joe. Have stayed away from this thread because there were too many trolls lurking here. Now thankfully we've bid them farewell (at least for now):
Joe Felsenstein said:
Dale Husband said: Have you looked at the Bathroom Wall lately? It is now up to 1947 Comments, and many of them consist of some troll called IBeleiveInGod being fed constantly by several people. I quit following the mayhem after a week or so.
I think that's great. The Wall drains off both the trolls and their feeders, neither of whom we need here.

eric · 23 February 2010

Mike Elzinga said: Depending on the ID/creationist you encounter, I suspect from my previous experience that this won’t make a dent in their misconceptions. They would argue that human actions or inanimate matter don’t violate the 2nd law.
Great, fine, this is progress. Any creationist who responds in this way loses the argument in two different ways. First, they lose the ability to use human action (i.e. breeding, genetic engineering) as "examples" of 2LOT violations. Creationists commonly use human actions as such examples, so arguing that humans can't build perpetual motion machines of the second type strips from them a commonly used false argument. Second, they lose the ability to claim that ID is about natural intelligent actors such as humans. If humans can't violate 2LOT, neither can natural aliens. This clearly makes the ID hypothesis a hypothesis about supernatural intelligences and strips away creationist claims that their ID theory is scientific. So, we should welcome this. We should use this question (why can't humans build perpetual motion machines of the 2nd type) as a means of exposing (i) their 2LOT examples as irrelevant and (ii) their "scientific" arguments as nonscientific.

TomS · 24 February 2010

I see that the "refrigerator" rebuttal could be interpreted two ways, and ought to be made clearer.

As I intended it, it is that the only examples of designers that we know of are also bound by the 2LOT. Therefore, introducing an "intelligent designer" does not account for any supposed violation of the 2LOT. Not without additional description of such designers, and the boosters for designers prominently avoid such descriptions.

Introducing intelligent designers to explain something that we know very well intelligent designers can't do is a loser from the start.

eric · 24 February 2010

TomS said: As I intended it, it is that the only examples of designers that we know of are also bound by the 2LOT.
Mike E. thinks that creationists interpret 2LOT this way too. I somewhat disagree. While creationists may not explicitly claim humans can violate 2LOT, its implied by their argument. Humans can, for instance, genetically engineer plants and animals for entirely new traits, which is exactly the sort of change that creationists claim nature can't do. My argument is that we should make this implication clear. Call them on it; can natural intelligences violate 2LOT or not? If yes, demand that creationists demonstrate a "classic" 2LOT violation such as a perpetual motion machine. If no, this puts their designer in the religion category. But either way clarification helps us; the creationist position on 2LOT is only sustainable as long as they obfuscate the details of what their claim implies.

Vaughn · 24 February 2010

Mike Elzinga, your lucid descriptions of the 2LOT have helped clarify my own understanding. The visual image of "energy wells" is particularly useful and should also benefit my students next time I teach intro Bio. Thanks!

I don't comment often, but for all the articulate contributors like Mike on this blog, know that your collective efforts are appreciated.

Vaughn

Diogenes · 24 February 2010

It isn't exactly true that creationists say only life can violate 2LOT. The sneakier argument goes: 2LOT always applies...and you CAN have a local decrease in entropy as when living things grow...but, they add, ONLY IF SOME KIND OF MYSTICAL "information" is already present in the system.
This argument combines the "rape of thermodynamics" with the "rape of information theory" argument.

Now this is a sneakier idea than just saying you can't violate 2LOT. They're redefining their own 2LOT to say it's really about an undefined, faux-Shannon "information."

For example, here the great Henry Morris rapes thermodynamics:
"In any ordered system, open or closed, there exists a tendency for that system to decay to a state of disorder, which tendency can only be suspended or reversed by an external source of ordering energy directed by an informational program and transformed through an ingestion-storage-converter mechanism into the specific work required to build up the complex structure of that system."

And here one David Malcolm rapes thermodynamics : "...the trap people fall into is thinking that all that is required for evolution to occur is the input of energy into the system. Nothing could be further from the truth. The vital component is for INFORMATION (i.e. organization) to be added to the system."

But of course creationist information is a mystic undefined property, so I call it "info shminfo" (let's not confuse it with Shannon information.)

Now, returning specifically to the title and original subject of this post, Sewell has no evidence, experimentally or theoretically, that 2LOT is wrong. Actually, what Sewell is trying to do is claim the arbitrary invention of an unlimited number of laws of physics: a 2LOT for "carbon order", a 2LOT for "chromium order", and on and on for every kind of molecule.

But notice how the creationists are upping the ante. Sewell is not just saying that evolution (and growth of living things) violates ONE law of physics. He's saying it violates an UNLIMITED NUMBER OF LAWS OF PHYSICS.

Are Mike and I the only ones who have problems with Sewell's equation D.3 in his technical appendix?

TomS · 24 February 2010

eric said: Call them on it; can natural intelligences violate 2LOT or not?
In agreement with eric: If something-or-other about life violates 2LOT, what is it about "intelligent designers" that accounts for that? We know that their being "intelligent" or "designers" is irrelevant.

Mike Elzinga · 24 February 2010

eric said: Mike E. thinks that creationists interpret 2LOT this way too. I somewhat disagree. While creationists may not explicitly claim humans can violate 2LOT, its implied by their argument. Humans can, for instance, genetically engineer plants and animals for entirely new traits, which is exactly the sort of change that creationists claim nature can't do.
That’s a good point; and in fact, I have also seen that claim as well. Airplanes are assembled by violating the “law of entropy” is how the argument goes. In fact, here is Sewell from that Appendix D of his book:

In a recent Mathematical Intelligencer article [Sewell 2000], after outlining the specific reasons why it is not reasonableto attribute the major steps in the development of life to natural selection,I asserted that the idea that the four fundamental forces of physics alone could re-arrange the fundamental particles of Nature into spaceships, nuclear power plants,and computers, connected to laser printers, CRTs, keyboards, and the Internet, appears to violate the second law of thermodynamics in a spectacular way.

I could go on and mention a lot of other things wrong with Sewell’s Appendix D. As Diogenes has already noticed, there is something fishy about just plugging in “carbon distributions” and “calculating” “carbon order.” This simply amounts to an assertion that one can substitute matter flow and concentrations of matter for the flow of energy. That is simply wrong. If one wants to do such calculations with matter/energy flows, one has to use relativity and things like E2 - (pc)2 = (m0c2)2. Then the “volume integrals” are over 4-dimensional space-time. But this takes us far beyond where the elementary misconceptions already occur; and we need to address these misconceptions about the most fundamental and elementary physics notions before we even attempt to discuss relativity and quantum mechanics. ID/creationists, even those with PhD’s, can’t even get the basics right; and after 40+ years of observing this, I claim that many of them have already crossed the line into to conscious fraud.

Mike Elzinga · 24 February 2010

Vaughn said: Mike Elzinga, your lucid descriptions of the 2LOT have helped clarify my own understanding. The visual image of "energy wells" is particularly useful and should also benefit my students next time I teach intro Bio. Thanks! I don't comment often, but for all the articulate contributors like Mike on this blog, know that your collective efforts are appreciated. Vaughn
Vaughn, Thanks for the feedback; it’s greatly appreciated. The task over the years I have been doing this has not been smooth. And no researcher ever advances his/her career by taking on pseudo-science; it is done on one’s own time and money. After being thoroughly debunked, ID/creationists tend to dig in their heels and just go on repeating their misconceptions in even greater volume. They get at least two benefits from this: (1) they fake “being in the game” with real scientists, and (2) they can keep reciting their mantra that this proves there is real controversy in the science community about evolution. But they never correct their misconceptions. After many years of wrestling with conceptual issues for laypersons, it is still hard for me to see much progress in the public understanding of science. And I am not getting any younger, so I have to trust that the younger generations of scientists and teachers will pick up the load and carry on. The best I can do at this point is to pass on what I have experienced and what I have observed that works. It has been a bit exasperating to see the hard work of my generation and earlier generations in this area buried and forgotten. I would encourage anyone who teaches biology, or any area of science for that matter, to constantly polish up their conceptual understandings of the other sciences. It isn’t necessary to get into the math; the math is simply an efficient way to work with specific examples of the concepts. Many physicists in my generation and prior have constantly emphasized practicing the ability to conceptualize and explain physics concepts without using math. One of my favorites was Victor Weisskopf who did this so easily that all of us who observe him recognized its benefits immediately. Our research group lunch breaks began applying this idea to our own research efforts. You will note that ID/creationists don’t use math when misinforming their audiences. They use plausible-sounding misconceptions and encourage their audiences to believe that they have deeper insights than those arrogant, egg-headed scientists. In fact, here is Sewell again in his Appendix D.

The discovery that life on Earth developed through evolutionary “steps”, coupled with the observation that mutations and natural selection—like other natural forces—can cause (minor) change, is widely accepted in the scientific world as proof that natural selection—alone among all natural forces—can create order out of disorder, and even design human brains with human consciousness. Only the layman seems to see the problem with this logic.

Just Bob · 24 February 2010

"Only the layman seems to see the problem with this logic."

Lord, save us from laymen who "see the problem with...logic" that scientists in that field fail to see. If we depended on laymen's logic, then the world would still be flat and unmoving. I mean, any peasant can see that it's flat and not going anywhere. After all, if it were round, the folks on the bottom would fall off, and if it were flying that fast, we'd all be blown off. It's just logical.

John Stockwell · 24 February 2010

The answer to the second law complaint, is two-fold.
The earth is an open system, and, most importantly,
the part of the system that consists of the biosphere is not in equilibrium. All of the 2nd law "analyses" are equilibrium thermodynamics arguments.

Dr. Sewell's mathematical examples are all "flow with no turbulence" representations. Biology is a nonequilibrium, nonlinear system, so if you wanted a fair comparison, an analogy to flow with turbulence would be more apt.

Mike Elzinga · 24 February 2010

John Stockwell said: Dr. Sewell's mathematical examples are all "flow with no turbulence" representations. Biology is a nonequilibrium, nonlinear system, so if you wanted a fair comparison, an analogy to flow with turbulence would be more apt.
And this is also an important example of what happens as matter condenses and starts behaving collectively. One of the favorite “arguments” by ID/creationists is that the influx of energy – usually sunlight or radiation – breaks up what forms (ah ha; they admit some things form). But turbulence is crucial in shuttling compounds formed in highly energetic environments into more “quiescent” environments in which they can remain intact. A lot of chemical processing depends on just this kind of turbulence.

Diogenes · 25 February 2010

One of their main arguments is the unproven claim that, even in an open system, you can only have a local decrease in entropy if some "info shminfo" (not Shannon information) is in the system.

Usually, when physicists try to show counter-examples of a local decrease in entropy, they mention some kind of man-made machine (like a hydraulic ram pump) that harnesses heat or energy to do some work. The creationists refute this by saying that machines are intelligently designed and have indefinable info shminfo that makes the local entropy decrease possible. That's not the 2LOT, but they say it is.

But this is disproven by the following example: if the Earth were dead, no life, no creationist information or info shminfo; and if all the water had run into the oceans and was salt water; the sun would still evaporate water, rain would still fall, mountain lakes would form, and fresh water would be (partially) separated from salt water. So even on a lifeless planet, there would be local decreases in entropy.

Joe Felsenstein · 25 February 2010

Mike Elzinga said: But turbulence is crucial in shuttling compounds formed in highly energetic environments into more “quiescent” environments in which they can remain intact. A lot of chemical processing depends on just this kind of turbulence.
Pardon my naïvete, but even without turbulence, particles will tend to move away from areas where they have greater thermal motion and collect in areas where they have less. It's just a basic property of diffusion processes.

Mike Elzinga · 25 February 2010

Joe Felsenstein said: Pardon my naïvete, but even without turbulence, particles will tend to move away from areas where they have greater thermal motion and collect in areas where they have less. It's just a basic property of diffusion processes.
Yes; that is also one of the processes. This process is associated more with matter in a vapor stage in which the individual molecules still interact relatively weakly; i.e., their kinetic energies are quite large relative to their mutual interaction potential energies. Diffusion pumps work on this idea; and the cold windows or walls of a house in winter can often be the places where water vapor collects as it is “pumped” in the direction of temperature gradients and gives up its kinetic energy to the molecules of the window or wall. As matter condenses even more toward the level where kinetic energies are comparable to the depths of those potential wells of interaction, we begin to see more coordinated collective motions like fluid flow. Then we often see a viscous phase and finally a solid phase in which quantized sound waves (phonons) begin to sweep any relatively free charge carriers along in the direction of temperature gradients and carry energy through the material to any container in which the material resides. Then, with some molecules like helium, we can encounter a superfluid state in which the liquid flows without any resistance or viscosity. At very high energies, plasmas exhibit extremely complicated behaviors. And, of course, the behaviors of various compounds in water are some of the more interesting phenomena that probably relate to how life came about. Similar ideas apply to liquid methane. There is a good reason why condensed matter physics is by far the largest subfield of physics. It is an extremely rich field for research; the ranges of subtle phenomena are virtually limitless. It is often characterized as a messy field because it doesn’t have the austere purity of, say, a field like elementary particle physics. But some of the theoretical work that has gone on in condensed matter physics has also laid the foundations for some of the theoretical work in elementary particle physics. Because of the perceived “messiness” of condensed matter physics, it doesn’t get the public press of some of the more “glamorous” fields such as elementary particle physics. So the public doesn’t get to see the extreme importance of this field and its influence on nearly every other area of physics and chemistry as well as its importance to technology. Things like computers, high-density storage and flash drives, and CCD imagers wouldn’t exist without the research in condensed matter physics. And that just scratches the surface.

Mike Elzinga · 25 February 2010

Diogenes said: So even on a lifeless planet, there would be local decreases in entropy.
The ID/creationists have too often dragged the discussion onto their own turf where their own misconceptions abound. On that turf they can conflate entropy, disorder, information and force any discussion to use their pseudo-science concepts (I like your “info schminfo”; it is most appropriate). Entropy should always remain what is means in statistical mechanics and thermodynamics; and people should not permit ID/creationists to redefine well-established concepts in science. We can always find examples of systems in which entropy decreases; but I think the focus needs to always be on the various ways energy enters and leaves any given system. Kinetic energy, potential energy, potential wells and falling into wells and staying in them makes a pretty good skeleton outline of what the central issues are. That way one focuses on the 2nd law and the bookkeeping of energy and is less likely to be drawn into the persistent misconceptions and conflations by the ID/creationists.

TomS · 25 February 2010

Mike Elzinga said: Airplanes are assembled by violating the “law of entropy” is how the argument goes.
I hadn't heard, but I'm not surprised, that extension of the 2LOT argument. It makes the parody seem mild: Airplanes fly by violating the "law of gravity", and the only reason that they can fly is that they are intelligently designed. Which proves that birds are intelligently designed.

Frank J · 25 February 2010

The ID/creationists have too often dragged the discussion onto their own turf where their own misconceptions abound.

— Mile Elzinga
Exactly. That's what peddlers of every "kind" of pseudoscience do. It's all they can do. Other than the Godwin's Law thing, which, as you know, is becoming an increasingly prominent part of ID/creationism. What increasingly annoys me is how often our side takes the bait, and allows the pseudoscience peddlers to control the terms of the "debate." I understand that we have to clear up many public misconceptions about evolution. But every fact we add about evolution is another one that skilled pseudoscience peddlers can take out of context to promote unreasonable doubt. That's why I think much more emphasis must be put on the details of the ID/creationists' mutually contradictory and "don't ask, don't tell" alternate "theories." It's up to us to make it perfectly clear that the ID/creationists have nothing but a hopeless mess of completely failed "explanations," and an increasingly common, deliberate cover-up of that fact. So when I hear people who are capable of knowing better saying things like "I hear the jury's still out on evolution" or "it's only fair to teach both sides" I can't help thinking that, despite the court victories, we're failing miserably.

Dan · 25 February 2010

Diogenes said: Usually, when physicists try to show counter-examples of a local decrease in entropy, they mention some kind of man-made machine (like a hydraulic ram pump) that harnesses heat or energy to do some work. The creationists refute this by saying that machines are intelligently designed and have indefinable info shminfo that makes the local entropy decrease possible.
Creationists (e.g. Henry Morris) say things like "evolution is like water running uphill". Can water go uphill naturally? Yes. Evaporation, geysers, capillary tubes, convection currents in lakes, artesian springs, tides, whirlpools and eddies.

stevaroni · 25 February 2010

Dan said: Creationists (e.g. Henry Morris) say things like "evolution is like water running uphill".
Water goes uphill all the time. After all, the mountain peaks of the world are regularly covered with snow. If fact, any water we actually see flowing downhill had to start the trip by somehow getting uphill first. All it takes is a little energy flux to locally decrease entropy, thus apparently violating the second law of creationist thermodynamics.

Henry J · 25 February 2010

ID and Creationist, otoh, always seem to go downhill...

Vaughn · 25 February 2010

Mike Elzinga said: - snip - Then we often see a viscous phase and finally a solid phase in which quantized sound waves (phonons) begin to sweep any relatively free charge carriers along in the direction of temperature gradients and carry energy through the material to any container in which the material resides.
OK. "Phonons" is not a term I have encountered before. The Wikipedia entry was not helpful. Mike, can you give a brief description of these particle/waves or direct me to an introductory level (high school would be best as it has been a looong time since college physics) description of phonons? Thanks. Vaughn

eric · 25 February 2010

Vaughn said: OK. "Phonons" is not a term I have encountered before. The Wikipedia entry was not helpful. Mike, can you give a brief description of these particle/waves or direct me to an introductory level (high school would be best as it has been a looong time since college physics) description of phonons? Thanks. Vaughn
Phonons refer to acoustic vibrational waves in solids. They are directly analogous to the way "sound waves" are really just vibrational waves in gasses. There is no phonon particle (again, think sound waves, which have no "sound particle" either).

SWT · 25 February 2010

diogenes said: I don't think anyone has addressed the quasi-interesting, or at least less obviously wrong (to me) aspects of Sewell's mathematical argument. In Sewell's mathematical index, he defines some equations for the diffusion of heat and the entropy flux, related to the total entropy change in the system. The math doesn't look wrong to me, but the interpretation does. [snip!] I know his interpretation is wrong. But I want to know about Equations D.3 and higher: do they really apply for all kinds of entropy such as "carbon entropy"?
This is probably a bit late, but I just dragged myself through Sewell's note. Sewell is attempting to make an anti-evolution argument using non-equilibrium thermodynamics. Setting aside his comments about "randomness" and "order," there are some clear flaws in his analysis. Most serious discussions of non-equilibrium thermodynamics start with a general entropy balance that includes the effects of flows of momentum, energy, and matter. In doing so, they usually come up with something analogous to Sewell's Eq. D.4, which expresses the change in entropy at a point into an entropy generation term (the triple integral in Eq. D.4) and an entropy flow term (the double integral in Eq. D.4). However, the form of Eq. D.4 holds only for entropy production due to heat flow. So far, so good, mathematically. (Of course, what Sewell calls "thermal entropy" is what people who understand thermodynamics call "entropy.") However ... Sewell does manage to get some cause and effect mixed up even in this very simple case. The second law tells us that the entropy production must be non-negative, meaning that the integrand of the volume integral in D.4 must be non-negative. Eq. D.2 and the sign in Fourier's law follow from this directly. He starts going off the rails when tries to appropriate his result in D.4 for diffusion due to composition gradients using a simple change of interpretation. The entropy production associated with mass transfer is the product (mass flux).div(chemical potential/T) (neglecting extenal forces). Because his analysis is simple-minded and wrong, he ends up not only with the wrong expression for the entropy production, but also the wrong units. When you do the analysis correctly, you get the correct units and you don't have to resort to silly things like "carbon entropy." Entropy is entropy is entropy; it doesn't come in different flavors. What's most interesting to me in Sewell's narrative, though, is that he seems to grasp that entropy production can be balanced by a flow of entropy out of a system (this is what D.4 means for the simple case of heat conduction) but doesn't seem to belive the consequences of that result. I guess Sewell never took the time to review any of Ilya Prigogine's results; Prigogine won the Nobel Prize in 1977 for his work in this area.

Just Bob · 25 February 2010

stevaroni said: Water goes uphill all the time.
What the creationist imagines (in his limited way) is a simple stream flowing downhill. Of course it doesn't go uphill. But anyone who has ever kayaked or rafted on whitewater knows that among all that downhill rush, there can be some very large and frightening uphill flows. The overall direction is downhill, sure, powered by gravity. But the same power forces the water uphill in places. If it didn't, there wouldn't be any whitewater! Hey, that's kind of like all that "downhill" energy flow from the sun producing a few "uphill" bumps, like life on Earth.

Mike Elzinga · 25 February 2010

Vaughn said: OK. "Phonons" is not a term I have encountered before. The Wikipedia entry was not helpful. Mike, can you give a brief description of these particle/waves or direct me to an introductory level (high school would be best as it has been a looong time since college physics) description of phonons? Thanks. Vaughn
As eric has mentioned, these are acoustic waves in solids, but they are quantized. The reason for being quantized is because many solids – metals for example – have a periodic crystalline lattice structure that can sustain collective motions of the lattice that are on the order of a few atoms or molecules in length. By being quantized, these phonons behave like individual “particles” that can interact with electrons that are free to move about within the metal. Obviously there are also the “regular” sound waves that travel through the material. But even in this case, the bulk solid can sustain only discrete wavelengths that are on the order of the size of the bulk object itself. You are most likely familiar with standing waves on a string or rope fastened at both ends. These are quantized wavelengths, but they are not phonons. Phonon wavelengths are on the order of several lattice periods. One can illustrate the difference by replacing a rope with a bead chain. A little careful observation will show quantized waves on the order of a few bead lengths. There are also surface acoustic waves that are very short wavelengths running along the surface of a material. They can be much longer than phonons and much shorter than sound waves in the bulk of the material. There are a number of signal processing devices that make use of surface acoustic waves and do things like take Fourier transforms of signals (signal in, Fourier transform out). One of the prime mechanisms of heat conduction is by way of phonons. These transmit energy from point to point within the material. One of the ways to reduce the conduction of heat through the material is to introduce defects and inclusions of crystalline materials that scatter the phonons so that they can no longer pass their energy and momentum efficiently onto adjacent phonons. Stainless steel has less conductivity than normal steel or other metals because its crystalline structure contains many scattering centers. Another technique for reducing thermal conductivity is to layer the material. The boundaries between the various layers act as scattering planes that inhibit the transmitting of phonons across the boundaries. One way to get a teakettle to heat faster on an electric burner is to “scrub” the bottom of the teakettle on the burner to remove any oxides that scatter phonons. I still haven’t mentioned quantum mechanics in any of this, but it turns out that many of these details depend on quantum mechanics and the way the molecules and atoms in the lattice structure of a solid interact. Then we get into the concepts of metals, semi-metals, conductors, semi-conductors, superconductors (electron motion being correlated by interaction with phonons), etc.

Vaughn · 25 February 2010

A light bulb just turned on over my head! It was the transferring of energy via phonons that had me puzzled. Perhaps I shouldn't admit this in public (my excuse is I spend most of my time thinking about biological phenomena, not physical phenomena [sheepish grin]), but I had never made the connection that waves, be they sound waves in gases or phonons in solids represent a transfer of energy. Duh! That illustrates why I try to be patient with my students - the above connection only took me 20 years to make; I think I owe my students a bit of leniency if they don't "get it" in a single semester.

Thanks to both Eric and Mike for turning on that mental light.

Vaughn

Diogenes · 25 February 2010

Thanks for the comment SWT!
SWT said: He starts going off the rails when tries to appropriate his result in D.4 for diffusion due to composition gradients using a simple change of interpretation. The entropy production associated with mass transfer is the product (mass flux).div(chemical potential/T) (neglecting extenal forces). ...When you do the analysis correctly, you get the correct units and you don't have to resort to silly things like "carbon entropy." Entropy is entropy is entropy; it doesn't come in different flavors. What's most interesting to me in Sewell's narrative, though, is that he seems to grasp that entropy production can be balanced by a flow of entropy out of a system (this is what D.4 means for the simple case of heat conduction) but doesn't seem to belive the consequences of that result.
I'm a bit rusty on TD (but still better than Sewell), but I knew you needed a chemical potential in there somewhere. Here's another thought experiment that disproves Sewell's assertion that you can define unlimited kinds of entropy such as "carbon entropy", etc. etc. Suppose you have a solution of ions, like salt water, with Na+ and Cl-. You put it in a can. Initially, the distribution of Na+ and Cl- is uniform. So Sewell would say that the "Na+ entropy" and "Cl- entropy" are both MAXIMIZED. Now put the can in an external electrical field. The Na+ drift one way, the Cl- drift the other. The "Na+ entropy" and "Cl- entropy" have both LOCALLY DECREASED. Now consider Sewell's interpretation of his equation D.4 for "Na+ order" and "Cl- order." He says that if "Na+ order" locally increases in the can, then "Na+ order" must flow INTO THE CAN FROM OUTSIDE. But the can could be in a vacuum; there might be no other Na or Cl atoms anywhere else in the universe. How can "Na+ order" and "Cl- order" be defined outside the can-- and how can they both FLOW IN from outside the can, when there's just vacuum outside?

Henry J · 25 February 2010

Technical details aside though, it's growth and metabolism that produces entropy and dumps it into the environment. Any entropy associated with evolution is insignificant compared to that. So the 2nd law can't prevent evolution without preventing growth in the first place.

Besides, if the 2nd law was wrong, that in itself would kill any arguments that try to use it to establish or disestablish something else.

Henry

Mike Elzinga · 25 February 2010

Henry J said: Technical details aside though, it's growth and metabolism that produces entropy and dumps it into the environment. Any entropy associated with evolution is insignificant compared to that. So the 2nd law can't prevent evolution without preventing growth in the first place. Besides, if the 2nd law was wrong, that in itself would kill any arguments that try to use it to establish or disestablish something else. Henry
Even more important, however, is that it is very problematic to even connect the word entropy with the characteristics of a living organism; that somehow “higher organisms” have less entropy or that, as evolution progresses, entropy diminishes. That way of thinking is also allowing the ID/creationists to drag the discussion onto their territory and work with their misconceptions. Never ever forget that thermodynamics is about the bookkeeping of energy in any physical process that takes place in any given system living or non-living. Entropy is not about the configuration of the system; its physical or structural arrangements, or its organization, or its complexity. All those things are peripheral to what is going on with energy flowing in and out of the system or being stored within. This notion that ID/creationists push that somehow entropy is just another way of talking about information is simply another way they misconstrue entropy as being connected with disorder or “simplicity” or “complexity.” Just because they slip the word “information” in there doesn’t hide the misconception. It’s conflation all the way down. Living organisms of any type, of any era in evolutionary history, take in energy and expel energy with the net result that the entropy of the environment in which the organism exists increases. It has nothing to do with what the organism looks like, when it existed or where it stands in an evolutionary chain. The only things that matter are how efficiently the organisms use energy; the less efficient ones probably generating more environmental entropy per unit mass of organism as a result of their existence in their environment.

Mike Elzinga · 25 February 2010

SWT said: He starts going off the rails when tries to appropriate his result in D.4 for diffusion due to composition gradients using a simple change of interpretation.
As I mentioned above, if one wants to do this with mass/energy, one has to turn to the relativistic versions in 4-dimensional spacetime. But there are some classical perspectives analogous to the flow of incompressible and compressible fluids that are also used. I am a bit squeamish about tackling this issue from this perspective because it assumes the most basic concepts are in place; and besides, the layperson usually can’t follow along. Considering an incompressible fluid for the moment, those surface and volume integrals express what I think most people can understand intuitively; namely, that the net flux (flow) of fluid through a closed surface surrounding a source or sink of fluid is directly proportional to the rate of production or destruction of the fluid within the volume enclosed by that surface. One could think of a lawn sprinkler, for example, and think of the outward spray as coming from a source within an enclosing sphere. If you forget about the hose connected to the sprinkler head for a moment, the net outward flow of water is proportional to its “rate of production” at the sprinkler head. However, if one now takes into account the hose that is attached to the sprinkler head, then the net flow through the enclosing sphere is zero; there is as much water coming in through the hose as there is going out in the form of the spray and evaporation. The way we talk about this in that volume integral is to state what the “divergence” is inside the sphere. If it is non-zero, the integral of this divergence over the volume of the sphere turns out to be equal to the integral of the flux per unit area summed over the entire area of the enclosing surface (sphere or no sphere). This is referred to as the “divergence theorem” in vector calculus. If the fluid is compressible, we can consider a compressed air can within the enclosing surface as the source. Here again, the rate at which the compressed air is being released is expressed as a divergence and the net flow of air through the enclosing surface is again proportional to the integral of that divergence over the volume of the sphere. But again we have to decide whether or not that divergence includes placing the canister of compressed air inside the enclosing surface. If so, then the divergence is zero; we brought as many air molecules into the enclosing surface as we bleed out. In the above examples, we are discussing matter; either air or water. Ultimately it comes down to counting molecules going in and out. We are not at this point talking about work and energy. One can do a similar exercise with energy, but now it becomes much more complicated. Contained within each of those integrals are all the mechanisms that produce, store, and dissipate energy. Accounting for all those mechanisms can be a real mess depending on what kinds of processes are involved. But now what happens when one divides energy by “temperature” and does the integrals? We are calculating “entropy production and flow”, but what does it mean to the layperson? The clue comes from statistical mechanics where we learn that “temperature” is related to the number of degrees of freedom of the constituents of the medium in which energy is stored. The same amount of energy “poured into” a fewer “buckets” means more energy per bucket (higher “temperature”). In a sense, it gives a measure of how “good” the energy storage medium is at soaking up energy; the more “little buckets” inside the medium, the more energy we can store at a given “temperature.” Now temperature does have something to do with how effectively energy gets transferred from place to place because higher kinetic energy per degree of freedom also implies more momentum transfers from energetic molecules to less energetic molecules for example. But now one also has to consider electrical charge, gravitational attraction, and any other interactions that result in forces that do work in moving particles from place to place. So there is much more wrapped up in those integrals which can be overlooked or misrepresented and result in confusion. This is why I don’t feel comfortable using this level of conceptual machinery for interpreting thermodynamics to laypersons. Sewell has made some egregious errors by simply replacing energy with carbon or chromium atoms in these integrals.

Mike Elzinga · 25 February 2010

I thought of an analogy to what Sewell has done in this Appendix D.

The Pythagorean Theorem for right triangles with sides of length a and b and hypotenuse of length c says that

c2 = a2 + b2.

This is “universally true”; it is an unimpeachable law of the universe.

So all we have to do is replace a with the weight of an individual, b with the individual’s age, and c with the individual’s IQ and we have the universal law that allows us to find a person's IQ from his/her age and weight!

Henry J · 25 February 2010

So all we have to do is replace a with the weight of an individual, b with the individual’s age, and c with the individual’s IQ and we have the universal law that allows us to find a person’s IQ from his/her age and weight!

Hey, does that mean I can raise my IQ by eating lots of burgers and fries?

John Stockwell · 25 February 2010

Mike Elzinga said:
John Stockwell said: Dr. Sewell's mathematical examples are all "flow with no turbulence" representations. Biology is a nonequilibrium, nonlinear system, so if you wanted a fair comparison, an analogy to flow with turbulence would be more apt.
And this is also an important example of what happens as matter condenses and starts behaving collectively. One of the favorite “arguments” by ID/creationists is that the influx of energy – usually sunlight or radiation – breaks up what forms (ah ha; they admit some things form). But turbulence is crucial in shuttling compounds formed in highly energetic environments into more “quiescent” environments in which they can remain intact. A lot of chemical processing depends on just this kind of turbulence.
Yes. Either Sewell is being purposely misleading, or he has never heard of those "Brussellator" models that Ilya Prigogine and others were experimenting with. These chemical cells developed complex behavior as long as the flow of input and output from the cells were maintained at a critical value.

Joe Felsenstein · 25 February 2010

OK, folks, time for me to stick my head in the lion's mouth. Now that we all are agreed about entropy, let me recall my Original Post where I said the growing weeds represented a decrease in entropy and an increase in “order”. OK, I should have left the part about “order” out.
  1. So was it OK to say that growth of the weeds were a (local) decrease in entropy? (I'd guess yes -- they certainly increased their energy content).
  2. Mike Elzinga wrote that
    Living organisms of any type, of any era in evolutionary history, take in energy and expel energy with the net result that the entropy of the environment in which the organism exists increases.
    But I suspect it is also OK to note that the growth of the weeds, by catching some energy from the sun and delaying its loss to the surroundings, actually does not increase entropy overall, but somewhat delays its increase. Don't all object at once!
  3. I predict that some day we will also know how to bookkeep a connection between energy flows, increase of entropy and (cringes and ducks behind the sofa) some relevant measure of the “adaptive information” that has accumulated in the biosphere by evolution and growth of populations. Note I said “some day”, not right now.

eric · 25 February 2010

Joe Felsenstein said: I predict that some day we will also know how to bookkeep a connection between energy flows, increase of entropy and (cringes and ducks behind the sofa) some relevant measure of the adaptive information that has accumulated in the biosphere by evolution and growth of populations. Note I said some day;, not right now.
I'm not sure that will ever be the case. Entropy is a state function. (For the non-physicists...) that means past history does not determine the quantity. If you could record the entropy of all life right now, and the entropy of all life at some future point, you could compare them. However, barring some realistic measurement like that it would be practically impossible to do what you suggest. Now, philosophically, there's another problem with your suggestion. Fitness is ecologically local. That means that the value of "adaptive information" varies with the local ecology. In essence your suggestion is that we attempt find some objective value for a quantity that is in reality relative to the environment. Consider coat color in predators. What is the "adaptive information" value of a mutation that provides a black coat? Well, that depends on whether you hunt in bright light or night, doesn't it?

Dr. Blow Torch · 25 February 2010

You guys are all dumb as a box of rocks.

You can apply heat all day long to a lava lamp and even a simple cube of lava will never be formed. You might get something that approaches a sphere once in a while, but not a cube.

Blind application of heat (energy) is not sufficient to form anything interesting and is usually destructive, like 99.999999999% of the time.

Prove me wrong. Now.

I'm getting tired of this 'earth isn't a closed system' BS; as if that is enough to explain how life started. It's not. What if I expand my sphere of the system boundary to include both the earth and the sun. Now wtf are you going to do? It's a closed system.

Prove me wrong. Now.

Joe Felsenstein · 26 February 2010

Dr. Blow Troll said: Blind application of heat (energy) is not sufficient to form anything interesting and is usually destructive, like 99.999999999% of the time. Prove me wrong. Now.
The weeds in my garden have already. Apply sunlight to them and they grow.
I'm getting tired of this 'earth isn't a closed system' BS; as if that is enough to explain how life started. It's not. What if I expand my sphere of the system boundary to include both the earth and the sun. Now wtf are you going to do? It's a closed system. Prove me wrong. Now.
You utterly failed to notice that the discussion was not about “explaining how life started”. It was about Granville Sewell's assertion that evolution violated the Second Law of Thermodynamics. And with the system a closed one including the sun, there is a huge increase of entropy as the sun radiates energy, and no violation of the 2LOT. Yawn. Back to the interesting posts.

Dr. Blow Torch · 26 February 2010

The weeds in my garden have already. Apply sunlight to them and they grow.
They have the machinery to _not_ blindly apply the energy.
You utterly failed to notice that the discussion was not about “explaining how life started”.
Until somebody can utterly explain how life got started with some energy flying around, this whole discussion is utterly useless, since the start of life is where the real action is and where the main violation of the 2nd Law would occur.

Dr. Blow Torch · 26 February 2010

The whole goal of all lifeforms everyday is: "How the hell can I keep from getting destroyed by the sun today? What tools do I have at my disposal to harness the sun for my own good, instead of getting fried by it?"

Mike Elzinga · 26 February 2010

Henry J said: Hey, does that mean I can raise my IQ by eating lots of burgers and fries?
And by just aging. Life's good! :-)

Joe Felsenstein · 26 February 2010

Dr. Blow Troll said: Until somebody can utterly explain how life got started with some energy flying around, this whole discussion is utterly useless, since the start of life is where the real action is and where the main violation of the 2nd Law would occur.
So glad you agree with us that Granville Sewell is wrong -- evolution after the start of life is in fact not a violation of the 2LOT. (Oh yes, and I'll have to tell all those weeds in my garden with chloroplasts that they should stay out of the sun). And oh yes, if the whole discussion is useless, why not avoid trolling in it? Now back to the interesting issues ...

Mike Elzinga · 26 February 2010

Joe Felsenstein said: So was it OK to say that growth of the weeds were a (local) decrease in entropy? (I'd guess yes -- they certainly increased their energy content)
Here it would depend on how energy is stored within the plant. How many energy states are involved in the storage of that energy? Does the number increase with energy input or decrease? How much energy gets dumped in that same time interval? If the answer is that the number of states increases, then we would say the entropy has increased. If the number of energy states decreased, then the entropy decreases. We are using the usual definition that the number of microstates is consistent with the macrostate of the entire system.

But I suspect it is also OK to note that the growth of the weeds, by catching some energy from the sun and delaying its loss to the surroundings, actually does not increase entropy overall, but somewhat delays its increase.

Even from the classical perspective, where we don’t have to know about the details of the “working medium” within the plant, this doesn’t make sense. The integral of dQ/T is into the system, and that is an increase of entropy if the net flux is into the system. If the plant dumps more energy than it takes in at the same temperature, then its entropy decreases. This is where the confusions and conflations begin to occur. The details of the number of microscopic states within the plant and any given instant have nothing to do with the overall organization of the plant. I think it is that overall organization, structure, complexity, or how this particular plant structure compares with its ancestors is what becomes of interest in discussing “information” about the plant compared with some baseline of measurement of “information.” It is somewhat like asking what is significant about a given dendritic structure of icicles compared with another structure that might just as well have occurred had some microscopic contingencies been different. The laws of thermodynamics chug along in either case, but the “information” about the structure is now in the eye of the beholder. Whenever a physicist gets into a complex problem, he finds it useful to strip down the complexity to the bare bones necessary to direct attention to the fundamental issue. So let’s go back to a scenario I raised on an earlier thread (I can’t find the thread at the moment). This was the problem of the difference between a highly elliptical orbit of a planet around a sun and a circular orbit. Getting from an elliptical orbit to a circular orbit requires the dissipation of energy, whether by gravitational tides that massage the planet and sun into dissipating energy ultimately in the form of heat or because other swarms of particles carried energy away. However it is done, entropy has decreased. But the further question that we can raise is “which orbital configuration carries more “information?” And here, it depends on what answer one is seeking. One way is to say that the elliptical orbit contains more information because it takes more parameters to describe it than it does for a circle. On the other hand, the circle reveals more about the history of the system provided we already know how circular orbits come about. We would very likely know, for example, that a solar system with circular orbits is older than one with highly elliptical orbits. And there is also the question about “order” and how that relates to “information.” But the point here is that these issues are pretty much independent of the fact that thermodynamics just chugs along. Getting back to the much more complicated system of a weed, the issues about what constitutes information are again not directly related to thermo chugging along. The more interesting issue, however, is what kind of organization, synchronization, self-organized criticality, or perhaps ill-understood emergent phenomenon is critical to making a system a living organism. We don’t have a good handle on that yet. Whatever that might be, there is no evidence in physics that would make us think that the laws of thermodynamics would be violated or that somehow entropy would become a property we could use to characterize such a system. We are off on the wrong track to associate entropy with being some kind of characterization of living systems. It is a big step in the direction of conflation that ID/creationists have been doing since Morris and Gish.

raven · 26 February 2010

Blind application of heat (energy) is not sufficient to form anything interesting and is usually destructive, like 99.999999999% of the time.
Tell that to the plants. There is a reason they are green. Almost our entire biosphere depends on plants capturing sunlight to make more plants.
I’m getting tired of this ‘earth isn’t a closed system’ BS; as if that is enough to explain how life started. It’s not. What if I expand my sphere of the system boundary to include both the earth and the sun. Now wtf are you going to do? It’s a closed system.
No it isn't. If you say a dog has 5 legs, how many legs does a dog have? Four, saying a dog has 5 legs doesn't mean dogs have 5 legs. The boundary of a system isn't whatever you want it to be. It actually means something in reality. If the earth and sun were a closed system, we would have long ago fried because all the energy radiated by the sun would have nowhere to go.

Eric Finn · 26 February 2010

Joe Felsenstein said: But I suspect it is also OK to note that the growth of the weeds, by catching some energy from the sun and delaying its loss to the surroundings, actually does not increase entropy overall, but somewhat delays its increase. Don't all object at once!
Entropy is an extensive quantity and we may expect entropy to increase as the system grows. Here growing means that we add atoms to our system, which in this case is a weed. Surely, the entropy of the “system of weeds” increases, as weeds grow. Similarly, the entropy of the “system of humans” increases, as the population grows. Chemical reactions are ordinarily described using equation with the same amount of atoms on both sides of the equation. This might suggest another definition for the system to study. We start with the existing weed, carbon dioxide, water and some minerals and see what happens, when we add energy from the Sun. After rather involved chemical reactions the weed grows and oxygen is released. This is during the day, when energy from the Sun is available. Much the opposite reactions take place during the night. Let’s discuss a similar (although not truly analogous) case of iron rusting. We can use tabulated values for the entropies of iron (solid), oxygen (gas) and rust (solid) to find out that the entropy of rust is lower than the combined entropies of oxygen gas and iron. A spontaneous chemical reaction violates the second law of thermodynamics? Well, not quite so. We should concentrate on keeping track of the energy and it turns out that energy is released in the reaction. According to the equation dS=dQ/T the entropy of the environment has increased more than the entropy of iron + oxygen has decreased. Now, let us combine these two examples using a simple mental picture. Imagine a smooth valley and a ball kicked in. Eventually the ball settles on the bottom. However, before settling the ball needs to dissipate its kinetic energy. This is where the second law of thermodynamics enters the scene. The valley receives an amount of energy rising its temperature. This mental picture applies to iron rusting. Next, we shall modify the landscape by adding a depression somewhere uphill. The ball is originally at the bottom, but it is then kicked towards the depression. If the ball loses its kinetic energy in a right way, then it can end up stationary in the depression. Now the ball has potential to do work, if released using a small amount of energy (activation energy). Similarly, plants store some of the energy they receive from the Sun by forming sugars. No violation of the second law of thermodynamics anywhere. And yes, it appears to delay the increase in the entropy of the environment – at least according to this crude mental picture. P.S. I noted the answer from Mike Elzinga just before sending mine, but decided to send an entry anyway.

Rolf Aalberg · 26 February 2010

Dr. Blow Torch said: You guys are all dumb as a box of rocks. You can apply heat all day long to a lava lamp and even a simple cube of lava will never be formed. You might get something that approaches a sphere once in a while, but not a cube. Blind application of heat (energy) is not sufficient to form anything interesting and is usually destructive, like 99.999999999% of the time. Prove me wrong. Now. I'm getting tired of this 'earth isn't a closed system' BS; as if that is enough to explain how life started. It's not. What if I expand my sphere of the system boundary to include both the earth and the sun. Now wtf are you going to do? It's a closed system. Prove me wrong. Now.
Staring out with "You guys are all dumb as a box of rocks" isn't the best way if you have the slightest intention of being taken seriously. But let me, a layman, follow your way of thinking - why stop at the solar system, let's make our the whole universe our system. Using your mode of expression and thinking: Now wtf is going to happen? Nothing, it's a closed system. No energy in - no energy out, it's all static, right? A zero sum system. Weep, we are not her, it's an illusion. I suggest you either have religious/ideological mental blinds or you just don't know what you are talking about. Or more likely both. Sorry for responding to the troll. I've read other things in this thread too and have learned a lot.

Dan · 26 February 2010

Dr. Blow Torch said: You can apply heat all day long to a lava lamp and even a simple cube of lava will never be formed. You might get something that approaches a sphere once in a while, but not a cube. Blind application of heat (energy) is not sufficient to form anything interesting and is usually destructive, like 99.999999999% of the time. Prove me wrong. Now.
I can't prove you wrong, because you're right. But what you say has nothing to do with evolution.

Dan · 26 February 2010

Joe Felsenstein said: I predict that some day we will also know how to bookkeep a connection between energy flows, increase of entropy and (cringes and ducks behind the sofa) some relevant measure of the “adaptive information” that has accumulated in the biosphere by evolution and growth of populations. Note I said “some day”, not right now.
I don't think so. Consider two systems both at temperature 0 degrees C. Apply the same amount of heat to them. The two will undergo the same increase in entropy. One of the systems is a block of ice and the other is a one of these antarctic fish that can withstand freezing. The first system melts and the second swims away. We need to know more than energy flows and entropy increases to find "adaptive information".

Dave Lovell · 26 February 2010

Dr. Blow Torch said: Blind application of heat (energy) is not sufficient to form anything interesting....
The manufacture of key parts of your computer suggests you are totally wrong with this assertion. In a magical process called "soldering", surface tension instantly produces tens of thousands of perfect and isolated connections as a result of the application of heat. Try also looking up an exotic metal working technique called "casting"

eric · 26 February 2010

Dr. Blow Torch said: You can apply heat all day long to a lava lamp and even a simple cube of lava will never be formed. You might get something that approaches a sphere once in a while, but not a cube.
If you're suggesting that the application of pressure and heat in nature can't make cubes, your alma mater should rescind that "Dr." Take salt water. Heat. You get cubes of NaCl.

Diogenes · 26 February 2010

Eric Finn said: Let’s discuss a similar (although not truly analogous) case of iron rusting. We can use tabulated values for the entropies of iron (solid), oxygen (gas) and rust (solid) to find out that the entropy of rust is lower than the combined entropies of oxygen gas and iron. A spontaneous chemical reaction violates the second law of thermodynamics? Well, not quite so. We should concentrate on keeping track of the energy and it turns out that energy is released in the reaction.
That's great Eric! I love that because the creationists always say that iron rusting is an example of disorder increasing! Do you have a reference for the fact that rust has lower intrinsic entropy than iron+oxygen? If you had a reference, it'd be great. You could debate the creos, wait for them to say, "Iron rusting is increasing disorder..." and then you go "GOTCHA!!"

Dan · 26 February 2010

Dr. Blow Torch said: The whole goal of all lifeforms everyday is: "How the hell can I keep from getting destroyed by the sun today? What tools do I have at my disposal to harness the sun for my own good, instead of getting fried by it?"
This explains why the antarctic plain is brimming with a riot of life, while the amazon basin is sterile and unproductive.

Diogenes · 26 February 2010

A creationist shows up, so now we have a real example of their mysticism.
Dr. Blow Chunks said: Blind application of heat (energy) is not sufficient to form anything interesting and is usually destructive...
When Dr. Blow Chunks brings up the subject of what he feels is "interesting", he's trying to hijack this discussion and force us to talk about his feelings about what's "interesting" and what's not. This is not a therapy group for superstitionists where we discuss your damn feelings. Scientists ONLY care about what can be DEFINED AND MEASURED OBJECTIVELY. The question here is whether living things violate 2LOT (they don't), and whether increasing-complexity is proportional to decreasing-entropy (it's not). IDiot: natural processes cannot produce complexity! Scientist: Counter-examples: Magnetization, crystallization, convection currents. IDiot: I don't feel those are complex! My mystic intuition says they're simple. You can't prove my feelings wrong! (Weeping hysterically) Let's talk about my feelings! We don't give a rat's ass what you feel. We've been through this with IDiots countless times. IDiots say that natural forces cannot make something that is "interesting" or that has "specified complexity" or some kind of undefined "info shminfo". When scientists provide real-world counter-examples, the IDiots reject them because their terminology is deliberately vague, permitting them to cheat and move their goal posts.
Dr. Blow Chunks said: Until somebody can utterly explain how life got started with some energy flying around, this whole discussion is utterly useless, since the start of life is where the real action is and where the main violation of the 2nd Law would occur.
Scientists are NOT disputing that living cells are more complex than dead matter. We are NOT disputing that humans are more complex than bacteria. We ARE disputing your assumption that local complexity increase (which you gauge by mystic intuition) is proportional to total entropy decrease (which can be measured.) They're not proportional. Your assumption is wrong, and it depends on your mystic intuitions which we don't care about anyway. You have no idea how matter and energy were arranged before the first cell, so you can't compute the entropy change. The appearance of the first living cell presumably involved an increase in complexity. But local complexity increase is not total entropy decrease. You just ASSUME that the appearance of the first cell violated 2LOT: an ASSUMPTION without evidence. Furthermore, you ignore the huge amounts of heat thrown off by chemical reactions, in which the entropy of the environment is increased, changing the total value. You have no intuitive sense of how much entropy is in the infrared radiation thrown off by the Earth into space; so your intuition is no guide as to total entropy change. But notice the IDiot bait-and-switch. IDiot: Evolution CANNOT happen, which I prove with this equation: X=X-1 for all X. Scientist: But if X = 2, then your equation becomes 2=1. Therefore your equation is wrong. IDiot: Waah, you say 2 is not 1 proves evolution, so you're as dumb as a box of rocks! But YOU HAVEN'T EXPLAINED THE APPEARANCE OF THE FIRST CELL, so you haven't explained anything! No, We haven't explained the origin of the first life form, but we have proven that your 2LOT argument is moronic, and we have proven that 2LOT is irrelevant to the appearance of the first life form.
Dr. Blow Chunks said: They [weeds growing] have the machinery to _not_ blindly apply the energy.
Above, I predicted the creationists would whip out the counter-argument that decreases of entropy are due to some kind of mystical "info shminfo" in living things and in man-made objects. Of course, they can't measure info shminfo and don't have an equation for it. It is not enough for creationists to rape thermodynamics, they must rape information theory too.

SWT · 26 February 2010

Dr. Blow Torch said: Blind application of heat (energy) is not sufficient to form anything interesting and is usually destructive, like 99.999999999% of the time. Prove me wrong. Now.
Exhibit 1: Hurricanes. These large, organized, and structured dynamic systems form spontaneously and are driven by heat. Exhibit 2: The Great Red Spot on Jupiter. See comments on Exhibit 1.

John Stockwell · 26 February 2010

Dr. Blow Torch said: You guys are all dumb as a box of rocks. You can apply heat all day long to a lava lamp and even a simple cube of lava will never be formed. You might get something that approaches a sphere once in a while, but not a cube. Blind application of heat (energy) is not sufficient to form anything interesting and is usually destructive, like 99.999999999% of the time. Prove me wrong. Now. I'm getting tired of this 'earth isn't a closed system' BS; as if that is enough to explain how life started. It's not. What if I expand my sphere of the system boundary to include both the earth and the sun. Now wtf are you going to do? It's a closed system. Prove me wrong. Now.
It's not a system in equilibrium. The issue is that biological systems are all systems that are not in equilibrium. Non-equilibrium thermodynamics is a different ballgame fromt the simplistic equilibrium thermodynamics strawmen that are demolished by creationists.

Joe Felsenstein · 26 February 2010

Re: the comments responding to Dr. Blow Torch:

OK, I was guilty of it myself, but **please** do not feed the troll!!

Henry J · 26 February 2010

But but but, trolls gotta eat! Otherwise they'd become an endangered species!11!!!one!

Eric Finn · 26 February 2010

Diogenes said: Do you have a reference for the fact that rust has lower intrinsic entropy than iron+oxygen? If you had a reference, it'd be great. You could debate the creos, wait for them to say, "Iron rusting is increasing disorder..." and then you go "GOTCHA!!"
First, anyone might by right, while claiming that iron rusting is an example of disorder increasing. It depends on how one defines order and disorder. Rust iron might be less useful in making tools than pure iron. On other occasions, the same anyone might seem to regard molecular complexity as a sign of order. Iron rusting represents increase in molecular complexity. It is very baffling. You will find the intrinsic entropies (J/K/mol) for iron, oxygen and rust e.g. here: http://chemistry.alanearhart.org/Courses/Docs/Handouts/thermo-entropy.pdf The reaction for rusting can be simplified as: 4Fe + 3O2 -- 2 Fe2O3 Using the molar entropies, one finds 4*27.3 + 3*205.1 -- 2*87.4 (J/K), or 724.2 -- 174.8 (J/K), a decrease of about 550 J/K (per 4 moles of iron and 3 moles of oxygen) This reaction will give out energy increasing the entropy of the environment (at 290 K) by 5670 J/K. I wish you luck, but I am not quite confident that a relatively simple fact could alone turn the debate in your favour. You might be advised to pay attention to the mutually conflicting, or changing definitions. Also, you should pay attention, if the “facts” have any bearing to the issue at hand. In the present thread, physicists have argued that the theory of biological evolution is fully compatible with thermodynamics. To my understanding, it boils down to noting that complex molecules can form, if there is energy available.

Henry J · 26 February 2010

To my understanding, it boils down to noting that complex molecules can form, if there is energy available.

Sounds right to me. Besides, if the 2nd law (or anything else) prevented complex molecules from forming, there wouldn't be growth or reproduction. Henry J

Mike Elzinga · 27 February 2010

Henry J said: Besides, if the 2nd law (or anything else) prevented complex molecules from forming, there wouldn't be growth or reproduction. Henry J
And we wouldn’t be here, and none of this would be happening. :-)

Rolf Aalberg · 27 February 2010

Can the issue be boiled down to "The 2LOT can not be violated (like all the rest of 'natural law') except by magic?

Joe Felsenstein · 27 February 2010

When I argued that energy flowing from the sun into plants, then later out to the rest of the universe represented a delay of increase of entropy (as compared to having no plants there) Mike Elzinga argued that
Even from the classical perspective, where we don’t have to know about the details of the “working medium” within the plant, this doesn’t make sense. The integral of dQ/T is into the system, and that is an increase of entropy if the net flux is into the system. If the plant dumps more energy than it takes in at the same temperature, then its entropy decreases.
while Eric Finn said (discussing an analogy to balls moving on a surface)
And yes, it appears to delay the increase in the entropy of the environment – at least according to this crude mental picture.
These appear to be different conclusions. My own guess is closer to the latter. As a theoretician I would like there to be some way to discuss this that does not involve a full understanding of the complexities of the plants, though that appears to be what Mike is calling for (in the rest of his comment). Suppose the plants grow by simply making more of the same stuff, and that this goes along with them containing more energy (proportionally). And we compare this to a situation where everything is the same except that there are rocks there instead of plants, and the rocks are simply heated by the run. In which of these case is there more increase in entropy?

Joe Felsenstein · 27 February 2010

Typo. I meant to write:

“and the rocks are simply heated by the sun.”

Mike Elzinga · 27 February 2010

Joe Felsenstein said: And we compare this to a situation where everything is the same except that there are rocks there instead of plants, and the rocks are simply heated by the run. In which of these case is there more increase in entropy?
I think the difference between what I said and what Eric said is only a slight quibble. Eric was saying something analogous to there being an input of energy that is temporarily stored within the plant and then dumped later into its surroundings. During that time the plant’s entropy increased. The question about what happens during the subsequent dump is also an issue, because at first glance it appears that the plant’s entropy decreases. But we still have to know what the energy inputs to the plant are occurring during the time of dumping. My point was that dQ/T was into the plant so the plant’s entropy increased. Because the plant is also contained within the environment, there is an overall increase in entropy even if there was no increase going on in the surroundings. Referring back to my longer post about those volume and surface integrals in Sewell’s Appendix D; when discussing energy and entropy, one must account for all processes that are doing work, exchanging energy, and storing energy when looking at a system of any kind, plants included. There are also chemical reactions going on inside the plant, water and chemical compounds are being exchanged with the plant’s surroundings. The main difficulty here, I suspect, is that we are looking at non-equilibrium situations but thinking in terms of equilibrium. It is not as big a problem as it first seems if we simply look at time intervals that are small enough for the processes to be quasi-static on those scales. The rock example is a little like what I think Eric was referring to. We heat the rocks, and then put them into our sleeping bag at night to keep warm. There is a delay in which the energy from the rocks is dumped into the sleeping bag. But we are talking about energy, not entropy. Note also that the temperatures are going up during warming and going down during cooling. Entropy in the system and its environment is still increasing unless during that same interval more energy is dumped than is accumulated within the bubble surrounding the system and its environment.

Mike Elzinga · 27 February 2010

Let me try to put in another point about the difference between energy and entropy. When we talk about delays in energy exchanges, this does not imply delays in entropy “exchanges.” Energy can be stored and carried from place to place; it can be absorbed and released at different times.

Entropy, on the other hand, refers to one of the states of a system. Even though we can play around with “entropy flows”, we are always talking about the instantaneous state of a system and its surroundings.

If we pick small enough time intervals in which temperatures have not had time to change – i.e. they are effectively constant - then mathematically energy and entropy can be treated the same. But they mean completely different things; be sure you understand the difference.

I didn’t read Eric reply very carefully, so I missed the fact that he said entropy while thinking of energy.

I was distracted because I was also looking at this “discussion” on UD during this discussion; trying to analyze the misconceptions over there. Good grief; what a mess of confusions and conflations!

Eric Finn · 27 February 2010

Joe Felsenstein said: These appear to be different conclusions. [...] Suppose the plants grow by simply making more of the same stuff, and that this goes along with them containing more energy (proportionally). And we compare this to a situation where everything is the same except that there are rocks there instead of plants, and the rocks are simply heated by the run. In which of these case is there more increase in entropy?
I think part of the apparent disagreement may lie in the way the boundary between the system and the environment is defined. I preferred to define the system containing the existing plant plus necessary ingredients for its growth (carbon dioxide, water and minerals). I wanted to keep the system closed (no exchange of matter), at least for a while. This system receives an amount of energy and ends up containing a slightly bigger plant plus some left-over oxygen. The system received energy and its entropy increased. If we wish to get rid of the oxygen, we need to dump it in the environment, thus decreasing the entropy of the system an increasing the entropy of the environment. I am not quite sure, how the entropy change should be calculated (E=mc2?). Later on, when a rabbit eats the plant (and destroys the structure of our nice system), some more energy is released and the entropy increases. The increase in the entropy would be the same, were the molecules just floating around without forming sugars as an intermediate step. It is very hard to see, how thermodynamics could be any obstacle to evolution, or even for abiogenesis.
Mike Elzinga said: I think the difference between what I said and what Eric said is only a slight quibble.
I agree. The example of a rock storing energy and later releasing it is a good one.
Mike Elzinga said: I didn’t read Eric reply very carefully, so I missed the fact that he said entropy while thinking of energy.
In fact, I did equate energy and entropy in the sense dS=dQ/T at system boundaries. My crude mental analogue did not have internal energy states (for the ball).

Henry J · 27 February 2010

when a rabbit eats the plant (and destroys the structure of our nice system),

Wascally wabbit!

fnxtr · 27 February 2010

... and then the fox eats the rabbit and then the fox dies and the maggots eat the fox carcass... ad infinitum.

Mike Elzinga · 27 February 2010

Eric Finn said: It is very hard to see, how thermodynamics could be any obstacle to evolution, or even for abiogenesis.
No working physicist or chemist I know of believes that thermodynamics is an “obstacle” to evolution or abiogenesis. But I am not sure how far one can go in trying to think up colloquial examples and explanations from thermodynamics for the layperson. I’ve tried a number of times over the years and have always come away from the exercise feeling frustrated and unsatisfied. It can be fun to try, but it’s far harder than it first appears. It’s not that the layperson is too stupid (many are indeed very intelligent). It’s that, at the very minimum, one needs the tools of mathematics. Many of the ideas require a substantial background of conceptual and quantitative understanding of basic classical physics and the ways physicists talk about “phase space.” And we aren’t even into quantum mechanics at this point. So I have tended to fall back on just the bookkeeping of energy and the 2nd law by trying to find relatively homey examples from classical physics to illustrate the concepts. Besides, there are too many definitions of entropy; and invariably someone is going to start bringing these up and start conflating them while losing track of the underlying physics. In every discussion I can find online, and in those I have seen in the past, no one seems to be aware of the facts of condensed matter physics, chemistry, and all the phenomena one finds in organic chemistry. These facts just never appear in any discussion; yet it is all around for everyone to observe as they hammer on their keyboards, drink water, and wipe off their eyeglasses. In my opinion, that is where the focus should be instead of on entropy. But I could be wrong.

SWT · 27 February 2010

Mike Elzinga said:
Eric Finn said: It is very hard to see, how thermodynamics could be any obstacle to evolution, or even for abiogenesis.
No working physicist or chemist I know of believes that thermodynamics is an "obstacle" to evolution or abiogenesis.
Using these comments to springboard back to the original post, I find it telling that Sewell's previous essay was entitled "Can 'ANYTHING' Happen in an Open System?" -- as though the the choice was either that evolution can't happen or that there are no constraints at all on how organized systems can form and change through time.

fnxtr · 27 February 2010

SWT said:
Mike Elzinga said:
Eric Finn said: It is very hard to see, how thermodynamics could be any obstacle to evolution, or even for abiogenesis.
No working physicist or chemist I know of believes that thermodynamics is an "obstacle" to evolution or abiogenesis.
Using these comments to springboard back to the original post, I find it telling that Sewell's previous essay was entitled "Can 'ANYTHING' Happen in an Open System?" -- as though the the choice was either that evolution can't happen or that there are no constraints at all on how organized systems can form and change through time.
Yeah, there's an edge to evolution, but it isn't what Behe and his clown college pretend it is.

Joe Felsenstein · 28 February 2010

SWT said: Using these comments to springboard back to the original post, I find it telling that Sewell's previous essay was entitled "Can 'ANYTHING' Happen in an Open System?" -- as though the the choice was either that evolution can't happen or that there are no constraints at all on how organized systems can form and change through time.
Sewell was arguing (correctly) that just because entropy increases in one part of an open system, this would not bring about a decrease of entropy in another part of the system (the part that is life evolving). There has to be some flow of energy between the two parts in order for that to happen. So yes, it is not true that anything can happen in an open system. Having made that valid point, he then descended to utter silliness by noting that what is flowing between the rest of the system and life is merely “radiation”! As if that was uninteresting and unimportant, and as if it would not enable an evolving biosphere to survive and grow!

Mike Elzinga · 28 February 2010

Joe Felsenstein said: Sewell was arguing (correctly) that just because entropy increases in one part of an open system, this would not bring about a decrease of entropy in another part of the system (the part that is life evolving).
What is this idea about evolving life that requires the entropy of the system that is evolving to be decreasing? This appears to me to be some kind of assumption based on the misconception that order and information are related to the entropy of thermodynamics. What is the understanding of the information theorists about this? I don’t think they are using entropy in the same way physicists understand it, and I don’t see what this has to do with thermodynamics. Is this about the clustering of atoms and molecules, in which case the entropy of the clustered constituents is less because they shed energy? If so, how is this any different from any case of condensing matter?

Joe Felsenstein · 28 February 2010

Mike Elzinga said: (in response to me talking about evolution involving a (local) decrease of entropy). What is this idea about evolving life that requires the entropy of the system that is evolving to be decreasing? This appears to me to be some kind of assumption based on the misconception that order and information are related to the entropy of thermodynamics. What is the understanding of the information theorists about this? I don’t think they are using entropy in the same way physicists understand it, and I don’t see what this has to do with thermodynamics. Is this about the clustering of atoms and molecules, in which case the entropy of the clustered constituents is less because they shed energy? If so, how is this any different from any case of condensing matter?
I suspect we are going to go in a “does too! ... does not!” circle here. I do hope (rather than know) that there is a connection between thermodynamic entropy and the entropy used in information theory, particularly mutual information. I do think that the evolution of a biosphere involves catching energy from the sun the delaying its journey outward to the rest of the universe, relative to what happens if you have no biosphere. All this will probably strike you as impossibly woolly-minded. Nevertheless I have hopes for a more concrete connection between information and entropy in models of large-scale evolution.

Mike Elzinga · 28 February 2010

Joe Felsenstein said: I do think that the evolution of a biosphere involves catching energy from the sun the delaying its journey outward to the rest of the universe, relative to what happens if you have no biosphere. All this will probably strike you as impossibly woolly-minded. Nevertheless I have hopes for a more concrete connection between information and entropy in models of large-scale evolution.
From the perspective of a condensed matter physicist, I would be more inclined to look for emergent phenomena that involve synchronization or correlation of events throughout the complex system. This is the kind of stuff we see at every level of complexity already. Whether this would be a more complicated manifestation of self-organizing criticality, or emergent interactions among webs of complex structures, or autocatalytic events, or something we haven’t noticed yet, there is nothing in chemistry or physics that we already know about that suggests things like “delayed” transfer of entropy. I’m not quite sure what such an idea means. Delays in the capture, storage and release of energy happen all the time. In fact, whatever mechanisms we discover that are critical to making complex systems “alive”, we would expect to see coordinated matter and energy exchanges among subsystems. I’m not objecting to finding better ways to characterize complex systems; I think it is extremely important to find tools and perspectives that highlight phenomena we currently have difficulty recognizing and describing. My main concern is about hauling in misconceptions or concepts that conflict with the basic stuff we already know and have demonstrated repeatedly in complex systems that we currently understand. It muddles the research. But, on the other hand, that’s pretty much the history of frontier research; vast expanses of confusion and dead ends, but finally a breakthrough that makes us wonder why we didn’t see it all before. So, carry on. :-)

Dan · 28 February 2010

Joe Felsenstein said: I do hope (rather than know) that there is a connection between thermodynamic entropy and the entropy used in information theory, particularly mutual information.
Well, there certainly is some connection, but it's not a strong one. The second law of thermodynamics states that entropy of the universe always increases. (That is, thermodynamic or statistical mechanical entropy.) Entropy can decrease in one place (for example it's decreasing in the sun) if that decrease is counterbalanced by a larger increase elsewhere in the universe (for example in the cosmic microwave background). There is no such law for information entropy. Every publication of a new issue of Physical Review Letters involves the creation of new information. There is no requirement for the destruction of information somewhere else in the universe to make up for it.

Henry J · 28 February 2010

I do hope (rather than know) that there is a connection between thermodynamic entropy and the entropy used in information theory, particularly mutual information.

A connection, maybe, but a huge difference - thermodynamics involves the energy state of all the molecules in organisms and their surroundings. Information (if that's a reference to DNA) is but a tiny subset of that. Henry J

Mike Elzinga · 1 March 2010

Dan said: There is no such law for information entropy. Every publication of a new issue of Physical Review Letters involves the creation of new information. There is no requirement for the destruction of information somewhere else in the universe to make up for it.
It didn’t occur to me until I thought about that paragraph that this may be just what the creationists are trying to do; destroy more information than the science community can create.

eric · 1 March 2010

Mike Elzinga said: Delays in the capture, storage and release of energy happen all the time. In fact, whatever mechanisms we discover that are critical to making complex systems “alive”, we would expect to see coordinated matter and energy exchanges among subsystems.
I think we can be more broad than that: capture and release of energy must result in some of the energy being transformed for all systems, not just biological ones. Nontransformation would mean energy was transferred though some media with 100% efficiency. Of course, by transformation what I'm referring to is commonly called "loss" or "waste," but one man's waste is another man's battery, to steal a phrase. (Figuratively speaking - if you've figured out a way to take that literally, I don't want to know about it...)

Mike Elzinga · 1 March 2010

eric said: I think we can be more broad than that: capture and release of energy must result in some of the energy being transformed for all systems, not just biological ones. Nontransformation would mean energy was transferred though some media with 100% efficiency. Of course, by transformation what I'm referring to is commonly called "loss" or "waste," but one man's waste is another man's battery, to steal a phrase. (Figuratively speaking - if you've figured out a way to take that literally, I don't want to know about it...)
The existence of extremophiles deep within the earth suggests some very interesting ideas about how and where life got started. It is possible that it started in far more extreme environments than was previously suspected. In those extreme environments, there is a much broader range of energies in the energy cascades taking place there. Somewhere along those cascades, there are very likely many permutations and combinations of complex processes feeding off the energy “leaking off” those cascades, some of which could very well lead to living organisms.

SWT · 5 March 2010

Joe Felsenstein said:
SWT said: Using these comments to springboard back to the original post, I find it telling that Sewell's previous essay was entitled "Can 'ANYTHING' Happen in an Open System?" -- as though the the choice was either that evolution can't happen or that there are no constraints at all on how organized systems can form and change through time.
Sewell was arguing (correctly) that just because entropy increases in one part of an open system, this would not bring about a decrease of entropy in another part of the system (the part that is life evolving). There has to be some flow of energy between the two parts in order for that to happen. So yes, it is not true that anything can happen in an open system.
Perhaps, but I think this argument gets the causality exactly backwards. Dissipative structures are entropy sources, and one of the constraints how long such a structure can persist is whether or not there is someplace for that entropy to go. I can't think of anyone who claims that an entropy increase one part of a system necessarily causes a decrease in entropy somewhere else; entropy is not a conserved quantitiy in the way that mass and energy are conserved in classical mechanics. The usual argument is instead that dissipative structures can form spontaneously due to gradients in temperature, chemical potential, etc. and that these systems ultimately cause an increase in the entropy of their surroundings. Note also that this self-organization can occur in closed systems; however, the dissipative structure cannont persist indefinitely in a closed system. Matter and/or energy must pass through the system to maintain a dissipative structure, otherwise it sort of winds down.

Joe Felsenstein · 5 March 2010

SWT said:
Joe Felsenstein said:
SWT said: Using these comments to springboard back to the original post, I find it telling that Sewell's previous essay was entitled "Can 'ANYTHING' Happen in an Open System?" -- as though the the choice was either that evolution can't happen or that there are no constraints at all on how organized systems can form and change through time.
Sewell was arguing (correctly) that just because entropy increases in one part of an open system, this would not bring about a decrease of entropy in another part of the system (the part that is life evolving). There has to be some flow of energy between the two parts in order for that to happen. So yes, it is not true that anything can happen in an open system.
Perhaps, but I think this argument gets the causality exactly backwards. Dissipative structures are entropy sources, and one of the constraints how long such a structure can persist is whether or not there is someplace for that entropy to go. I can't think of anyone who claims that an entropy increase one part of a system necessarily causes a decrease in entropy somewhere else; entropy is not a conserved quantitiy in the way that mass and energy are conserved in classical mechanics. The usual argument is instead that dissipative structures can form spontaneously due to gradients in temperature, chemical potential, etc. and that these systems ultimately cause an increase in the entropy of their surroundings. Note also that this self-organization can occur in closed systems; however, the dissipative structure cannont persist indefinitely in a closed system. Matter and/or energy must pass through the system to maintain a dissipative structure, otherwise it sort of winds down.
I am not sure whose argument is the one you are saying “gets the causality exactly backwards”. I agree about dissipative structures (being one myself). Sewell was erecting a straw man by equating the usual argument with one that allowed anything to happen in a closed system. He then proceeded to ignore the importance of the flow of “radiation” into the biosphere. His argument, if accepted, would leave us forced to conclude that when weeds grow, the Second Law is violated.

SWT · 5 March 2010

I was referring to Sewell's argument as summarized in the first of your sentences that I quoted. Sorry to have been unclear.

Mike Elzinga · 5 March 2010

Joe Felsenstein said: Sewell was erecting a straw man by equating the usual argument with one that allowed anything to happen in a closed system. He then proceeded to ignore the importance of the flow of “radiation” into the biosphere. His argument, if accepted, would leave us forced to conclude that when weeds grow, the Second Law is violated.
I suspect Sewell actually believes what you refer to as his straw man. If you look over all ID/creationist writings and arguments about how matter interacts, the underlying misconception that runs through all their arguments is that it's all chaos down there at the atomic and molecular level. Dembski’s calculations betray this notion, Abel’s “spontaneous molecular chaos”, and all the other ID/creationist arguments about the probability of abiogenesis and evolution have this assumption at their base. “Entropy barriers” apparently prevent order from proceeding above a certain level of complexity; though they never say at what level. So, according to their misconceptions (misrepresentations?) something has to “flow” through the system of atoms and molecules creating order. According to them, that can’t be radiation or energy of any kind because that is supposed to simply contribute to the chaos. So it has to be “information.” Then you get such silly things as Philip Bruce Heywood’s “superconduction” plus the Earth, Sun, Moon gravitational system imparting intelligence to electrons. “Information” can easily be attributed to intelligence, therefore “intelligent design.” I don’t know why this thread of ID/creationist misconceptions - about how matter interacts and condenses - is not mentioned very often these days. That link between creationism and intelligent design was picked up by physicists years ago. But I keep seeing the counter-argument returning to the differences between open and closed systems. That counter-argument simply plays into the hands of the ID/creationists because they pull out their old “inflow of energy just makes things worse” argument. But that “gotcha” argument simply reveals their fundamental misconceptions about condensed matter, chemistry, and the laws of thermodynamics. The thread is crystal clear; even clearer than “cdesign proponentsists.”

Joe Felsenstein · 5 March 2010

Mike Elzinga said: I suspect Sewell actually believes what you refer to as his straw man. If you look over all ID/creationist writings and arguments about how matter interacts, the underlying misconception that runs through all their arguments is that it's all chaos down there at the atomic and molecular level. Dembski’s calculations betray this notion, Abel’s “spontaneous molecular chaos”, and all the other ID/creationist arguments about the probability of abiogenesis and evolution have this assumption at their base. ... So, according to their misconceptions (misrepresentations?) something has to “flow” through the system of atoms and molecules creating order. According to them, that can’t be radiation or energy of any kind because that is supposed to simply contribute to the chaos. ... I don’t know why this thread of ID/creationist misconceptions - about how matter interacts and condenses - is not mentioned very often these days. That link between creationism and intelligent design was picked up by physicists years ago. But I keep seeing the counter-argument returning to the differences between open and closed systems. That counter-argument simply plays into the hands of the ID/creationists because they pull out their old “inflow of energy just makes things worse” argument. ...
That is worth paying attention to. But they are also very quick to point to any case where they can argue that they have a serious scientific argument that scientists refuse to answer. So I think the discussion of open and closed systems is necessary. That could be combined with your points. However, they are painting all of science (especially evolutionary biology) as corrupt, oppressive, and intellectually bankrupt -- about to collapse any minute now. Their students are told that we have no answers to their powerful technical arguments. In addition to connecting the dots about this image of molecular chaos, we have to have sound and clear technical answers to their ostensibly-technical arguments, even if those arguments are, at root, theology.

Mike Elzinga · 5 March 2010

Joe Felsenstein said: But they are also very quick to point to any case where they can argue that they have a serious scientific argument that scientists refuse to answer. So I think the discussion of open and closed systems is necessary. That could be combined with your points. However, they are painting all of science (especially evolutionary biology) as corrupt, oppressive, and intellectually bankrupt -- about to collapse any minute now. Their students are told that we have no answers to their powerful technical arguments. In addition to connecting the dots about this image of molecular chaos, we have to have sound and clear technical answers to their ostensibly-technical arguments, even if those arguments are, at root, theology.
In the 40+ years I have watched them, I get the impression that one of their primary objectives is to leverage “respectability”, “credibility”, and fame from their mud-wrestles with scientists. They don’t appear to be fazed by crushing technical arguments; their following only sees their heroes as “being in the game and defeating everything that can be thrown at them.” So I think we need to be careful not to hand them our coattails. Frank J frequently makes the point of emphasizing the profound differences within the ranks of ID/creationists about “scientific” details such as the age of the earth and universe as well as their “theological” differences. In every debate I have seen over the years, ID/creationists have always been keen to tie the hands of any scientist by forcing a debate agreement that religion will not be part of the “scientific debate.” So we know they are sensitive about this. ID/creationists have to be dealt with on multiple fronts without giving them the credibility and respectability they crave and most certainly have not earned. Theirs is a pseudo-science both in terms of its concepts and in the way it is marketed. That needs to be hammered home as well.

Robert Oerter · 10 March 2010

I haven't read all the comments on this post, but the fact is that Granville has a better understanding of entropy than many of the pro-evolution respondents, including, I'm afraid, Joe Felsenstein.

The argument that inflow of energy from the sun just makes things worse is, in fact, correct. It is actually the OUTFLOWING energy - usually ignored by both sides - that fixes things up as far as the 2LOT.

Simple example: Think of a pond full of liquid water on a cold winter's night. The water spontaneously DECREASES its entropy and turns into ice. How does it accomplish this? By losing energy "through the boundary", i.e., into the environment, by way of radiation, conduction, evaporation, etc. This outflow of energy involves a corresponding INCREASE of entropy of the environment.

The earth is similarly radiating energy constantly into outer space. This outflow of energy creates a corresponding INCREASE of entropy of the "environment" (outer space) that more than compensates for any decrease of entropy here on earth.

(BTW, I have never seen any creationist exhibit a calculation showing where this supposed decrease of entropy is, and how big it is.)

I have more details, including some of the math, at the following website:
http://physics.gmu.edu/~roerter/EvolutionEntropy.htm

Mike Elzinga · 10 March 2010

Robert Oerter said: I haven't read all the comments on this post,...
Obviously you haven’t, because a number of us in these discussions have a pretty good handle on the accountancy of energy; far, far better than the erroneous arguments the ID/creationists have been pushing since Morris and Gish. We have encountered that "gotcha" retort from ID/creationists many times over 40+ years of attempts to get them to correct their misconceptions and mischaracterizations. Before you get the idea that creationists have any insight into thermodynamics and the concept of entropy, you might also check the Entropy and Evolution discussion. You might also want to check out the fields of condensed matter and organic chemistry. Go back and read this entire thread and the link I gave above. In that linked discussion you will also find links I made to previous discussions. Thermodynamics and entropy have been discussed in considerable detail on these threads; and our understanding of these is not what you apparently think.

Mike Elzinga · 10 March 2010

Robert Oerter said: I have more details, including some of the math, at the following website: http://physics.gmu.edu/~roerter/EvolutionEntropy.htm
The point is NOT to bamboozle laypersons with math. If you really understand thermodynamics and the concept of entropy, you should be able to use classical analogs and carefully chosen verbal illustrations. And further back up this thread we already took Sewell to task for his mathematical misconceptions; and we did it without the pretentiousness of splattering the discussion with mathematical equations. The code for the posting of equations has been turned off on this site. And the reason is very likely to encourage clear explanation rather than dazzling displays of mathematics that hide misconceptions.

stevaroni · 10 March 2010

Robert Oerter said: I haven't read all the comments on this post, but the fact is that Granville has a better understanding of entropy than many of the pro-evolution respondents, including, I'm afraid, Joe Felsenstein.
The problem we're having, Robert, isn't so much that we don't understand classical thermodynamics, but rather that we're trying to address this weird pseudo-science creationist argument that mixes well understood heat flow laws with nonsensical "information theory' arguments. When physicists say "entropy" they mean heat distribution mitigating against the extraction of useful work. When creationists say "entropy", they mean chaos. Or maybe they mean random data. Or, more likely, they just mean "sciency sounding argument stuff". While they may call their argument 'thermodynamics', it has nothing to do with the real discipline. Which is why Joe is attempting to show how silly their argument is by applying their version of it to plant growth.

Robert Oerter · 10 March 2010

Mike:

On the one hand you accuse me of bamboozling with math, and on the other hand you point me to a post that is full of ... math. Hmmm.

Actually, the PZ Myers post you linked to makes exactly the same point as my article I linked to (though he says it much more elegently): a simple calculation of the entropies involved shows how ridiculous is the creationist claim.

Let me point out that I did NOT put any equations in my post, rather, I DID cite a very simple example that anyone can understand: the freezing of a pond.

My point is that many folks on "our side" - the scientists - get the answer WRONG, or at least incomplete. And if the scientists and their defenders are making incorrect arguments, that plays into the hands of the anti-science forces.

So here it is once more for emphasis:

WRONG ANSWER: Entropy is not an issue for evolution because the earth is not a closed system: it gets energy from the sun.

RIGHT ANSWER: Entropy is not an issue for evolution because the earth is not a closed system: it gets energy from the sun AND RE-RADIATES THAT ENERGY INTO SPACE. A proper accounting of entropy must include BOTH processes. The absorption of energy from the sun does indeed "make the problem worse", but taking the re-radiation into account more than makes up for it.

Kevin B · 10 March 2010

Robert Oerter said: Mike: On the one hand you accuse me of bamboozling with math, and on the other hand you point me to a post that is full of ... math. Hmmm. Actually, the PZ Myers post you linked to makes exactly the same point as my article I linked to (though he says it much more elegently): a simple calculation of the entropies involved shows how ridiculous is the creationist claim. Let me point out that I did NOT put any equations in my post, rather, I DID cite a very simple example that anyone can understand: the freezing of a pond. My point is that many folks on "our side" - the scientists - get the answer WRONG, or at least incomplete. And if the scientists and their defenders are making incorrect arguments, that plays into the hands of the anti-science forces. So here it is once more for emphasis: WRONG ANSWER: Entropy is not an issue for evolution because the earth is not a closed system: it gets energy from the sun. RIGHT ANSWER: Entropy is not an issue for evolution because the earth is not a closed system: it gets energy from the sun AND RE-RADIATES THAT ENERGY INTO SPACE. A proper accounting of entropy must include BOTH processes. The absorption of energy from the sun does indeed "make the problem worse", but taking the re-radiation into account more than makes up for it.
You are, I'm afraid, merely quibbling about the details. There is a much more fundamental issue that you definitely don't get... WRONG ANSWER: Granville Sewell has a valid argument. RIGHT ANSWER: Granville Sewell is playing "find-the-lady" with a lot of dodgy assertions, to obscure the fact that the "excess energy" in the system (due to the sun) is taken into account, there is no problem at all in finding the energy "lost" to entropy as biological systems live (and evolve). That there is so much energy that the seas would boil if it didn't mostly get reradiated is a very trite secondary observation.

SWT · 10 March 2010

Robert Oerter said: I haven't read all the comments on this post, but the fact is that Granville has a better understanding of entropy than many of the pro-evolution respondents, including, I'm afraid, Joe Felsenstein. The argument that inflow of energy from the sun just makes things worse is, in fact, correct. It is actually the OUTFLOWING energy - usually ignored by both sides - that fixes things up as far as the 2LOT. Simple example: Think of a pond full of liquid water on a cold winter's night. The water spontaneously DECREASES its entropy and turns into ice. How does it accomplish this? By losing energy "through the boundary", i.e., into the environment, by way of radiation, conduction, evaporation, etc. This outflow of energy involves a corresponding INCREASE of entropy of the environment. The earth is similarly radiating energy constantly into outer space. This outflow of energy creates a corresponding INCREASE of entropy of the "environment" (outer space) that more than compensates for any decrease of entropy here on earth. (BTW, I have never seen any creationist exhibit a calculation showing where this supposed decrease of entropy is, and how big it is.) I have more details, including some of the math, at the following website: http://physics.gmu.edu/~roerter/EvolutionEntropy.htm
While I appreciate your good intenttions, I must respectfully disagree with some of what you're saying. None of the PT pro-evolution respondents have seriously believed that there were different kinds of entropy, and when Sewell tries to discuss the entropic effects associated with, for example, concentration gradients he doesn't even get the units right. If the serious conceptual problems creationists have with entropy could be cured by simple calculations, PZ's post about Styer's paper would have done the trick. (Dan Styer even participated in that discussion.) No matter how carefully you explain it, creationists seem intent on confusing the information measure Shannon called entropy (by analogy with statistical thermodynamics) with thermodynamic entropy. No matter how carefully you explain it, creationists refuse to recognize that dissipative structures spontaneously form and are maintained by energy (entropy) flows through the region where the dissipative structure exists. No matter how you carefully explain it, creationists seem intent on maintaining that the second law applies to entropy as used by Shannon. No matter how carefully you explain it, creationists would have you believe that the "entropy" of a functional genome is always lower than the "entropy" of a non-functional genome.

Mike Elzinga · 10 March 2010

Robert Oerter said: Mike: On the one hand you accuse me of bamboozling with math, and on the other hand you point me to a post that is full of ... math. Hmmm. Actually, the PZ Myers post you linked to makes exactly the same point as my article I linked to (though he says it much more elegently): a simple calculation of the entropies involved shows how ridiculous is the creationist claim.
You were directed to that discussion precisely to show you we have been through this entire sequence before. If I seem a little brusque, it is because for 40+ years I and some of my colleagues feel we are dealing with collective Alzheimer’s disease among those defending science against the ID/creationists on just this subject of thermodynamics and the 2nd law. No sooner does a complete conversation and discussion of the central issues end, then it starts all over again as though no such discussion has ever transpired before. After 40+ years of dealing with this, one begins to feel that he is the only conscious individual alive. If you follow the sequence of the discussions there and on this thread, you will note that I and others have been zeroing in on conceptual errors and conflations by ID/creationists. Using mathematics is not going to help the layperson understand these fundamental misconceptions; nor will it untangle all the conflations the ID/creationists make among energy, entropy, and “information.” Attempting to argue about (dQ/T)in vs. (dQ/T)out is not going to mean anything to most laypersons. Those ideas are already at an abstract level considerably beyond the concepts of energy and energy accounting. And, as those of us who have watched and been involved in this “debate” over that last 40 years know, the second you introduce some mathematics, you not only loose your audience, you will taunt the ID/creationist into “upping the ante” by “trumping” you with “more advanced” mathematics that is pure gibberish. It is a game to impress his rube followers. You have to deal with fundamental misconceptions; and you have to do that with well-chosen classical (not quantum) examples and analogies that don’t add to further confusion down the line. It is not as easy as it looks. Every novice scientist or teacher who first comes into such a discussion wants to fire off his most impressive “mathematical cannon.” But that is an “ego thing’, and it sets up an arms race with ID/creationists. You have to analyze and understand the misconceptions and conflations clearly, and then find ways to address them verbally in a way that helps the layperson get these concepts right. Forget the math unless you are talking with those who understand the concepts and the math.

Mike Elzinga · 10 March 2010

Robert Oerter said: Let me point out that I did NOT put any equations in my post, rather, I DID cite a very simple example that anyone can understand: the freezing of a pond.
Since you teach some introductory physics courses as well as a Classical Mechanics course, here are a few suggestions from my years of grappling with conceptual issues with students and the general public with regard to evolution and thermodynamics. The skeleton outline of concepts that seems to work with the public and with introductory students is as follows: kinetic energy, potential energy, total energy, and falling into potential wells without bouncing back out. Then, as your freezing ice example illustrates, the general ideas from condensed matter physics that matter condenses, and when it does, energy must be released (falling into wells without bouncing back out). This is the general rule in the universe. And don’t forget organic chemistry examples. Have a few simple examples in which photons, phonons, and other particles carry energy away from condensing molecules. There are various kinds of potential wells, but don’t overlook Van der Waals potentials. For the ideas of looking inside the “working media” of thermodynamics, think up a few simple, classical “molecules” that can tumble, stretch, flex and spin; and calculate the number of ways energy can be stored in these. Then make a “gas” of these such that they can exchange energy with each other, with the walls of their “container” and with a “piston”. This last exercise is mostly for your own benefit and for your introductory physics students; you will not use any of the mathematics when talking with the general public. You will develop verbal descriptions using words the general public can understand. Don’t worry about quantum effects in the excitation of any of the modes of your “molecules.” If it comes up, you tell your public audience that some of these don’t “kick in” until fixed thresholds are reached. Most of the time it will never come up. Don’t start out any of your discussions with entropy. Do the energy bookkeeping, especially when collections of atoms are condensing into their mutual potential wells. When someone falls down a manhole, he doesn’t bounce back out because of the “splat effect” (humor) of broken bones, torn skin and other bodily damage. Frictional heating can be illustrated by a rattle-trap old car going down a washboard road and absorbing energy into all the loose things that vibrate, rattle around and fall off. “Information” does not have mass nor does it “interact” or exchange particles with other “information” or matter. Therefore work is not required to “produce information.” I think it was eric on this site who suggested the idea of the energy required to transmit six dots and three dashes. In some orders, the “information” content is high (SOS); in other orders, meaningless.

Jesse Johnson · 12 March 2010

Ugh,

Can't we find a way to embarrass creationists when they pull this stuff? I mean, really make them feel embarrassed? They should feel this way, but they don't. There is no such thing as a truly closed system (i.e. no net energy flux - except maybe the universe itself is closed) and as has stated many times in this thread, when not dealing with a closed system, it is possible to observe decreases in entropy. There had just better be a corresponding increase elsewhere and that increase had better be greater than or equal to the decrease that you witnessed.

But all of that is moot.

Find a way to implant a cute little kitten zygote into a dog's womb so that it grows, survives and the dog gives birth to a kitten. Heck, find a way to make the dog give birth to a kitten without any transplantation. You know what? The entropy of the universe will increase! It will increase whether the critter that was born was more complex or less complex than the mother. You raise entropy like crazy when you have kids.

TomS · 12 March 2010

I have seen responses from creationists to "there is no such thing as a truly closed system."

One of the responses is something like this: "If there is no closed system, then the statement of the 2LOT which refers to closed systems is pointless. You're just denying the whole of thermodynamics."

WHich response reminds me of the various non-existent idealizations in physics such as a frictionless surface.

Another is to say that the universe as a whole is a closed system.

Stanton · 12 March 2010

Jesse Johnson said: Ugh, Can't we find a way to embarrass creationists when they pull this stuff? I mean, really make them feel embarrassed? They should feel this way, but they don't.
That's because the typical creationist is shameless and supremely arrogant in their stupidity. In their stunted, and stupid minds, they are incapable of being wrong because they're lying to help Jesus.

Jesse Johnson · 12 March 2010

TomS said: I have seen responses from creationists to "there is no such thing as a truly closed system." One of the responses is something like this: "If there is no closed system, then the statement of the 2LOT which refers to closed systems is pointless. You're just denying the whole of thermodynamics." Which response reminds me of the various non-existent idealizations in physics such as a frictionless surface. Another is to say that the universe as a whole is a closed system.
Of course, the full statement of the 2nd law says nothing about open or closed systems. You nailed it right on the head. Frictionless surfaces are used as a teaching tool for first year physics students. "We'll worry about that next week, but for now, lets build on the complexity step by step." Closed systems are much the same in thermodynamics.
Stanton said: That’s because the typical creationist is shameless and supremely arrogant in their stupidity. In their stunted, and stupid minds, they are incapable of being wrong because they’re lying to help Jesus.
Lying for Jesus. They should start a club. I tend to think that the only way to embarrass them in the matter is for some of us to start acting like a cross between a scolding preacher and a scolding mother when they are caught red handed. On a somewhat unrelated note, a friend of mine related a recurring creationist argument that has been debunked over and over to a zombie. I liked the analogy, because it leads to the question "How does one kill that which has no life?" It's much like the situation with these stupid arguments that the creationists come up with. They have no real life as a scientific explanation, and they are damn hard to kill. One could also liken them to a zombie process on a computer. $kill -9 [pid] does not work!

stevaroni · 12 March 2010

TomS said: I have seen responses from creationists to "there is no such thing as a truly closed system."
I always make the offer that we can always investigate what happens in a mostly closed system. All we have to do is take a creationist, seal him in a 55 gallon drum, and store him in the back of a cool, dark, closet for a week or two. I suspect that at the end of the experiment, entropy inside the drum will be found to have increased dramatically. (at least the creationist version of entropy)

darwinism.dogBarf() · 12 March 2010

Evolutionists are so stupid they do not even know the difference between a closed and an isolated system. A closed system can have energy exchange with the outside world, but not matter exchange. Only in an isolated system are both energy and matter sealed off from the outside world.

Evolutionists think even in a closed system like the earth, and certainly in an open one, complexity increases because of the input of energy. Well, why is it that you can't build cars by blowing up junk yards? If evolutionism was true, we could make environmentally friendly, durable, fast, and safe cars just by blowing up the old ones. Why can't we do that?

Evolutionists have not considered the earth is a cognitively isolated system. The amount of information present on earth always stays the same. No new information is being injected from the outside. That is why you can't make cars by the method described and why evolutionism--which is the same thing--doesn't work.

Henry J · 12 March 2010

The input of energy is a prerequisite, not a cause by itself. Sheesh.

Rilke's granddaughter · 12 March 2010

Even in the confused world of creationism, your claim is utterly wrong. Information (you might consider defining that, child) flows into the earth continually, giving us data on every EMR source available. Are you only here to snark or do you want to discuss anything? Starting off with numerous errors made be a bad choi e on your part.
darwinism.dogBarf() said: Evolutionists are so stupid they do not even know the difference between a closed and an isolated system. A closed system can have energy exchange with the outside world, but not matter exchange. Only in an isolated system are both energy and matter sealed off from the outside world. Evolutionists think even in a closed system like the earth, and certainly in an open one, complexity increases because of the input of energy. Well, why is it that you can't build cars by blowing up junk yards? If evolutionism was true, we could make environmentally friendly, durable, fast, and safe cars just by blowing up the old ones. Why can't we do that? Evolutionists have not considered the earth is a cognitively isolated system. The amount of information present on earth always stays the same. No new information is being injected from the outside. That is why you can't make cars by the method described and why evolutionism--which is the same thing--doesn't work.

eric · 12 March 2010

darwinism.dogBarf() said: Evolutionists are so stupid they do not even know the difference between a closed and an isolated system. A closed system can have energy exchange with the outside world, but not matter exchange... ...Evolutionists think even in a closed system like the earth...
Doesn't look too closed to me.

Jesse · 12 March 2010

darwinism.dogBarf() said: Evolutionists are so stupid they do not even know the difference between a closed and an isolated system. A closed system can have energy exchange with the outside world, but not matter exchange. Only in an isolated system are both energy and matter sealed off from the outside world. Evolutionists think even in a closed system like the earth, and certainly in an open one, complexity increases because of the input of energy. Well, why is it that you can't build cars by blowing up junk yards? If evolutionism was true, we could make environmentally friendly, durable, fast, and safe cars just by blowing up the old ones. Why can't we do that? Evolutionists have not considered the earth is a cognitively isolated system. The amount of information present on earth always stays the same. No new information is being injected from the outside. That is why you can't make cars by the method described and why evolutionism--which is the same thing--doesn't work.
Give a definition of what it means for a system to be closed. Then explain how that big, bright thingy in the daytime sky that your ancestors probably worshiped 10,000 years ago plays into that. Please. It'll be interesting.

stevaroni · 12 March 2010

darwinism.dogBarf() said: Evolutionists have not considered the earth is a cognitively isolated system. The amount of information present on earth always stays the same. No new information is being injected from the outside.
Interesting... a cognitively isolated system. That's a new one to me. Care to define some terms, dogbarf? How do I measure information? And can information be created or destroyed? If so,(or if not) how do I demonstrate this? If I have a page full of English text, is there less "information" if I leave it on a train station in rural China where few people could read it? If I reach into a bucket of scrabble tiles and come out with a word, have I "created" information? More directly to the point, if I take a string of DNA, split it in half, and rejoin it with one end turned around, does it have more, less, or the same information I started with. How could I tell? short of finding the exact right organism to "run the program" how might I measure the information of both strands? And, if I did "run the program" in two organisms and got different results in both, how could I objectively tell which was "right"? If I took a piece of nonfunctional "junk" DNA from organism A, and put it into organism B and it did something, have I created or destroyed information? And how can I objectively measure any of this without assigning a human value to what it does? Does Dawkin's weasel "create" information or merely "search" for it where there was none before? I ask this because your nom de plume seems to infer a certain familiarity with programming languages. Are you another one of Dembski's "software engineers", A'la Tommy Hard? If so, this should be fun, because you should understand enough information theory to actually make your case. Besides, this is all a straw man anyhow. Even if Earth were a "cognitively isolated system", whatever that unsubstantiated word salad might mean, that still isn't a problem for evolution. "Information" in the genome demonstrably does not come from "nothing". It is transferred from the environment into the genome when the environment selects for fitness. Essentially, the environment performs a sort function and specifies a cutoff point. That "information" (in colloquial terms, which organisms were fit enough to survive), is demonstrably all the proscess needs to iterate. And, unlike your "blow up a car" analogy, that assertion is actual demonstrable fact. It's not even apparent that the earth has to "loose" information in the accounting, the "information" might simply be duplicated. (How do multiple copies of the same information fit into your math anyhow, dogbarf?)

darwinism.dogBarf() · 12 March 2010

Jesse said:
darwinism.dogBarf() said: Evolutionists are so stupid they do not even know the difference between a closed and an isolated system. A closed system can have energy exchange with the outside world, but not matter exchange. Only in an isolated system are both energy and matter sealed off from the outside world. Evolutionists think even in a closed system like the earth, and certainly in an open one, complexity increases because of the input of energy. Well, why is it that you can't build cars by blowing up junk yards? If evolutionism was true, we could make environmentally friendly, durable, fast, and safe cars just by blowing up the old ones. Why can't we do that? Evolutionists have not considered the earth is a cognitively isolated system. The amount of information present on earth always stays the same. No new information is being injected from the outside. That is why you can't make cars by the method described and why evolutionism--which is the same thing--doesn't work.
Give a definition of what it means for a system to be closed. Then explain how that big, bright thingy in the daytime sky that your ancestors probably worshiped 10,000 years ago plays into that. Please. It'll be interesting.
Well, I am using the same definition used at evolutionists' universities. Check this site out if you're not convinced. A closed system can still exchange energy, just not matter. (Yes, I am aware there are a few meteorites coming down and space probes going up, but it still practically closed.) I am proposing a new category of system--cognitively isolated--that does not allow information exchange.

Stanton · 12 March 2010

So, dogbarf, please explain why you say the Earth is a "closed" system when the vast majority of life derives energy taken from the light radiating from the Sun?

Mike Elzinga · 12 March 2010

darwinism.dogBarf() said: I am proposing a new category of system--cognitively isolated--that does not allow information exchange.
That would be an ID/creationist.

Mike Elzinga · 12 March 2010

darwinism.dogBarf() said: Evolutionists are so stupid they do not even know the difference between a closed and an isolated system. A closed system can have energy exchange with the outside world, but not matter exchange. Only in an isolated system are both energy and matter sealed off from the outside world.
Look up the words adiabatic and isothermal. Then look up the word brain-dead.

Evolutionists think even in a closed system like the earth, and certainly in an open one, complexity increases because of the input of energy.

This is a false characterization so that you can make the stupid remark that followed. We suspect that you know that you are doing the typical “Christian” taunting shtick. Before you make a whole bunch of assertions and assumptions about what scientists know, why don’t you read this entire thread and the “Entropy and Evolution” thread as well?

stevaroni · 12 March 2010

darwinism.dogBarf() said: I am proposing a new category of system--cognitively isolated--that does not allow information exchange.
Oh. And are you going to conduct any actual research as to the veracity of your construct, or is this a another Bill Dembski "definition by fiat"?

Jesse · 12 March 2010

darwinism.dogBarf() said: Well, I am using the same definition used at evolutionists' universities. Check this site out if you're not convinced. A closed system can still exchange energy, just not matter. (Yes, I am aware there are a few meteorites coming down and space probes going up, but it still practically closed.) I am proposing a new category of system--cognitively isolated--that does not allow information exchange.
I can say great confidence that a) your assumptions are wrong by more than just a few meteorites (the Earth's atmosphere is constantly being bombarded) and b) a system need not exchange matter for a local decrease in entropy to be observed. Since you're going to make up a new category of system called "cognitively" isolated (which, BTW, anthropomorphizes natural phenomena themselves - the irony is delicious,) you had better define it. And all of the supporting terms. In a way that is testable. Then you should really strive hard to make the argument that you are not conflating shannon entropy with thermal entropy. Let me just make this statement: Entropy doesn't mean what you think it means.

fnxtr · 12 March 2010

I only count two so far, e.db.
You still need eight more for extra credit.

SWT · 12 March 2010

dogbarf(),

Actually, I made the distinction between closed and isolated systems on the fourth page of this thread. If the argument you are trying to make is that the second law of thermodynamics in all cases prevents the formation of dissipative structures (like living organisms), the distinction between open, closed, and isolated systems doesn't matter -- if I have an isolated system that is not at equilibrium, I can subdivide it into subsystems that can participate in the mass and/or energy exchanges necessary to maintain a dissipative structure for some period of time. There is some very nice work done on the requirements for the formation of dissipative structures and the stability of these structures. You appear to be completely unaware of this work, as do most if not all of your fellow science deniers.

If you really want to discuss advanced thermodynamics with people who are (or were) using it as part of their work as scientists, you really do need to learn at least basic undergraduate thermodynamics ... and you won't get that from an introductory book on earth science. Especially from one that is, wrong in categorizing the earth as a closed system.

And, I'm sorry I didn't see your posts sooner, all the really good snark about cognitive isolation has already been used.

stevaroni · 12 March 2010

SWT said: And, I'm sorry I didn't see your posts sooner, all the really good snark about cognitive isolation has already been used.
Fear not, SWT. I suspect that, with a fresh semester of Dembski students vying for those extra credit points, there will be plenty of new and previously unexplored word salad thermodynamics and information theory nonsense to snark at.

Mike Elzinga · 12 March 2010

fnxtr said: I only count two so far, e.db. You still need eight more for extra credit.
I wonder if Dembski counts snarky taunts as part of the 10 posts. And I don’t know how he would judge substance of any of his students’ posts since he is not aware of his own misconceptions which are so profound and ingrained. It makes it appear that his is sending out his rubes as point men to do the reconnaissance and take the flack for his own stupidity because he himself is terrified of the crucible of peer-review by real scientists.

Jesse · 12 March 2010

SWT said: And, I'm sorry I didn't see your posts sooner, all the really good snark about cognitive isolation has already been used.
Not so. That was some good snark all by itself.

Mike Elzinga · 12 March 2010

stevaroni said:
SWT said: And, I'm sorry I didn't see your posts sooner, all the really good snark about cognitive isolation has already been used.
Fear not, SWT. I suspect that, with a fresh semester of Dembski students vying for those extra credit points, there will be plenty of new and previously unexplored word salad thermodynamics and information theory nonsense to snark at.
Yeah, like how a system “knows” whether or not to take in information, and further, what to do with it if it “decides” to take it in.

Jesse · 12 March 2010

Mike Elzinga said: Yeah, like how a system “knows” whether or not to take in information, and further, what to do with it if it “decides” to take it in.
Maxwell's Daemon? Or Morton's Daemon?

DS · 12 March 2010

darwinism.dogBarf() said:

"I am proposing a new category of system–cognitively isolated–that does not allow information exchange."

Oh, like creationists. No matter what, no new information will ever be looked at, discussed or even acknowledged. They just keep pointing out over and over again that Darwin didn't know everything while ignoring all of the findings of science in the last one hundred and fifty years. You mean that kind of "cognitive isolation"? Yea, nothing good can ever come of that type of thing.

ben · 12 March 2010

I am proposing a new category of system–cognitively isolated–that does not allow information exchange
I am proposing that you don't know the first thing about information or entropy, beyond whatever rhetorical balloon animals you can spin with those words and concepts, to manufacture sciency but vacuous religious apologetics for your lame god, who apparently has nothing to say herself.

Rilke's granddaughter · 12 March 2010

And do you think all this exploratory snark will help the IDists any closer to a working definition of infotmation.

Henry J · 12 March 2010

Maybe they're trying to prove conservation of information by showing that they never increase the amount of it they possess?

tresmal · 12 March 2010

Henry J said: Maybe they're trying to prove conservation of information by showing that they never increase the amount of it they possess?
I would take it a little farther than that. The Law of Conservation of Information requires that an increase in scientific knowledge must be offset by an equal increase in ignorance somewhere else. In other words scientific progress is making creationists more ignorant.

Jesse · 12 March 2010

tresmal said:
Henry J said: Maybe they're trying to prove conservation of information by showing that they never increase the amount of it they possess?
I would take it a little farther than that. The Law of Conservation of Information requires that an increase in scientific knowledge must be offset by an equal increase in ignorance somewhere else. In other words scientific progress is making creationists more ignorant.
You forgot about the intelligent designer part. It takes some intelligence to be that willfully ignorant. You could say it is by design.

Joe Felsenstein · 12 March 2010

darwinism.dogBarf() said: Evolutionists are so stupid they do not even know the difference between a closed and an isolated system. A closed system can have energy exchange with the outside world, but not matter exchange. Only in an isolated system are both energy and matter sealed off from the outside world. ... [delete rest] ...
I am going to make a big confession. darwinism.dogbarf() is right ... on one point. After looking at a few thermodynamics textbooks, Wikipedia, etc. I have to say that I was wrong -- the opposite of an open system is supposed to be called an isolated system, not a closed system. My bad. So please go through my original argument and replace “closed” by “isolated” throughout. And then what? Well, it turns out to still be valid. Granville Sewell turns out to still be wrong, and the Discovery Institute turns out to still be sponsoring wrong science. If dogbarf is an not a silly off-the-wall troll, dogbarf could perhaps explain what is wrong with my argument. But not by making up general principles of “cognitive isolation” which are contradicted -- like Sewell's original argument -- every time a weed grows in my back yard.

fnxtr · 13 March 2010

ben said: rhetorical balloon animals
Brill. Absolutely brill.

Mike Elzinga · 13 March 2010

Joe Felsenstein said: I am going to make a big confession. darwinism.dogbarf() is right ... on one point. After looking at a few thermodynamics textbooks, Wikipedia, etc. I have to say that I was wrong -- the opposite of an open system is supposed to be called an isolated system, not a closed system. My bad.
It’s a little easier to keep track if you think of the three main mechanisms that can carry energy into an out of the system; namely, photons, phonons, or other particles of matter. Then there is also the issue of interactions among the constituents of a system whereby they exchange energy among themselves. All matter interacts, especially when in close proximity. And it is the nature of these interactions that generate the photons and/or phonons that carry away energy (unless the system is adiabatically enclosed; in which case those photons are returned to the system and transfer their energy back into the matter). If the constituents of a system did not interact at all, then the energy within the system would not ultimately get distributed into the most probable states. Those interactions lead to the 2nd law because photons or phonons get generated. If these can leave the constituents, carrying energy away as they do, then matter condenses. It is extremely difficult to make a totally isolated system; and it is nearly impossible to make the constituents of such a system non-interactive.

stevaroni · 13 March 2010

tresmal said: I would take it a little farther than that. The Law of Conservation of Information requires that an increase in scientific knowledge must be offset by an equal increase in ignorance somewhere else. In other words scientific progress is making creationists more ignorant.
Actually, this is kinda true. Once upon a time, it was common for learned men to have a background in both science and theology. In fact, you weren't considered "educated" without it. These mean (there were precious few women, sadly) had no trouble keeping both sides of the equation in their heads. DaVinci, Gallileo, Newton, Maxwell, they were all religious men. Copernicus was a monk, and even Darwin was an ordained minister. They were all unblinking creationists, the vast majority of Victorian scientists were happy to accept that God made the world, they were excited that they finally had the tools to figure out exactly how the Big Guy accomplished the task. The problem was, that as more and more knowledge about the mechanisms of nature was dug up (sometimes literally), the less and less need there turned out to be for God to watch every sparrow fall. The more people really looked at nature, the more it was apparent that the world seemed to run just fine without divine intervention. As Laplace famously noted in the dry analysis of science "The 'God hypothesis' was no longer necessary." This started to pose a significant problem for people who read the Bible literally. In order to remain a classic New Earth / Garden / Noah's Ark creationist, you actually had to start ignoring an increasing pile of data that pointed in the other direction. Nowadays, we're faced with the farcical display of creationist websites like AIG trying to explain that creation could have happened as told in Genesis becasue the speed of light randomly changes, the Earth is surrounded by a giant shell of water, and the dinosaurs were all killed and methodically sorted by global floods - all things which can only be believed if you're willing to ignore piles of empirical data that the rest of mankind has been happily using for decades. So yes, scientific progress is making creationists ignorant. The more data science turns up, the more things that creationists must ignore. Maybe dogbarf is onto something here and I've been too hasty with him. Maybe Dembski actually has turned up a new principal of nature - "conservation of ignorance".

Mike Elzinga · 13 March 2010

stevaroni said: Nowadays, we're faced with the farcical display of creationist websites like AIG trying to explain that creation could have happened as told in Genesis becasue the speed of light randomly changes, the Earth is surrounded by a giant shell of water, and the dinosaurs were all killed and methodically sorted by global floods - all things which can only be believed if you're willing to ignore piles of empirical data that the rest of mankind has been happily using for decades.
I suspect it has a lot to do with market share. Ken Ham’s AiG, the “Discovery” Institute, and the Institute for Creation “Research”, all these are the primary sources of income for the charlatans who run them. Fundamentalists are a fertile territory for finding rubes. They are already frightened into line by their personality cult leaders, and they have spent so much time in word-gaming that they can no longer discriminate among concepts, reality, and fantasy. So snake-oil salesmen can find easy refuge among them by speaking their language and appearing educated in science. Then the political demagogues take note and sweep them up in conspiracy theories and paranoiac fear. Now you have an army of blind rubes who will obey every command of their leaders while believing they are doing God’s work.

TomS · 13 March 2010

stevaroni said: Copernicus was a monk, and even Darwin was an ordained minister.
Neither is true.

stevaroni · 13 March 2010

TomS said:
stevaroni said: Copernicus was a monk, and even Darwin was an ordained minister.
Neither is true.
OK, after looking it up, here's the long story. Copernicus had a long affiliation with the Catholic church. He appears to have have skirted the actual formalisms of church hierarchy, being more interested in the access his credentials provided to the science and diplomatic actives of the church. Nonetheless, he was an apprentice at the Papal Curia in 1500 and received a Doctorate in Canon Law in 1503, positions which, at the time, would have required demonstrable adherence to formal theological practice. It is unknown whether he was fully ordained a priest, he is known to have taken minor orders, giving him similar status to a monk. He was known to be a member of the Warmia canonry. Although he had independent means which at times he enjoyed, he spent most of his life living in a semi-formal relationship with the church. I'm calling that legitimate "monk". You are, correct on Darwin, however. Charles Darwin went to Cambridge to earn a degree in Theology in anticipation of a career in the Anglican clergy. However, he got diverted into biology. After his return to England, he was active as an assistant deacon and elder in his parish but was not in fact, ever ordained. Later in life, the death of his beloved daughter, Annie caused Darwin to have a severe crisis of faith and he stopped going to church.